CN113547819A - Transparent film for vacuum insulation panel and vacuum insulation composite board - Google Patents
Transparent film for vacuum insulation panel and vacuum insulation composite board Download PDFInfo
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- CN113547819A CN113547819A CN202110866482.9A CN202110866482A CN113547819A CN 113547819 A CN113547819 A CN 113547819A CN 202110866482 A CN202110866482 A CN 202110866482A CN 113547819 A CN113547819 A CN 113547819A
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- 238000009413 insulation Methods 0.000 title claims abstract description 72
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 230000004888 barrier function Effects 0.000 claims abstract description 46
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 33
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 33
- 239000004952 Polyamide Substances 0.000 claims abstract description 32
- 229920002647 polyamide Polymers 0.000 claims abstract description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920006267 polyester film Polymers 0.000 claims abstract description 16
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 15
- 230000001070 adhesive effect Effects 0.000 claims abstract description 15
- 239000011230 binding agent Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 22
- 239000011888 foil Substances 0.000 abstract description 20
- 229910052751 metal Inorganic materials 0.000 abstract description 14
- 239000002184 metal Substances 0.000 abstract description 14
- 239000000463 material Substances 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 70
- 238000012360 testing method Methods 0.000 description 15
- 238000004458 analytical method Methods 0.000 description 6
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
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Landscapes
- Laminated Bodies (AREA)
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Abstract
The invention relates to a transparent film for a vacuum heat insulation plate and a vacuum heat insulation composite plate. The transparent film for the vacuum insulation panel comprises a polyamide film layer, a low-density polyethylene layer and three barrier layers. The polyamide film layer, the low-density polyethylene layer and the three barrier layers are bonded and connected through adhesives. The barrier layer is made of vapor-deposited silicon oxide polyester film. The transparent film for the vacuum heat-insulating plate uses a pure transparent evaporated silicon oxide polyester film as a barrier layer of a product instead of a conventional aluminum-plated film and an aluminum foil, and prevents water vapor and oxygen from permeating into the vacuum heat-insulating plate. The pure transparent evaporated silicon oxide polyester film does not contain any metal component, so that the edge heat conduction caused by metal heat conduction is greatly reduced, and the barrier property can also reach that of an aluminum-plated film material containing the metal component.
Description
Technical Field
The invention relates to the technical field of vacuum heat insulation plates, in particular to a transparent film for a vacuum heat insulation plate and a vacuum heat insulation composite plate adopting the transparent film for the vacuum heat insulation plate.
Background
The vacuum heat insulation plate is one kind of vacuum heat insulation material, is formed by filling a core material inside and covering a vacuum protection surface layer outside, effectively avoids heat transfer caused by air convection, thereby greatly reducing the heat conductivity coefficient.
The vacuum protection surface layer covered outside is often a material with high barrier property, which can block gas and liquid outside, the common film layer is a multilayer film, but the film contains a metal layer, and the metal layer has certain heat-conducting property, so that the edge heat-conducting effect of the vacuum insulation plate can be improved, and the comprehensive heat-insulating property of the vacuum insulation plate is influenced.
Disclosure of Invention
In view of the above, it is necessary to provide a transparent film for a vacuum insulation panel and a vacuum insulation composite panel using the same, in order to solve the problem that the heat-conductive property of a metal layer itself in a conventional vacuum insulation panel film affects the heat-insulating property of the vacuum insulation panel.
A transparent film for a vacuum insulation panel comprises a polyamide film layer, a low-density polyethylene layer and three barrier layers. The polyamide film layer, the low-density polyethylene layer and the three barrier layers are bonded and connected through adhesives. The barrier layer is made of vapor-deposited silicon oxide polyester film.
The transparent film for the vacuum insulation panel uses a pure transparent vapor-deposited silicon oxide polyester film as a barrier layer of a product instead of a conventional aluminum-plated film and aluminum foil, and prevents water vapor and oxygen from permeating into the vacuum insulation panel. The pure transparent evaporated silicon oxide polyester film does not contain any metal component, so that the edge heat conduction caused by metal heat conduction is greatly reduced, the barrier property can also reach the aluminum-plated film material containing the metal component, and the pure transparent evaporated silicon oxide polyester film has a good heat preservation effect.
In one embodiment, the polyamide film layer, the low density polyethylene layer and the three barrier layers are sequentially arranged in the order of polyamide film layer-barrier layer-low density polyethylene layer, or barrier layer-polyamide film layer-barrier layer-low density polyethylene layer.
In one embodiment, the transparent film comprises 14.01-15.76% of the polyamide film layer, 7.29-11.74% of the adhesive, 39.02-44.13% of the barrier layer and 30.87-37.28% of the low density polyethylene layer by weight.
In one embodiment, the transparent film has a polyamide film layer 14.87%, an adhesive 9.33%, a barrier layer 42.13%, and a low density polyethylene layer 33.67%, respectively, in terms of weight ratio.
In one embodiment, the polyamide film layer has a thickness of 15 μm. The low density polyethylene layer has a thickness of 45-55 μm. The thickness of the barrier layer is 12-12.8 μm.
In one embodiment, the bond thickness between each adjacent film layer is the same, and the overall bond thickness of the adhesive is 2-3.5 μm.
In one embodiment, the adhesive is a polyurethane adhesive.
The invention also discloses a vacuum heat insulation composite plate, which comprises a vacuum heat insulation plate and a transparent film wrapped outside the vacuum heat insulation plate; the transparent film is the transparent film for the vacuum insulation panel.
Compared with the prior art, the invention has the following beneficial effects:
the transparent film for the vacuum heat-insulating plate uses the pure transparent evaporated silicon oxide polyester film as a barrier layer of the product instead of the prior aluminizer and aluminum foil, and prevents water vapor and oxygen from permeating into the vacuum heat-insulating plate.
The mode of laminating and compounding 3 layers of evaporated silicon oxide polyester films is used for obtaining excellent barrier performance.
The pure transparent evaporated silicon oxide polyester film does not contain any metal component, so that the edge heat conduction caused by metal heat conduction is greatly reduced, the barrier property can also reach the aluminum-plated film material containing the metal component, and the pure transparent evaporated silicon oxide polyester film has a good heat preservation effect.
Drawings
Fig. 1 is a schematic view of one of the structures of a transparent film for a vacuum insulation panel.
Fig. 2 is a thermal image of a vacuum insulation panel comprising an aluminum foil film.
Fig. 3 is a thermal imaging view of a vacuum insulation panel comprising an aluminum plated film.
Fig. 4 is a thermal imaging diagram of the composite board of the present embodiment.
In the figure: 1-polyamide film layer, 2-barrier layer and 3-low density polyethylene layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It will be understood that when an element is referred to as being "mounted on" another element, it can be directly on the other element or intervening elements may also be present. When a component is referred to as being "disposed on" another component, it can be directly on the other component or intervening components may also be present. When an element is referred to as being "secured to" another element, it can be directly secured to the other element or intervening elements may also be present.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "or/and" includes any and all combinations of one or more of the associated listed items.
Example 1
A transparent film for a vacuum insulation panel is used for wrapping the vacuum insulation panel and is used as an outer film of the vacuum insulation panel, so that the heat insulation performance of the vacuum insulation panel is improved. In this embodiment, the transparent film includes a composite stacked polyamide film layer, a low density polyethylene layer, and a three-layer barrier layer, and is a multilayer film structure. The polyamide film layer, the low-density polyethylene layer and the three barrier layers are bonded and connected through adhesives. Referring to fig. 1, in fig. 1, 1 is a polyamide film layer, 2 is a barrier layer, and 3 is a low density polyethylene layer. In this example, the layers of the transparent film were arranged in the order of a polyamide film layer-a barrier layer-a low density polyethylene layer. Of course, in other embodiments, the transparent film layers may also be arranged in the order of barrier layer-polyamide film layer-barrier layer-low density polyethylene layer, or barrier layer-polyamide film layer-barrier layer-low density polyethylene layer, barrier layer-polyamide film layer-low density polyethylene layer.
In one embodiment, the vacuum insulation panel is manufactured by a dry lamination process using a transparent film.
Wherein, the specific gravity of each component is 14.01 to 15.76 percent of the polyamide film layer, 7.29 to 11.74 percent of the adhesive, 39.02 to 44.13 percent of the barrier layer and 30.87 to 37.28 percent of the low-density polyethylene layer respectively according to the weight ratio. In this example, the specific gravities of the respective components were 14.87% for the polyamide film layer, 9.33% for the binder, 42.13% for the barrier layer, and 33.67% for the low-density polyethylene layer. Of course, in other embodiments, the weight ratio of the polyamide film layer can be any of 14.01%, 15.76%, or 14.01-15.76%; the weight proportion of the adhesive can be any value of 7.29%, 11.74% or 7.29-11.74%; the weight ratio of the barrier layer can be any value of 39.02%, 44.13% or 39.02-44.13%; the low density polyethylene layer may be 37.28%, 30.87%, or 30.87-37.28% by weight.
In this example, the thickness of the polyamide film layer was 15 μm. The low density polyethylene layer may have a thickness of between 45 and 55 μm, in this example 50 μm. Of course, in other embodiments, the thickness of the heat-seal layer, i.e. the low-density polyethylene layer, may be 45 μm, may also be 55 μm, or may have other values in the range of 45-55 μm. The barrier layer is made of vapor-deposited silicon oxide polyester film, and has a thickness of 12-12.8 μm and a total thickness of 36-38 μm. In one of the embodiments, the thickness of the barrier layer may be set to 12 μm.
In one embodiment, the adhesive is a polyurethane glue to ensure that the film does not delaminate.
The performance of the transparent film was also tested in this example, while using an aluminum foil film and an aluminum-plated film for a conventional vacuum insulation panel on the market as a comparison. The details are as follows.
a. Barrier test
The transparent film of the present example, the aluminum foil film for a vacuum insulation panel on the market, and the aluminum-plated film were cut into samples of 100MM × 100MM size, and the samples were placed on an MOCON oxygen permeation apparatus and a water permeation apparatus to be tested, and the test results are shown in table 1.
Table 1 shows the results of the barrier test.
b. Thermal diffusion Performance test
The transparent film of the present example, the aluminum foil film for a vacuum insulation panel on the market, and the aluminum-plated film were each analyzed by a laser thermal conductivity meter. In this example, an LFA thermal conductivity instrument from NETZSCH was used.
The conventional information parameters of the aluminum foil film are shown in Table 2, and the analysis results are shown in Table 3.
Table 2: conventional information parameter table of aluminum foil film
Table 3: thermal diffusion performance analysis result table of aluminum foil film
The conventional information parameters of the aluminum-plated film are shown in Table 4, and the analysis results are shown in Table 5.
Table 4: conventional information parameter table of aluminizer
Table 5: thermal diffusion performance analysis result table of aluminizer
The general information parameters of the transparent film are shown in Table 6, and the analysis results are shown in Table 7.
Table 6: conventional information parameter Table for the transparent film of the present example
Table 7: table of the results of analysis of thermal diffusion Properties of the transparent film of this example
The heat diffusion coefficients of the transparent film, the aluminum foil film and the aluminum-plated film are obtained as shown in table 8 by comparing the data analysis tables of the transparent film, the aluminum foil film and the aluminum-plated film.
Table 8: heat diffusion coefficient table of transparent film, aluminum foil film and aluminum-plated film
The transparent film for the vacuum insulation panel of the embodiment uses the pure transparent evaporated silicon oxide polyester film layer to replace the prior aluminum-plated film layer and aluminum foil layer as the barrier layer of the product, so as to prevent water vapor and oxygen from permeating into the vacuum insulation panel; the excellent barrier property is obtained by using a mode of superposing and compounding 3 layers of evaporated silicon oxide polyester film layers; the pure transparent evaporated silicon oxide polyester film layer does not contain any metal component, so that the edge heat conduction caused by metal heat conduction is greatly reduced.
Example 2
The embodiment discloses a vacuum heat insulation composite board, which comprises a vacuum heat insulation board and a transparent film wrapped outside the vacuum heat insulation board; the transparent film used in example 1 was used as the transparent film for the vacuum insulation panel. The vacuum heat insulation composite board made of the transparent film can clearly see the conditions of the inner core materials, whether impurities exist, whether the arrangement is uniform and whether the core materials have defects or not, and is more favorable for acceptance and inspection of products.
The performance of the vacuum insulation composite panel was also tested in this example, and the commercial vacuum insulation panels including aluminum foil films and vacuum insulation panels including aluminum-plated films were used as a comparison. The details are as follows.
c. Test of plate thermal conductivity
The comparison test under normal temperature conditions shows the test results in table 9.
Table 9: test result table for heat conductivity coefficient of plate under normal temperature condition
Through comparison tests, the heat conductivity coefficient of the vacuum heat insulation composite board made of the transparent film is consistent with that of the vacuum heat insulation board made of the aluminum-plated film and is slightly lower than that of the vacuum heat insulation board made of the aluminum foil film under the condition that the vacuum heat insulation composite board is placed at normal temperature, so that the barrier property of the transparent film is judged to reach the same level of the aluminum-plated film, and the heat conductivity coefficient of the made vacuum heat insulation composite board is also consistent with that of the vacuum heat insulation board made of the aluminum-plated film.
d. Edge conduction testing of sheet materials
The experimental method comprises the following steps: the composite board and the vacuum insulation board with the size of 300MM × 300MM made of different film materials are placed on a heating table with the temperature of 40 ℃ to be heated for 30 minutes, and the edge heat transfer effect is checked through infrared imaging and temperature detection.
Referring to fig. 2-4, fig. 2 is a thermal image of a vacuum insulation panel including an aluminum foil film. Fig. 3 is a thermal imaging view of a vacuum insulation panel comprising an aluminum plated film. Fig. 4 is a thermal imaging diagram of the composite board of the present embodiment. The comparison shows that the composite board has obviously lower edge heat conduction effect and is superior to the heat conduction of the vacuum heat-insulating board made of the aluminum foil film and the aluminum-plated film, so that the composite board made of the transparent film has superior comprehensive heat-insulating performance.
e. Aging test of plate life
The test method comprises the following steps: referring to the standard GB37608-2018, the composite board and the vacuum composite board made of the aluminizer and the aluminum foil are placed in a high-temperature high-humidity box with the temperature of 70 ℃ and the humidity of 90% for life aging test, the heat conductivity coefficient is detected every 7 days, and the conclusion of the life test is judged according to the increase condition of the heat conductivity coefficient. The results are shown in Table 10.
Table 10: plate life aging test result table
The test shows that the performance of the composite board prepared by the embodiment is superior to that of the vacuum insulation board prepared by the aluminum-plated film when the composite board is subjected to an accelerated aging test under the humidity condition of 70-90%, but the composite board is inferior to that of the vacuum insulation board prepared by the aluminum foil film, so that the transparent film prepared by the embodiment has better high-temperature and high-humidity resistance than that of the aluminum-plated film product for the vacuum insulation board.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present application shall be subject to the appended claims.
Claims (10)
1. The transparent film for the vacuum insulation panel is characterized by comprising a polyamide film layer, a low-density polyethylene layer and three barrier layers; the polyamide film layer, the low-density polyethylene layer and the three barrier layers are bonded through adhesives, and the barrier layers are made of evaporated silicon oxide polyester films.
2. The transparent film for vacuum insulation panels according to claim 1, wherein the polyamide film layer, the low density polyethylene layer and the three barrier layers are sequentially arranged in the order of polyamide film layer-barrier layer-low density polyethylene layer, or barrier layer-polyamide film layer-barrier layer-low density polyethylene layer, or barrier layer-polyamide film layer-barrier layer-low density polyethylene layer, barrier layer-polyamide film layer-low density polyethylene layer.
3. The transparent film for a vacuum insulation panel according to claim 1, wherein the transparent film comprises 14.01 to 15.76% by weight of the polyamide film layer, 7.29 to 11.74% by weight of the binder, 39.02 to 44.13% by weight of the barrier layer, and 30.87 to 37.28% by weight of the low density polyethylene layer.
4. The transparent film for a vacuum insulation panel according to claim 1, wherein the transparent film comprises 14.87% of the polyamide film layer, 9.33% of the binder, 42.13% of the barrier layer and 33.67% of the low density polyethylene layer, respectively, in terms of weight ratio.
5. The transparent film for a vacuum insulation panel according to claim 1, wherein the thickness of the polyamide film layer is 15 μm.
6. The transparent film for vacuum insulation panel according to claim 1 wherein the low density polyethylene layer has a thickness of 45 to 55 μm.
7. The transparent film for a vacuum insulation panel according to claim 1, wherein the barrier layer has a thickness of 12 to 12.8 μm.
8. The transparent film for a vacuum insulation panel according to claim 1, wherein the bonding thickness between each adjacent film layers is the same, and the overall bonding thickness of the adhesive is 2 to 3.5 μm.
9. The transparent film for vacuum insulation panels according to claim 1, wherein the adhesive is a polyurethane adhesive.
10. The vacuum heat insulation composite board comprises a vacuum heat insulation board and is characterized by also comprising a transparent film wrapped outside the vacuum heat insulation board; the transparent film is the transparent film for vacuum insulation panel according to any one of claims 1 to 9.
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CN106232356A (en) * | 2014-04-23 | 2016-12-14 | 乐金华奥斯有限公司 | Vacuum heat insulation materials skin material and comprise its vacuum heat insulation materials |
CN206335933U (en) * | 2016-09-23 | 2017-07-18 | 中国乐凯集团有限公司 | A kind of high-isolating packaging film |
CN215512694U (en) * | 2021-07-29 | 2022-01-14 | 安徽省恳思惠新型材料有限责任公司 | Transparent film for vacuum insulation panel and vacuum insulation composite board |
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2021
- 2021-07-29 CN CN202110866482.9A patent/CN113547819A/en active Pending
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CN202911236U (en) * | 2012-07-03 | 2013-05-01 | 上海紫江彩印包装有限公司 | High-barrier film for insulation material |
CN203032025U (en) * | 2013-01-10 | 2013-07-03 | 中亨新型材料科技有限公司 | Barrier film and vacuum insulation board adopting barrier film |
CN106232356A (en) * | 2014-04-23 | 2016-12-14 | 乐金华奥斯有限公司 | Vacuum heat insulation materials skin material and comprise its vacuum heat insulation materials |
CN206335933U (en) * | 2016-09-23 | 2017-07-18 | 中国乐凯集团有限公司 | A kind of high-isolating packaging film |
CN215512694U (en) * | 2021-07-29 | 2022-01-14 | 安徽省恳思惠新型材料有限责任公司 | Transparent film for vacuum insulation panel and vacuum insulation composite board |
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Application publication date: 20211026 |