CN110372355A - 一种50度珠光全抛石材瓷质砖及其制备方法 - Google Patents
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Abstract
本发明属于瓷质砖制备技术领域且公开了一种50度珠光全抛石材瓷质砖及其制备方法,所述瓷质砖的化学成分为:SiO266.5~67%、Al2O319.2~19.5%、Fe2O30.8~1.0%、TiO20.3~0.6%、CaO 0.5~0.8%、MgO 0.9~1.2%、K2O 3.0~3.4%、Na2O 2.5~2.8%、余量为杂质;所述瓷质砖的坯体原料包括以重量百分比计的:粘土15~25%、高铝砂8.0~10%、钾长石20~25%、钠长石15~20%、石英砂20~25%、生滑石1.0~2.5%、添加剂0.5~1.0%。本发明的产品光泽度低且耐磨性能高,不易磨面和刮伤表面,经久耐用,上墙和下地都可使用,从而替代天然石材的应用,减少天然石材的开挖量,从而节约资源。
Description
技术领域
本发明涉及瓷质砖制备技术领域,尤其涉及一种50度珠光全抛石材瓷质砖及其制备方法。
背景技术
随着建筑陶瓷行业的发展,瓷质砖的表面装饰效果越来越丰富,其规格越来越大。瓷质砖以其美观性好、防水性好、硬度高、易清洁等优点,受到人们的喜爱,在装修行业的使用量逐年增加,使用范围也越来越广泛。瓷质砖是由天然石料破碎后添加化学粘合剂压合经高温烧结而成。砖的烧结温度高,瓷化程度好。但目前瓷质砖抗折断能力差,耐磨性能不高,不易磨面,并且容易刮伤表面。
发明内容
本发明要解决的技术问题是克服现有的缺陷,提供一种50度珠光全抛石材瓷质砖及其制备方法,产品光泽度低耐磨性能高,不易磨面和刮伤表面,经久耐用,上墙和下地都可使用,从而替代天然石材的应用,减少天然石材的开挖量,从而节约资源,可以有效解决背景技术中的问题。
为了解决上述技术问题,本发明提供了如下的技术方案:
本发明首先提供一种50度珠光全抛石材瓷质砖,所述瓷质砖的化学成分为:
SiO266.5~67%、Al2O319.2~19.5%、Fe2O30.8~1.0%、TiO20.3~ 0.6%、CaO0.5~0.8%、MgO 0.9~1.2%、K2O 3.0~3.4%、Na2O 2.5~2.8%、余量为杂质;
所述瓷质砖的坯体原料包括以重量百分比计的:
粘土15~25%、高铝砂8.0~10%、钾长石20~25%、钠长石15~ 20%、石英砂20~25%、生滑石1.0~2.5%、添加剂0.5~1.0%。
作为本发明的一种优选技术方案,所述瓷质砖的灼减量为5.2~ 5.5%。
本发明同时还提供一种50度珠光全抛石材瓷质砖的制备方法,包括以下步骤:
S1:将所述瓷质砖的坯体原料按比例混合均匀,压制成为坯体;
S2:配置抛釉,将砖坯保持在60~65℃喷淋于处理过的坯体上,喷淋流速为30~45秒,比重为1.82±0.1g/mL,抛釉的用量为105±1g/370 ×680mm;
S3:经1220~1250℃高温烧成1.5~2个小时后,依次进行一次粗抛光和二次精抛光的工序,最后打蜡处理。
作为本发明的一种优选技术方案,所述抛釉的化学成分为:
SiO247~49%、Al2O313~14%、Fe2O30.2~0.3%、TiO20.1~0.2%、CaO 6.0~7.0%、MgO 0.5~1.0%、K2O 4.0~5.0%、Na2O 1.5~2.0%、BaO 9.0~10%、ZrO20.1~0.2%、ZnO 9.0~10%。
作为本发明的一种优选技术方案,所述抛釉的灼减量为5.2~5.5%。
优选的,所述添加剂为甲基纤维素、羧甲基纤维素、硅酸钠、减水剂中的任意一种或几种。甲基纤维素是一种非离子纤维素醚,它是通过醚化在纤维素中引入甲基而制成的,甲基纤维素有4种重要功能:即增稠、表面活性、成膜性以及形成热凝胶。甲基纤维素溶液在很宽的PH值 (3.0~11.0)范围内是稳定的,它具有独特的热胶凝性质,即在加热时形成凝胶,冷却时熔化,胶凝温度范围为50~70℃。羧甲基纤维素又称羧甲基纤维素钠盐,羧甲基纤维素,简称CMC-Na,是葡萄糖聚合度为 100~2000的纤维素衍生物,相对分子质量242.16。白色纤维状或颗粒状粉末。无臭、有吸湿性,溶于水,不溶于乙醇、***和三聚甲烷,在日用化学工业中用作黏结剂、抗再沉凝剂。硅酸钠俗称泡花碱,是一种水溶性硅酸盐,其水溶液俗称水玻璃,是一种矿黏合剂。其化学式为 R2O·nSiO2,式中R2O为碱金属氧化物,n为二氧化硅与碱金属氧化物摩尔数的比值,称为水玻璃的摩数,具有粘结力强、强度较高,耐酸性、耐热性好的理化性能。减水剂是一种在维持混凝土坍落度基本不变的条件下能减少拌合用水量的混凝土外加剂。大多属于阴离子表面活性剂,有木质素磺酸盐、萘磺酸盐甲醛聚合物等。加入混凝土拌合物后对水泥颗粒有分散作用,能改善其工作性,减少单位用水量,改善混凝土拌合物的流动性;或减少单位水泥用量,节约水泥。
本发明中提供的一个或多个技术方案,至少具有如下技术效果或者优点:
产品光泽度低且耐磨性能高,不易磨面和刮伤表面,经久耐用,上墙和下地都可使用,从而替代天然石材的应用,减少天然石材的开挖量,从而节约资源。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
在本发明的描述中,需要理解的是,术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”等指示的方位或位置关系为基于所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。
为了更好地理解上述技术方案,下面将结合具体实施方式对上述技术方案进行详细的说明。
实施例一:
本发明一种50度珠光全抛石材瓷质砖,所述瓷质砖的化学成分为:
SiO266.5%、Al2O319.2%、Fe2O30.8%、TiO20.3%、CaO 0.5%、MgO 0.9%、K2O3.0%、Na2O 2.5%、余量为杂质;灼减量为5.2%。
所述瓷质砖的坯体原料包括以重量百分比计的:
粘土22%、高铝砂9.5%、钾长石22%、钠长石22%、石英砂22%、生滑石1.0%、添加剂0.5%,且添加剂采用甲基纤维素。
本发明同时还提供上述50度珠光全抛石材瓷质砖的制备方法,包括以下步骤:
S1:将所述瓷质砖的坯体原料按比例混合均匀,压制成为坯体;
S2:配置抛釉,抛釉的化学成分为:
SiO247%、Al2O313%、Fe2O30.2%、TiO20.1%、CaO 7.0%、MgO 0.5%、 K2O 4.0%、Na2O 1.5%、BaO 9.0%、ZrO20.1%、ZnO 9.0%、灼减量为 5.2%,将砖坯保持在60℃喷淋于处理过的坯体上,喷淋流速为30秒,比重为1.82g/mL,抛釉的用量为105g/370×680mm;
S3:经1220℃高温烧成1.5个小时后,依次进行一次粗抛光和二次精抛光的工序,最后打蜡处理。
实施例二:
本发明一种50度珠光全抛石材瓷质砖,所述瓷质砖的化学成分为:
SiO267%、Al2O319.5%、Fe2O31.0%、TiO20.6%、CaO 0.8%、MgO 1.2%、K2O3.4%、Na2O 2.8%、余量为杂质;灼减量为5.5%。
所述瓷质砖的坯体原料包括以重量百分比计的:
粘土25%、高铝砂8.0%、钾长石20%、钠长石20%、石英砂25%、生滑石1.0%、添加剂1.0%,且添加剂采用硅酸钠。
本发明同时还提供上述50度珠光全抛石材瓷质砖的制备方法,包括以下步骤:
S1:将所述瓷质砖的坯体原料按比例混合均匀,压制成为坯体;
S2:配置抛釉,抛釉的化学成分为:
SiO249%、Al2O314%、Fe2O30.3%、TiO20.2%、CaO 6.0%、MgO 1.0%、K2O 5%、Na2O2.0%、BaO 10%、ZrO20.2%、ZnO 10%、灼减量为5.5%,将砖坯保持在65℃喷淋于处理过的坯体上,喷淋流速为45秒,比重为 1.82g/mL,抛釉的用量为105g/370×680mm;
S3:经1250℃高温烧成2个小时后,依次进行一次粗抛光和二次精抛光的工序,最后打蜡处理。
实施例三:
本发明一种50度珠光全抛石材瓷质砖,所述瓷质砖的化学成分为:
SiO266.8%、Al2O319.3%、Fe2O30.9%、TiO20.5%、CaO 0.7%、MgO 1.1%、K2O3.2%、Na2O 2.6%、余量为杂质;灼减量为5.3%。
所述瓷质砖的坯体原料包括以重量百分比计的:
粘土20%、高铝砂9.2%、钾长石22%、钠长石23%、石英砂23%、生滑石2%、添加剂0.8%,且添加剂采用减水剂。
本发明同时还提供上述50度珠光全抛石材瓷质砖的制备方法,包括以下步骤:
S1:将所述瓷质砖的坯体原料按比例混合均匀,压制成为坯体;
S2:配置抛釉,抛釉的化学成分为:
SiO248%、Al2O313.5%、Fe2O30.25%、TiO20.15%、CaO 6.5%、MgO 0.8%、K2O4.5%、Na2O 1.8%、BaO 9.5%、ZrO20.15%、ZnO 9.5%、灼减量为5.3%,将砖坯保持在63℃喷淋于处理过的坯体上,喷淋流速为38秒,比重为1.82g/mL,抛釉的用量为105g/370×680mm;
S3:经1230℃高温烧成2个小时后,依次进行一次粗抛光和二次精抛光的工序,最后打蜡处理。
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (6)
1.一种50度珠光全抛石材瓷质砖,其特征在于,所述瓷质砖的化学成分为:
SiO266.5~67%、Al2O319.2~19.5%、Fe2O30.8~1.0%、TiO20.3~0.6%、CaO 0.5~0.8%、MgO 0.9~1.2%、K2O 3.0~3.4%、Na2O 2.5~2.8%、余量为杂质;
所述瓷质砖的坯体原料包括以重量百分比计的:
粘土15~25%、高铝砂8.0~10%、钾长石20~25%、钠长石15~20%、石英砂20~25%、生滑石1.0~2.5%、添加剂0.5~1.0%。
2.根据权利要求1所述的一种50度珠光全抛石材瓷质砖,其特征在于:所述瓷质砖的灼减量为5.2~5.5%。
3.一种权利要求1~2任一项所述的50度珠光全抛石材瓷质砖的制备方法,其特征在于,包括以下步骤:
S1:将所述瓷质砖的坯体原料按比例混合均匀,压制成为坯体;
S2:配置抛釉,将砖坯保持在60~65℃喷淋于处理过的坯体上,喷淋流速为30~45秒,比重为1.82±0.01g/mL,抛釉的用量为105±1g/370×680mm;
S3:经1220~1250℃高温烧成1.5~2个小时后,依次进行一次粗抛光和二次精抛光的工序,最后打蜡处理。
4.根据权利要求3所述的50度珠光全抛石材瓷质砖的制备方法,其特征在于,所述抛釉的化学成分为:
SiO247~49%、Al2O313~14%、Fe2O30.2~0.3%、TiO20.1~0.2%、CaO6.0~7.0%、MgO0.5~1.0%、K2O 4.0~5.0%、Na2O1.5~2.0%、BaO9.0~10%、ZrO20.1~0.2%、ZnO 9.0~10%。
5.根据权利要求4所述的50度珠光全抛石材瓷质砖的制备方法,其特征在于:所述抛釉的灼减量为5.2~5.5%。
6.根据权利要求1所述的50度珠光全抛石材瓷质砖的制备方法,其特征在于:所述添加剂为甲基纤维素、羧甲基纤维素、硅酸钠、减水剂中的任意一种或几种。
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