CN110040990A - A kind of preparation method and products thereof of carboaluminates cement - Google Patents
A kind of preparation method and products thereof of carboaluminates cement Download PDFInfo
- Publication number
- CN110040990A CN110040990A CN201910406982.7A CN201910406982A CN110040990A CN 110040990 A CN110040990 A CN 110040990A CN 201910406982 A CN201910406982 A CN 201910406982A CN 110040990 A CN110040990 A CN 110040990A
- Authority
- CN
- China
- Prior art keywords
- carboaluminates
- cement
- light
- calcium carbonate
- burned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/32—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/44—Burning; Melting
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to a kind of preparation methods and products thereof of carboaluminates cement, belong to novel gelled material technical field.The novel concrete mainly contains the component of following mass fraction: 1.0~8.0 parts of calcium carbonate, 2.0~9.0 parts of aluminium mineral material, 0.5~2.0 part of adjustable solidification agent, 0.1~0.3 part of reinforcing agent, before adjustable solidification agent and reinforcing agent wherein is added, calcium carbonate will be pre-mixed levigate in proportion and carry out light-burned with aluminium mineral material.The preparation method of carboaluminates cement of the invention is relatively easy, operation is easy, without high-temperature calcination, convenient for promoting, raw material sources are extensive, cheap simultaneously, the carbonic acid calcium substance such as lime stone is not required to a wide range of high-temperature calcination in preparation process, reduces CO2 emissions, reduces the pollution to environment.
Description
Technical field
The invention belongs to novel gelled material preparation fields, are related to the preparation method and its production of a kind of carboaluminates cement
Product.
Background technique
Agstone is the byproduct generated in Limestone mining and Machine-made Sand production, and main component is calcium carbonate, is had
The advantages that source is wide, grindability is high, stable components.At present all circles mainly using agstone as a kind of inert filler come using,
But lot of documents shows that agstone has cryptoactive.When agstone is spiked into portland cement, from
The calcium carbonate dissolved out in lime stone can be reacted with the aluminium phase hyrate in portland cement, generated calcium aluminate of hydrated carbon, thus changed
Kind substrate performance, but the rate of the reaction due to generating calcium aluminate of hydrated carbon under general condition is extremely slow, therefore do not obtain also temporarily wide
General application.
Synergistic effect based on calcium carbonate Yu aluminium phase material, current someone is by agstone and aluminum-containing phase supplementary cementitious material
It is used etc. compound substitution clinker, and has developed new product, such as limestone calcination clay cement.But since calcium carbonate belongs to difficult
Soluble substance, solubility is extremely low, and the aluminium phase content in common cementitious material is limited and poor activity, needs to be excited for a long time by alkali
Could slowly it come Aluminum, therefore currently for the chemical activity application and development of calcium carbonate, also in the stage of very shallow-layer.
The agstone even nanometer of the limit is such as ground using calcium carbonate superfine powder by current accessible process conditions
Calcium carbonate and the aluminium phase material that aluminum content is high and activity is big, such as high alumina cement, artificial synthesized monocalcium aluminate are mutually compound, and pass through
Light-burned processing, reacting between calcium carbonate and aluminium phase will be accelerated.
Therefore, it based on the cryptoactive of calcium carbonate, researches and develops a kind of using calcium aluminate of hydrated carbon as the novel of primary product
Cement will largely improve the resource utilization of agstone, and solve the huge energy consumption of traditional cement production bring and
CO2 emission problem.
Summary of the invention
In view of this, one of the objects of the present invention is to provide a kind of preparation methods of carboaluminates cement；Of the invention
The second purpose is to provide a kind of carboaluminates cement.
In order to achieve the above objectives, the invention provides the following technical scheme:
1, a kind of preparation method of carboaluminates cement, the described method comprises the following steps:
(1) it stocks up: according to mass parts meter, by 1.0~8.0 parts of calcium carbonate, 2.0~9.0 parts of aluminium mineral materials, 0.5~2.0
Part adjustable solidification agent and 0.1~0.3 part of reinforcing agent carry out weighing stock；
(2) it mixes: being ground after calcium carbonate described in step (1) is mixed with aluminium mineral material, forming specific surface area is 400
~700m2The mixture of/kg；
(3) light-burned processing: the powder after grinding in step (2) is placed in roaster and carries out light-burned processing, to light-burned place
It is cooled to room temperature after reason, storage is stand-by in dry conditions；
(4) it prepares carboaluminates cement: adjustable solidification agent described in step (1) being added to reinforcing agent light-burned in step (3)
Secondary mixing is carried out in treated powder, can be prepared by carboaluminates cement.
Preferably, calcium carbonate described in step (1) derives from lime stone, marble, calcite, light calcium carbonate powder or nanoscale
Calcium carbonate.
Preferably, aluminium mineral material described in step (1) is aluminate cement clinker, tricalcium aluminate or seven aluminic acids 12
At least one of calcium.
Preferably, adjustable solidification agent described in step (1) is dihydrate gypsum.
Preferably, reinforcing agent described in step (1) is calgon, triisopropanolamine, triethanolamine or hexafluoro silicon
At least one of sour magnesium.
Preferably, temperature light-burned described in step (3) is 300~600 DEG C, and the light-burned time is 20~60min.
2, carboaluminates cement prepared by the above method.
Preferably, the hydrated product of the carboaluminates cement contains calcium aluminate of hydrated carbon.
The beneficial effects of the present invention are:
1, of the invention to provide a kind of preparation method of carboaluminates cement, method uses light-burned technique, without height
Temperature calcining, convenient for promoting；The raw material sources used simultaneously are extensive, cheap, and the calcium carbonate such as lime stone in preparation process
Substance is not required to a wide range of high-temperature calcination, thus reduces CO2 emissions, reduces the pollution to environment.
2, the present invention uses calcium carbonate, aluminium mineral material for main raw material(s), enables the cement of preparation in use process
Middle formation hydrated product calcium aluminate of hydrated carbon, therefore make carboaluminates cement that there is early strength to develop fast and later strength not
The advantages of retraction, has a wide range of applications in the fields such as materials for wall, plastics or gum filler, building coating, fire resistant coating；
Other advantages, target and feature of the invention will be illustrated in the following description to a certain extent, and
And to a certain extent, based on will be apparent to those skilled in the art to investigating hereafter, Huo Zheke
To be instructed from the practice of the present invention.Target of the invention and other advantages can be realized by following specification and
It obtains.
Specific embodiment
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this specification
Other advantages and efficacy of the present invention can be easily understood for disclosed content.The present invention can also pass through in addition different specific realities
The mode of applying is embodied or practiced, the various details in this specification can also based on different viewpoints and application, without departing from
Various modifications or alterations are carried out under spirit of the invention.It should be noted that diagram provided in following embodiment is only to show
Meaning mode illustrates basic conception of the invention, and in the absence of conflict, the feature in following embodiment and embodiment can phase
Mutually combination.
Embodiment 1:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials, 0.50 part of adjustable solidification agent and
0.10 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from lime stone, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon and triisopropanolamine by 1.5:1.0 mass ratio；
(2) it mixes: 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
600m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control is existed
300 DEG C, the light-burned time is 40min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly, test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 2:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials, 0.50 part of adjustable solidification agent and
0.10 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from nanometer calcium carbonate, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is two water stones
Cream, reinforcing agent are made of hexafluorophosphoric acid magnesium and triisopropanolamine by 2.0:1.0 mass ratio；
(2) it mixes: 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
600m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control is existed
300 DEG C, the light-burned time is 20min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly, test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 3:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials, 0.50 part of adjustable solidification agent and
0.10 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from nanometer calcium carbonate, and aluminium mineral material presses 7.0 by aluminate cement clinker and tricalcium aluminate:
3.0 mass ratioes composition, adjustable solidification agent are dihydrate gypsum, and reinforcing agent presses 2.0:1.0 mass ratio by hexafluorophosphoric acid magnesium and triisopropanolamine
Composition；
(2) it mixes: 1.0 parts of calcium carbonate, 9.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
700m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control is existed
300 DEG C, the light-burned time is 20min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly, test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 4:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials, 0.75 part of adjustable solidification agent and
0.15 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from lime stone, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon and triisopropanolamine by 2.0:1.0 mass ratio；
(2) it mixes: 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
550m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control is existed
300 DEG C, the light-burned time is 50min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly, test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 5:
A kind of preparation method of carboaluminates cement, includes the following steps:
The carboaluminates cement of the present embodiment mainly contains following raw material: 3.5 parts of calcium carbonate, aluminic acid salt mine
6.5 parts of object, the mixing of above component, it is levigate after by light-burned, then mix 0.75 part of adjustable solidification agent, 0.15 part of reinforcing agent.
Wherein, the calcium carbonate derives from light calcium carbonate powder, and the aluminium mineral material is aluminate cement clinker, described
Adjustable solidification agent is dihydrate gypsum, and the reinforcing agent is made of magnesium fluosilicate and triisopropanolamine by 2.5:1.0 mass ratio.
Preparation method and preparation step are as follows:
(1) stock up: according to mass parts meter, by 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials, 0.75 part of adjustable solidification agent and
0.15 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from light calcium carbonate powder, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of magnesium fluosilicate and triisopropanolamine by 2.5:1 mass ratio；
(2) it mixes: 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
550m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control exists
400 DEG C, the light-burned time is 40min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 6:
A kind of preparation method of carboaluminates cement, includes the following steps:
The carboaluminates cement of the present embodiment mainly contains following raw material: 3.5 parts of calcium carbonate, aluminic acid salt mine
6.5 parts of object, the mixing of above component, it is levigate after by light-burned, then mix 0.75 part of adjustable solidification agent, 0.15 part of reinforcing agent.
Wherein, the calcium carbonate derives from nanometer grade calcium carbonate, and the aluminium mineral material is by aluminate cement clinker
It is formed with C 12 A 7 by 3.0:1.0 mass ratio, the adjustable solidification agent is dihydrate gypsum, and the reinforcing agent is by hexafluoro silicon
Sour magnesium and triisopropanolamine are formed by 2.5:1.0 mass ratio.
Preparation method and preparation step are as follows:
(1) stock up: according to mass parts meter, by 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials, 0.75 part of adjustable solidification agent and
0.15 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from light calcium carbonate powder, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of magnesium fluosilicate and triisopropanolamine by 2.5:1 mass ratio；
(2) it mixes: 3.5 parts of calcium carbonate, 6.5 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
600m2/kg；
(3) light-burned processing: the powder after grinding being placed in roaster and carries out light-burned processing, and light roasting temperature control exists
400 DEG C, the light-burned time is 20min, to be cooled to room temperature after light-burned, and is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 7:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials, 1.0 parts of adjustable solidification agents and
0.15 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from lime stone, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon and triisopropanolamine by 4.0:1.0 mass ratio；
(2) it mixes: 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
500m2/kg；
(3) light-burned processing: the powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control exists
500 DEG C, the light-burned time is 40min, to be cooled to room temperature after light-burned, and is stored in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 8:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials, 1.00 parts of adjustable solidification agents and
0.2 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from marble, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon, magnesium fluosilicate and triisopropanolamine by 2.0:1.5:1.0 mass ratio；
(2) it mixes: 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
500m2/kg；
(3) light-burned processing
Powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control is at 400 DEG C, the light-burned time
For 60min, to be cooled to room temperature after light-burned, and it is stored in spare in dry environment；
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 9:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials, 1.00 parts of adjustable solidification agents and
0.2 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from light calcium carbonate powder, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon, magnesium fluosilicate and triethanolamine by 2.0:1.5:1.5 mass ratio；
(2) it mixes: 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
500m2/kg；
(3) light-burned processing: the powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control exists
500 DEG C, the light-burned time is 40min, to be cooled to room temperature after light-burned, and is stored in dry environment.
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 10:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) stock up: according to mass parts meter, by 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials, 1.00 parts of adjustable solidification agents and
0.2 part of reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from light calcium carbonate powder, and aluminium mineral material is by aluminate cement clinker, tricalcium aluminate and seven aluminic acids ten
Dicalcium is formed by 6.0:3.0:2.0 mass ratio, and adjustable solidification agent is dihydrate gypsum, reinforcing agent by calgon, magnesium fluosilicate and
Triethanolamine is formed by 2.0:1.5:1.5 mass ratio；
(2) it mixes: 5.0 parts of calcium carbonate, 5.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
500m2/kg；
(3) light-burned processing: the powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control exists
500 DEG C, the light-burned time is 40min, to be cooled to room temperature after light-burned, and is stored in dry environment.
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 11:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) it stocks up: according to mass parts meter, by 6.0 parts of calcium carbonate, 4.0 parts of aluminium mineral materials, 1.5 parts of adjustable solidification agents and 0.2
Part reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from lime stone, and aluminium mineral material is aluminate cement clinker, and adjustable solidification agent is dihydrate gypsum, increases
Strong agent is made of calgon, magnesium fluosilicate and triisopropanolamine by 3.5:1.0:1.0 mass ratio；
(2) it mixes: 6.0 parts of calcium carbonate, 4.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
450m2/kg；
(3) light-burned processing: the powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control exists
600 DEG C, the light-burned time is 30min, to be cooled to room temperature after light-burned, and is stored in dry environment.
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Embodiment 12:
A kind of preparation method of carboaluminates cement, includes the following steps:
(1) it stocks up: according to mass parts meter, by 8.0 parts of calcium carbonate, 2.0 parts of aluminium mineral materials, 2.0 parts of adjustable solidification agents and 0.3
Part reinforcing agent carries out weighing stock；
Wherein calcium carbonate derives from lime stone, and aluminium mineral material is by aluminate cement clinker, tricalcium aluminate and seven aluminic acids ten
Dicalcium is formed by 6.0:3.0:2.0 mass ratio, and adjustable solidification agent is dihydrate gypsum, reinforcing agent by calgon, magnesium fluosilicate and
Triisopropanolamine is formed by 3.5:2.0:1.0 mass ratio；
(2) it mixes: 8.0 parts of calcium carbonate, 2.0 parts of aluminium mineral materials being ground to specific surface area after mixing is greater than and be equal to
400m2/kg；
(3) light-burned processing: the powder after will be levigate, which is placed in roaster, carries out light-burned processing, and light roasting temperature control exists
600 DEG C, the light-burned time is 30min, to be cooled to room temperature after light-burned, and is stored in dry environment.
(4) it prepares carboaluminates cement: load weighted adjustable solidification agent and enhancer component is added to light-burned treated powder
Secondary mixing is carried out in material, can be prepared by carboaluminates cement.
Appropriate mixing water is weighed by the 50% of carboaluminates cement weight, and is poured slowly into the container for filling dry mixing material
In, to slurry pouring molding after mixing evenly.Test specimen demoulding is placed on 20 ± 2 DEG C, conserves in relative humidity >=95% condition, and
According to GB/T 17671-1999, its compression strength at 3,28 days is tested respectively.
Reference examples 1:
Commercially available common high alumina cement keeps same molding and curing condition with preceding embodiment 1~12, and according to GB/T
17671-1999 tests its compression strength at 3,28 days respectively.
Reference examples 2:
Commercially available common 42.5 portland cement keeps same molding and curing condition with preceding embodiment 1~12, and according to
GB/T 17671-1999 tests its compression strength at 3,28 days respectively.
Specific test result is as shown in table 1:
Table 1 is the detected intensities of each embodiment and reference examples,
The comparison of the detected intensities of each embodiment of table 1 and reference examples
As shown in Table 1, the carboaluminates cement (embodiment 1~12) being prepared by means of the present invention is due to being easy
The hydrated product of calcium aluminate of hydrated carbon is formed, therefore the development of its early strength is fast, the cement being better than in the reference examples 1~2 of use,
And intensity of the carboaluminates cement in the later period is not in retraction, still has quite high intensity, in materials for wall, plastics
Or the fields such as gum filler, building coating, fire resistant coating have a wide range of applications.
In addition the preparation method of carboaluminates cement provided in the present invention is relatively easy, easy to operate, forges without high temperature
It burns, convenient for promoting, while raw material sources are extensive, cheap, and the carbonic acid calcium substance such as lime stone is not required to big model in preparation process
High-temperature calcination is enclosed, so that CO2 emissions are low, is reduced environmental pollution.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of the technical program, should all be covered in the present invention
Scope of the claims in.
Claims (8)
1. a kind of preparation method of carboaluminates cement, which is characterized in that the described method comprises the following steps:
(1) it stocks up: according to mass parts meter, by 1.0~8.0 parts of calcium carbonate, 2.0~9.0 parts of aluminium mineral materials, 0.5~2.0 part of tune
Solidifying agent and 0.1~0.3 part of reinforcing agent carry out weighing stock；
(2) mix: being ground after calcium carbonate described in step (1) is mixed with aluminium mineral material, formed specific surface area for 400~
700m2The mixture of/kg；
(3) light-burned processing: the powder after grinding in step (2) being placed in roaster and carries out light-burned processing, is tied to light-burned processing
It is cooled to room temperature after beam, storage is stand-by in dry conditions；
(4) it prepares carboaluminates cement: adjustable solidification agent described in step (1) and reinforcing agent is added to light-burned processing in step (3)
Secondary mixing is carried out in powder afterwards, can be prepared by carboaluminates cement.
2. a kind of preparation method of carboaluminates cement according to claim 1, which is characterized in that carbon described in step (1)
Sour calcium source is in lime stone, marble, calcite, light calcium carbonate powder or nanometer grade calcium carbonate.
3. a kind of preparation method of carboaluminates cement according to claim 1, which is characterized in that aluminium described in step (1)
Hydrochlorate mineral are at least one of aluminate cement clinker, tricalcium aluminate or C 12 A 7.
4. a kind of preparation method of carboaluminates cement according to claim 1, which is characterized in that adjusted described in step (1)
Solidifying agent is dihydrate gypsum.
5. a kind of preparation method of carboaluminates cement according to claim 1, which is characterized in that increase described in step (1)
Strong agent is at least one of calgon, triisopropanolamine, triethanolamine or magnesium fluosilicate.
6. a kind of preparation method of carboaluminates cement according to claim 1, which is characterized in that light described in step (3)
The temperature of burning is 300~600 DEG C, and the light-burned time is 20~60min.
7. a kind of carboaluminates cement being prepared by any one of claim 1~6 the method.
8. a kind of carboaluminates cement according to claim 7, which is characterized in that the hydrated product of the carboaluminates cement
Contain calcium aluminate of hydrated carbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910406982.7A CN110040990B (en) | 2019-05-16 | 2019-05-16 | Preparation method of carbonate aluminate cement and product thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910406982.7A CN110040990B (en) | 2019-05-16 | 2019-05-16 | Preparation method of carbonate aluminate cement and product thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110040990A true CN110040990A (en) | 2019-07-23 |
| CN110040990B CN110040990B (en) | 2021-07-06 |
Family
ID=67282201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910406982.7A Active CN110040990B (en) | 2019-05-16 | 2019-05-16 | Preparation method of carbonate aluminate cement and product thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110040990B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876108A (en) * | 2021-02-02 | 2021-06-01 | 郑州市建文特材科技有限公司 | Process for preparing high-strength sulphoaluminate cement by using red mud |
| CN114573258A (en) * | 2022-03-30 | 2022-06-03 | 重庆大学 | Material for carbon capture and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB632164A (en) * | 1939-04-25 | 1949-11-17 | Jean Charles Seailles | Method for the manufacture of aluminous cements, with special reference to white aluminous cement |
| RU2052407C1 (en) * | 1992-08-06 | 1996-01-20 | Научно-производственное объединение "Эмекат" | Method for production of high-alumina cement |
| CN102712548A (en) * | 2009-12-31 | 2012-10-03 | 卡勒拉公司 | Methods and compositions using calcium carbonate |
| CN109851260A (en) * | 2019-01-18 | 2019-06-07 | 武汉科技大学 | A kind of carbon containing aluminous cement and preparation method thereof |
-
2019
- 2019-05-16 CN CN201910406982.7A patent/CN110040990B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB632164A (en) * | 1939-04-25 | 1949-11-17 | Jean Charles Seailles | Method for the manufacture of aluminous cements, with special reference to white aluminous cement |
| RU2052407C1 (en) * | 1992-08-06 | 1996-01-20 | Научно-производственное объединение "Эмекат" | Method for production of high-alumina cement |
| CN102712548A (en) * | 2009-12-31 | 2012-10-03 | 卡勒拉公司 | Methods and compositions using calcium carbonate |
| CN109851260A (en) * | 2019-01-18 | 2019-06-07 | 武汉科技大学 | A kind of carbon containing aluminous cement and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李悦等: "铝酸盐矿物与碳酸钙的水化活性作用", 《河北理工学院学报》 * |
| 肖佳等: "C3A-CaSO4•2H2O-CaCO3-H2O体系水化性能的研究", 《建筑材料学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876108A (en) * | 2021-02-02 | 2021-06-01 | 郑州市建文特材科技有限公司 | Process for preparing high-strength sulphoaluminate cement by using red mud |
| CN114573258A (en) * | 2022-03-30 | 2022-06-03 | 重庆大学 | Material for carbon capture and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110040990B (en) | 2021-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Pu et al. | Investigation of carbonation depth and its influence on the performance and microstructure of MgO cement and PC mixes | |
| Rungchet et al. | Synthesis of low-temperature calcium sulfoaluminate-belite cements from industrial wastes and their hydration: Comparative studies between lignite fly ash and bottom ash | |
| CN103342481B (en) | A kind of filling in mine cementitious slurry and preparation method thereof | |
| EP3201156B1 (en) | Carbonatable calcium silicate cement composition containing hydraulic contaminants | |
| CN105330182B (en) | A kind of white quick setting and rapid hardening high belite sulphoaluminate cement clinker, using and its production technology | |
| CA2477709C (en) | High molecular weight additives for calcined gypsum and cementitious compositions | |
| JP5706417B2 (en) | Additives for hydraulic binders based on belite-calcium sulfoaluminate-ferrite clinker | |
| CN101367629B (en) | Manufacture of sulphur aluminate cements with electrolytic manganesium residue and method of manufacturing the same | |
| CN105753364B (en) | A kind of alkali-free high-strength concrete accelerator | |
| US7338990B2 (en) | High molecular weight additives for calcined gypsum and cementitious compositions | |
| CN104254502B (en) | The method using diethylene-triamine pentaacetic acid modification β plaster | |
| CN110451912A (en) | A kind of light thermal-insulation water proof type plastering ardealite material | |
| CN107056115B (en) | A kind of rush for ardealite based cementitious material coagulates type early strength agent and preparation method thereof | |
| CN106082720A (en) | A kind of high strength cement and preparation method thereof | |
| CN108191364A (en) | A kind of ardealite building gypsum products method of modifying | |
| CN102992804B (en) | Method for preparing aerated concrete by using phosphogypsum | |
| CN107207342A (en) | The hydraulic binder and its manufacture method of amorphous state low calcium content silicate | |
| CN102617058A (en) | Method for preparing hydraulic cementing material by utilizing sulfur fixation ash | |
| CN109437640A (en) | Composite modifier for ardealite building gypsum plaster | |
| EP3755639A1 (en) | Cement chemistries | |
| EP2822918A1 (en) | Hydraulic composition with low clinker content | |
| CN110040990A (en) | A kind of preparation method and products thereof of carboaluminates cement | |
| CN107555927A (en) | Half water filling phosphorous gypsum material and preparation method thereof | |
| CN112209640A (en) | Method for controlling setting time of cement produced by desulfurized gypsum | |
| CN102285773A (en) | Phosphogypsum-cement retarder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |