CN109593484A - Paster of surface anti sticking and the preparation method and application thereof - Google Patents
Paster of surface anti sticking and the preparation method and application thereof Download PDFInfo
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- CN109593484A CN109593484A CN201910097233.0A CN201910097233A CN109593484A CN 109593484 A CN109593484 A CN 109593484A CN 201910097233 A CN201910097233 A CN 201910097233A CN 109593484 A CN109593484 A CN 109593484A
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- layer
- paster
- pattern
- surface anti
- anti sticking
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 211
- 239000000758 substrate Substances 0.000 claims abstract description 67
- 238000003851 corona treatment Methods 0.000 claims abstract description 43
- 230000001464 adherent effect Effects 0.000 claims abstract description 41
- 239000012790 adhesive layer Substances 0.000 claims abstract description 31
- 239000003292 glue Substances 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 239000000853 adhesive Substances 0.000 claims description 15
- 230000001070 adhesive effect Effects 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000011247 coating layer Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010586 diagram Methods 0.000 abstract description 7
- 239000010408 film Substances 0.000 description 43
- 238000007639 printing Methods 0.000 description 31
- 230000000694 effects Effects 0.000 description 18
- 229920002545 silicone oil Polymers 0.000 description 14
- 238000001035 drying Methods 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 239000000428 dust Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 238000004528 spin coating Methods 0.000 description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 4
- 241001362551 Samba Species 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 239000012744 reinforcing agent Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
- C09J7/243—Ethylene or propylene polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention provides a kind of pasters of surface anti sticking, including adhesive layer, substrate layer, pattern layer, mute film layer and the adherent layer being stacked；Wherein, the first side surface of substrate layer is arranged in adhesive layer, for the paster of surface anti sticking to be pasted on target position；Substrate layer is used to support the paster of surface anti sticking；The second side surface of substrate layer is arranged in pattern layer；Mute film layer, coverage diagram pattern layer are used for bond graph pattern layer and adherent layer.The present invention also provides a kind of preparation methods of the paster of surface anti sticking, comprising: carries out sided corona treatment to a side surface of substrate layer；Pattern layer is formed in the side surface setting predetermined pattern by sided corona treatment of substrate layer；Glue coating forms mute film layer in pattern layer；It is coated with gloss oil in mute film layer, forms adherent layer after dry；In another side surface of substrate layer, adhesive layer is set.The present invention also provides a kind of yard of patch, the paster including surface anti sticking, wherein pattern layer uses pattern in 2 D code and/or bar code pattern.
Description
Technical field
The present invention relates to thin-film material technical fields, in particular it relates to the paster and its system of a kind of surface anti sticking
Preparation Method and application.
Background technique
Publicity, promote product or service when, businessman pass through frequently with a kind of mode be in billboard or building masonry wall
The post ads Deng on.When selling product, providing service, businessman can paste two dimensional code or bar code in order to care on product
Visitor buys or convenient for tracing product whereabouts to provide follow-up service.In addition, many restaurants can paste two dimensional code in dining table, sales counter
In order to which customer orders, thus simple flow, saving customer's time.But problem appear to is that advertisement, two dimensional code or bar code
Lid is pasted by others material for some reason Deng meeting, causes trouble to businessman and consumer.
Currently, a kind of technology generallyd use in terms of surface anti sticking is directly coated on polymer such as PVC patch
Silicone oil.Although this technology can reach preferable anti-sticking function in a short time, the technology is to work in practical applications
The requirement of skill is stringent, and silicone oil easily falls off from polymer surfaces.
All in all, there are no the materials with excellent surface anti-adhesion effects can satisfy market from demand.
Summary of the invention
Goal of the invention of the invention is the paster for providing a kind of surface anti sticking in view of the drawbacks of the prior art, the paster
The code of preparation method and the application paster pastes, and the surface anti sticking effect for solving the problems, such as the pasters such as code patch is poor.
On the one hand, the present invention provides a kind of pasters of surface anti sticking, including the adhesive layer, substrate layer, figure being stacked
Pattern layer, mute film layer and adherent layer；Wherein,
The first side surface of substrate layer is arranged in adhesive layer, for the paster of surface anti sticking to be pasted on target position；
Substrate layer is used to support the paster of surface anti sticking；
The second side surface of substrate layer is arranged in pattern layer；
Mute film layer, coverage diagram pattern layer are used for bond graph pattern layer and adherent layer.
Further, further include ground paper layer, be stacked the side surface in adhesive layer far from substrate layer, for by surface
Anti-sticking paster protects adhesive layer before being pasted on target position.
Further, substrate layer is that density is no more than 0.8g/cm2Synthetic paper.
Further, the first side surface and/or the second side surface of substrate layer have UV coating layer.
Further, the surface tension coefficient of substrate layer is more than or equal to 40 dynes per centimeters.
Further, mute film layer is that UV reinforces composite glue.
Further, the surface tension coefficient of mute film layer is more than or equal to 40 dynes per centimeters.
Further, adhesive layer is double-sided adhesive.
On the other hand, the present invention provides a kind of preparation methods of the paster of surface anti sticking, comprising:
Sided corona treatment is carried out to a side surface of substrate layer；
Predetermined pattern is set on the side surface by sided corona treatment of substrate layer and forms pattern layer；
Glue coating forms mute film layer in pattern layer；
It is coated with gloss oil in mute film layer, forms adherent layer after dry；With
Adhesive layer is set on another side surface of substrate layer.
Further, further includes: ground paper layer is set far from a side surface of substrate layer in adhesive layer.
Further, before the step of side surface to substrate layer carries out sided corona treatment, first to two sides of substrate layer
Surface is dusted processing.
Further, the power of sided corona treatment is 2 to 3 kilowatts, preferably 2.4 kilowatts.
Further, the step of predetermined pattern forms pattern layer is being set on the side surface by sided corona treatment of substrate layer
In, predetermined pattern is set by the way of printing and/or coding.
On the other hand, the present invention provides a kind of yard of patch, the pasters including surface anti sticking above-mentioned, wherein surface anti sticking
Paster pattern layer use pattern in 2 D code and/or bar code pattern.
Compared with the existing technology, the paster of surface anti sticking provided by the invention, the preparation method of the paster and application should
The advantages of code patch of paster are as follows:
The anti-adhesion effects of the paster of surface anti sticking of the invention are good, while also having wear-resisting, acid and alkali-resistance, Water-proof and oil-proof etc.
Effect.
Preparation method simple process of the invention is easily achieved.
Code patch of the invention is prepared using the paster of surface anti sticking, can effectively avoid being pasted by others when in use
The covering such as paper, advertisement.
Detailed description of the invention
Fig. 1 is the schematic diagram of the paster of the surface anti sticking of the first embodiment of the invention；
Fig. 2 is the schematic diagram of the paster of the surface anti sticking of second of embodiment of the invention；
Fig. 3 is the preparation method flow chart of the paster of surface anti sticking of the invention；
Fig. 4 is the schematic diagram of the two dimensional code paster of embodiment 1；
Fig. 5 is the schematic diagram of the two dimensional code paster of embodiment 2.
Specific embodiment
The present invention is done in detail by following specific embodiments for the purpose, feature and effect for fully understanding the present invention
Describe in detail bright, but the present invention is not restricted to this.
The paster of surface anti sticking
In a first aspect, the present invention provides a kind of pasters of surface anti sticking.In the first embodiment of the invention, such as
Shown in Fig. 1, the paster A of surface anti sticking of the invention includes the adhesive layer 1 being stacked, substrate layer 2, pattern layer 3, mute film layer 4
With adherent layer 5.
In the paster A of surface anti sticking of the invention, the first side surface of substrate layer 2 is arranged in adhesive layer 1, for making
Target position can be easily pasted on when with the paster A of surface anti sticking of the invention.Adhesive layer 1 can use any tool
There are the material of sticking effect, such as double-sided adhesive.
In the paster A of surface anti sticking of the invention, substrate layer 2 has the characteristics that density is high, stiffness is good, main to play branch
The effect of support.The material of substrate layer 2 is preferably synthetic paper, and more preferably density is no more than 0.8g/cm2Synthetic paper (such as 300
Gram or 350 grams of hard pearlescent synthetic paper), using the synthetic paper of the density, because of its light specific gravity, so substrate layer 2 can be made to have
Preferable rigidity.
In addition, the first side surface and/or the second side surface of substrate layer 2 preferably have UV coating layer.Different from traditional
Aqueous basecoat can be realized extraordinary printability using UV (ultraviolet light) coating, thus will not after being bent laminated film
There is folding line, and can be realized preferable ink attachment in spraying, printed patterns on substrate layer 2.Different materials have
Corresponding coating fluid, synthetic paper belong to PP (polypropylene) thin-film material, it is only necessary to buy film coated liquid, the present invention is to thin
Film coating fluid does not have particular/special requirement, it is only necessary to which by coating, a dyne value reaches 40 or more to coating fluid on the surface of the material.In reality
In the operation of border, those skilled in the art are able to carry out selection as needed.
Further, sided corona treatment can also be carried out to the second side surface of substrate layer 2, so that the surface tension of substrate layer 2
Coefficient is more than or equal to 40 dynes per centimeters, and then further enhances the printability (i.e. ink adhesion) of substrate layer 2.
In the paster A of surface anti sticking of the invention, the second side surface of substrate layer 2 is arranged in pattern layer 3, can be oil
Black pattern, for example, by using sun-proof ink, normal light is colour-fast according to 3 years or more.The sun-proof ink of any commercially available acquisition is used equally for
In the paster of surface anti sticking of the invention.
In the paster A of surface anti sticking of the invention, mute 4 coverage diagram pattern layer 3 of film layer, for bonding adherent layer 5 and pattern
Layer 3.Mute film layer 4 is the glue film of superstrong adhesive, with pattern layer 3 and substrate layer 2 it is compound after, be not in because viscosity not by force caused by
Paster layering and surrounding rise it is white (so-called is white, or print it is white, refer to printing in ink and print substance between adhesive force deficiency
Printing surface is caused white point occur).Also, the surface tension coefficient of mute film layer 4 is more than or equal to 40 dynes per centimeters, so that
The adhesive force of adherent layer 5 is good when adherent layer 5 being arranged on it.Preferably, mute film layer 4 can reinforce composite glue using UV, i.e.,
It is obtained after commercially available glue reinforcing agent mixing is added in commercially available glue.For example, will buy from Shenzhen Bu Ruite ink coating
The UV glue of Co., Ltd and purchase are from the UV glue of Shanghai Di Sen Chemical Co., Ltd. and purchase from the glue of Beijing University of Chemical Technology
The mixing of water reinforcing agent, in actual use, those skilled in the art can according to need to select suitably to match.It is a kind of optional
Proportional region be: 45%-60% (weight) is bought from UV glue, the 20%- of Shenzhen Bu Ruite ink coating Co., Ltd
35% (weight) buys the UV glue from Shanghai Di Sen Chemical Co., Ltd., 5%-20% (weight) is bought from Beijing University of Chemical Technology
Glue reinforcing agent.
In the paster A of surface anti sticking of the invention, adherent layer 5 covers mute film layer 4, has the function of anti-sticking, works as band
When having the adhesive paper of glue to be attached to 5 surface of adherent layer, which is easy to be torn or be easy to oneself to fall off.Adherent layer
5 are made of the high gloss oil of silicone oil, i.e., joined 25%-35% (weight) on the basis of the formula of conventional gloss oil (preferably
30%) the resistance to acid and alkali additive of silicone oil and 8%-13% (weight) (preferably 10%), general commercially available obtained silicone oil and resistance to
Acid-base property additive can be used in the present invention.Due to silicone oil height, so the surface of adherent layer 5 is especially smooth, it can
The effect of realizing anti-sticking effect well, while can also realizing acid and alkali-resistance, grease proofing, waterproof.
Currently, the film with anti-adhesion effects is usually provided with glue silicon oil membrane on its substrate in the market, but this is often reached
Less than the requirement used, it is mainly manifested in sticky not strong, easy blistering, has glue silicon oil membrane easy from substrate when use for a long time
It falls off.In the paster of surface anti sticking of the invention, adherent layer 5 and mute film layer 4 is respectively adopted, adherent layer 5 is anti-for surface
Viscous, mute film layer 4 is used to adherent layer 5 being firmly bonded in substrate.
Sided corona treatment is carried out to mute film layer 4 when mute film layer 4 is set, its surface tension coefficient is made to be more than or equal to 40 dynes/li
Rice, this mainly makes mute 4 surface irregularity of film layer, so that contact area be made to increase, the chemical reagent of adherent layer 5 is by electricity
Unit area usage amount in the mute film layer of dizzy processing is than the unit area usage amount in the mute film layer not Jing Guo sided corona treatment
It is bigger, while although the amount used increases, but apparent height does not increase that (highly increasing will cause instead because of height
Increase, coating is easy to become fragile, and the time, which has been grown, to be easy to fall off), so, by the irradiation of UV light source, light source can be very well
Penetrate reagent layer (i.e. adherent layer 5), reagent can sufficiently be reacted with mute film by heat, to be engaged more preferably, in turn
Adherent layer 5 is dried more thorough, and the cured effect of adherent layer 5 is more preferable, and then achievees the effect that avoid blistering and fall off.In addition,
The silicone oil of adherent layer 5 is relatively high, and by sufficient time levelling and suitable light intensity, surface will form very smooth silicon
Oil reservoir, silicone oil do not react with oil, water, acid, alkali etc., thus reach resistance to acid and alkali and other adhesive stickers adhere thereto after be easy it is de-
The effect fallen.Also, it is alternatively possible to carry out sided corona treatment to adherent layer 5, so that its surface tension coefficient is more than or equal to 40 and reach
Because/centimetre, silicone oil is then coated on a surface, and sided corona treatment can greatly increase the uptake of silicone oil, to be conducive to
Anti-adhesion effects are further increased, and are also beneficial to the transmission of UV light.Therefore, by the way that adherent layer 5 and mute film layer 4 is respectively adopted,
The problem of can either realizing excellent anti-adhesion effects, and can be avoided blistering and fall off.
Optionally, in order to be protected before the paster of surface anti sticking is pasted on target position to adhesive layer, such as Fig. 2
Shown, in second of embodiment of the invention, the paster A ' of surface anti sticking of the invention further includes ground paper layer 6, and setting exists
A side surface of the adhesive layer far from substrate layer.Ground paper layer 6 can be the paper of side surface anti sticking, such as release paper.
In the paster A ' of surface anti sticking of the invention, adhesive layer 1 and ground paper layer 6 commercially available can be obtained, such as gluing
Layer 1 and ground paper layer 6 can be the double-sided adhesive for the model 3M-55236 being combined with each other when purchase.
The present invention is not particularly limited each thickness degree of the paster of surface anti sticking and the length and width size of the paster,
In actual use, those skilled in the art can be rationally arranged as needed.
When using the paster A ' of surface anti sticking of the invention, first ground paper layer 6 is removed, then makes adhesive layer 1 towards mesh
The paster of surface anti sticking of the invention is pasted on target position by cursor position.
The preparation method of the paster of surface anti sticking
Second aspect, the present invention provides a kind of preparation methods of the paster of surface anti sticking, comprising: to the one of substrate layer 2
Side surface carries out sided corona treatment；Pattern layer 3 is formed in the side surface setting predetermined pattern by sided corona treatment of substrate layer 2；
Glue coating forms mute film layer 4 in pattern layer 3；It is coated with gloss oil in mute film layer 4, forms adherent layer 5 after dry；With in substrate
Adhesive layer 1 is set on another side surface of layer.
Optionally, in order to be protected before the paster of surface anti sticking is pasted on target position to adhesive layer 1, this hair
Bright preparation method further includes that ground paper layer 6 is arranged far from a side surface of substrate layer in adhesive layer 1.And optionally, adhesive layer 1
It is arranged simultaneously with ground paper layer 6.
Preferably, before sided corona treatment, preparation method of the invention further includes carrying out to two side surfaces of substrate layer 2
Dust removal process.
Therefore, in a preferred embodiment, as shown in figure 3, preparation method of the invention includes the following steps:
S101, surface dust: using dust-extraction unit by two side surfaces of substrate layer 2 dust and other impurity remove
Completely.
Sided corona treatment: S102 carries out sided corona treatment, sided corona treatment using a side surface of the corona treatment to substrate layer 2
Power be 2 to 3 kilowatts, preferably 2.4 kilowatts, the speed of service of corona treatment is no more than 70 ms/min.At corona
Reason can increase the side surface of substrate layer 2 in particular by the power for being higher than conventional sided corona treatment power (about 1.6 kilowatts)
Surface tension, and then increase printability, prevent from falling the effect of ink and film fall off.
Pattern layer is arranged in S103: forming pattern in the side surface setting predetermined pattern by sided corona treatment of substrate layer 2
Layer 3.Specifically, predetermined pattern can be set by the way of printing and/or coding.Wherein, printing e.g. flexographic printing five
Color, using flexible printing machine, by spot color printing, color is full, and text is three-dimensional and is less prone to color difference.Wherein, coding uses
Ink jet numbering machine, ink jet numbering machine are 150 ms/min for example, by using Fuji's Samba spray head, resolution ratio 1200DPI, speed, the figure of spray printing
Case is clear and without apparent convex sense, and qualification rate is high.Optionally, default to be arranged using printing and the united mode of coding
Pattern, for example, ink jet numbering machine and flexible printing machine combine online.
Mute film layer is arranged in S104: UV reinforcement composite glue being coated in pattern layer 3, obtains mute film layer 4 after dry.It applies
Cloth can be carried out using usual manners such as spraying, spin coatings, and drying can be using natural drying, drying, UV irradiation dry solidification etc.
Mode (preferably irradiated using UV, such as intermediate waves UV, such as wavelength 350nm to 450nm).Preferably, mute film layer 4 is obtained
Sided corona treatment is first carried out to it afterwards, design parameter is walked with S102, is then entered back into next step.
S105 is arranged adherent layer: gloss oil is coated in mute film layer 4, obtains adherent layer 5 after dry.Coating can use
The usual manners such as spraying, spin coating carry out, and drying can be carried out (excellent using modes such as natural drying, drying, UV irradiation dry solidifications
Choosing is irradiated using UV, such as intermediate waves UV, such as wavelength 350nm to 450nm).Preferably, obtain after adherent layer 5 first to its into
Row sided corona treatment, design parameter are walked with S102, are then coated silicone oil on its surface, are entered back into later in next step.
S106 is arranged adhesive layer and ground paper layer: double-sided adhesive being compounded in the not set pattern layer of substrate layer 2 by unwinding device
A side surface, wherein double-sided adhesive is not provided with release paper on the side compound with substrate layer 2.
Device involved in the above method, such as dust-extraction unit, corona treatment, ink jet numbering machine, flexible printing machine and unreel
Device etc., is conventional equipment, and those skilled in the art are able to carry out reasonable selection according to actual needs and use.
Code patch
The third aspect, the present invention provides a kind of yard of patch, the pasters including above-mentioned surface anti sticking, wherein surface anti sticking
The pattern layer of paster uses pattern in 2 D code and/or bar code pattern.
When preparing code patch of the invention, it is only necessary to set two dimension for the pattern layer of the paster of surface anti sticking of the invention
Code pattern and/or bar code.Wherein, two dimensional code can be QR two dimensional code, H grade two dimensional code etc..
Preferably, it is arranged after adherent layer, first carries out on-line checking, checks color, bar code and the adherent layer of printing
Deng whether qualified.
Preferably, it is arranged after adhesive layer and ground paper layer, carries out overlap, cross cutting, disconnected, individual detection, successively to obtain
The code obtained finally pastes product.
Therefore, the method preparation included the following steps can be used in code of the invention patch:
S201, surface dust: using dust-extraction unit by two side surfaces of substrate layer 2 dust and other impurity remove
Completely.
Sided corona treatment: S202 carries out sided corona treatment, sided corona treatment using a side surface of the corona treatment to substrate layer 2
Power be 2 to 3 kilowatts, preferably 2.4 kilowatts, the speed of service of corona treatment is no more than 70 ms/min.At corona
Reason can increase the side surface of substrate layer 2 in particular by the power for being higher than conventional sided corona treatment power (about 1.6 kilowatts)
Surface tension, and then increase printability, prevent from falling the effect of ink and film fall off.
Pattern layer is arranged in S203: forming pattern in the side surface setting predetermined pattern by sided corona treatment of substrate layer 2
Layer 3.Specifically, predetermined pattern can be set by the way of printing and/or coding.Wherein, printing e.g. flexographic printing five
Color, using flexible printing machine, by spot color printing, color is full, and text is three-dimensional and is less prone to color difference.Wherein, coding uses
Ink jet numbering machine, ink jet numbering machine are 150 ms/min for example, by using Fuji's Samba spray head, resolution ratio 1200DPI, speed, the figure of spray printing
Case is clear and without apparent convex sense, and qualification rate is high.Optionally, default to be arranged using printing and the united mode of coding
Pattern, for example, ink jet numbering machine and flexible printing machine combine online.
Mute film layer is arranged in S204: UV reinforcement composite glue being coated in pattern layer 3, obtains mute film layer 4 after dry.It applies
Cloth can be carried out using usual manners such as spraying, spin coatings, and drying can be using natural drying, drying, UV irradiation dry solidification etc.
Mode (preferably irradiated using UV, such as intermediate waves UV, such as wavelength 350nm to 450nm).Preferably, mute film layer 4 is obtained
Sided corona treatment is first carried out to it afterwards, design parameter is walked with S202, is then entered back into next step.
S205 is arranged adherent layer: gloss oil is coated in mute film layer 4, obtains adherent layer 5 after dry.Coating can use
The usual manners such as spraying, spin coating carry out, and drying can be carried out (excellent using modes such as natural drying, drying, UV irradiation dry solidifications
Choosing is irradiated using UV, such as intermediate waves UV, such as wavelength 350nm to 450nm).Preferably, obtain after adherent layer 5 first to its into
Row sided corona treatment, design parameter are walked with S202, are then coated silicone oil on its surface, are entered back into later in next step.
On-line checking: S206 checks whether color, two dimensional code and/or the bar code of printing qualified and whether is adherent layer
There is bubble.
S207 is arranged adhesive layer and ground paper layer: double-sided adhesive being compounded in the not set pattern layer of substrate layer 2 by unwinding device
A side surface, wherein double-sided adhesive is not provided with release paper on the side compound with substrate layer 2.
Overlap: S208 is cut away laminated film both sides redundance by carving knife.
S209, cross cutting: being die cut using graver, and cross cutting, which is subject to, does not switch to ground paper layer.
S210, disconnected: laminated film is cut into qualified finished size using disconnected knife by size as required.
Individual detection: S211 carries out individual detection using label rewinding checking machine DH-FJ6033, rejects and lack in the presence of printing
It falls into, the substandard product for the defects of color color difference, bar code grade are unqualified, repeated code is rejected.
S212, packaging: packing as required and mark, and traces convenient for the later period.
Embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.
Embodiment 1
A kind of two dimensional code paster is present embodiments provided, as shown in figure 4, size is 65 × 100 millimeters (4.0R fillets), two
Tie up yardstick cun as shown in Figure 4.
Preparation method is:
Surface dust: using dust-extraction unit by the dust and other impurity in the both side surface of 300 grams of hard pearlescent synthetic papers
Removal is clean.
Sided corona treatment: sided corona treatment, corona are carried out using a side surface of the corona treatment to 300 grams of hard pearlescent synthetic papers
The power of processing is 2.4 kilowatts, and the speed of service of corona treatment is no more than 70 ms/min.
Setting pattern layer: according to two dimensional code size shown in Fig. 4 and position use Fuji's Samba spray head (resolution ratio for
1200DPI) with 150 ms/min of speed, spray printing is two-dimentional on the side surface by sided corona treatment of 300 grams of hard pearlescent synthetic papers
Code.
Mute film layer is set: UV reinforcement composite glue being sprayed in pattern layer and is dried to obtain mute film layer.
Adherent layer is arranged: by silicone oil be 30% and the gloss oil of resistance to acid and alkali additive level 10% is sprayed on mute film layer
On, adherent layer is obtained after dry.
On-line checking: check whether color, two dimensional code and/or the bar code of printing are qualified and whether adherent layer has gas
Bubble.Qualified product enters in next step.
Setting adhesive layer and ground paper layer: 3M55236 double-sided adhesive is compounded in by the not set pattern of substrate layer by unwinding device
One side surface of layer.
Overlap: compound good material both sides redundance is cut away by carving knife.
Cross cutting: according to the size of 65 × 100 millimeters (4.0R fillet), being die cut using graver, is die cut not switch to
Subject to ground paper layer.
Disconnected: qualified finished product is cut by a disconnected knife.
Individual detection: individual detection is carried out using label rewinding checking machine DH-FJ6033, there are printing defects, face for rejecting
The substandard product for the defects of color color difference, bar code grade be unqualified, repeated code is rejected.
Packaging: packing qualified products and marked, and traces convenient for the later period.
Embodiment 2
Another two dimensional code paster is present embodiments provided, as shown in figure 5, size is 140 × 210 millimeters of (8.0R circles
Angle), two dimensional code size and literal field size are as shown in Figure 5.
The basic phase of preparation method of the two dimensional code paster of the preparation method and embodiment 1 of the two dimensional code paster of the present embodiment
Together, difference is: adjusting accordingly to paster size and two dimensional code size, and uses coding in the step of pattern layer is arranged
Machine and flexible printing machine combine spray printing two dimensional code and printing word simultaneously online；Obtain first using after mute film layer 4 2.4 kilowatts of function
Rate carries out sided corona treatment；Sided corona treatment is first carried out using 2.4 kilowatts of power after obtaining adherent layer 5, is then coated on its surface
One layer of silicone oil, carries out on-line checking again later.
Measure of merit:
10 samples are chosen from paster qualified product prepared by embodiment 1 and constitute first group of sample, are prepared from embodiment 2
10 samples are chosen in paster qualified product and constitute second group of sample, carry out measure of merit:
1. it is primary using detection in ageing device every 300 hours according to ASTM G155 standard, as the result is shown after 1500 hours,
Two groups of sample standard deviations do not occur intermediate peeling problem.
2. choose 3 kinds of different commercially available pasters (completes the packaging of color printing brush Co., Ltd, Guangzhou shellfish purchased from Dongguan City respectively
Print Co., Ltd, Cangnan Xian Longgang Rui Yue paper-plastic products factory) anti-adhesion effects test is carried out to first and second group of sample, as a result:
First group of sample: a sample occurs in the paster test for completing color printing brush Co., Ltd using Dongguan City slight
Adhesion, paster can be removed by gently being torn with hand；
Second group of sample: not occurring adhesion phenomenon, and above-mentioned three kinds of commercially available pasters can not be pasted onto each of second group of sample
Paster surface.
Finally it should be noted that: the above enumerated are only specific embodiments of the present invention son, the technology of certain this field
Personnel can be modified to the present invention and modification, if these modifications and variations belong to the claims in the present invention and its equivalent skill
Within the scope of art, it is considered as protection scope of the present invention.
Claims (10)
1. a kind of paster of surface anti sticking, which is characterized in that including the adhesive layer, substrate layer, pattern layer, mute film layer being stacked
And adherent layer；Wherein,
The first side surface of the substrate layer is arranged in the adhesive layer, for the paster of the surface anti sticking to be pasted on mesh
Cursor position；
The substrate layer is used to support the paster of the surface anti sticking；
The second side surface of the substrate layer is arranged in the pattern layer；
The mute film layer, covers the pattern layer, for bonding the pattern layer and the adherent layer.
2. the paster of surface anti sticking according to claim 1, which is characterized in that further include ground paper layer, be stacked in institute
A side surface of the adhesive layer far from the substrate layer is stated, for before the paster of the surface anti sticking is pasted on target position
The adhesive layer is protected.
3. the paster of surface anti sticking according to claim 1, which is characterized in that the substrate layer is that density is no more than
0.8g/cm2Synthetic paper.
4. the paster of surface anti sticking according to claim 1, which is characterized in that the first side surface of the substrate layer and/
Or second side surface have UV coating layer.
5. the paster of surface anti sticking according to claim 1, which is characterized in that the surface tension coefficient of the substrate layer is big
In equal to 40 dynes per centimeters.
6. the paster of surface anti sticking according to claim 1, which is characterized in that the mute film layer is that UV reinforces compound adhesive
Water.
7. the paster of surface anti sticking according to claim 1, which is characterized in that the surface tension coefficient of the mute film layer is big
In equal to 40 dynes per centimeters.
8. the paster of surface anti sticking according to claim 1, which is characterized in that the adhesive layer is double-sided adhesive.
9. the preparation method of the paster of the described in any item surface anti stickings of claim 1-8 characterized by comprising
Sided corona treatment is carried out to a side surface of substrate layer；
Predetermined pattern is set on the side surface by sided corona treatment of substrate layer and forms pattern layer；
Glue coating forms mute film layer in pattern layer；
It is coated with gloss oil in mute film layer, forms adherent layer after dry；With
Adhesive layer is set on another side surface of substrate layer.
10. a kind of yard of patch, the paster including the described in any item surface anti stickings of claim 1-8, wherein the surface anti sticking
The pattern layer of paster uses pattern in 2 D code and/or bar code pattern.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910097233.0A CN109593484A (en) | 2019-01-31 | 2019-01-31 | Paster of surface anti sticking and the preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910097233.0A CN109593484A (en) | 2019-01-31 | 2019-01-31 | Paster of surface anti sticking and the preparation method and application thereof |
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| Publication Number | Publication Date |
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| CN109593484A true CN109593484A (en) | 2019-04-09 |
Family
ID=65967115
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910097233.0A Pending CN109593484A (en) | 2019-01-31 | 2019-01-31 | Paster of surface anti sticking and the preparation method and application thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110126501A (en) * | 2019-06-28 | 2019-08-16 | 芜湖市祥和包装有限公司 | A kind of preparation method of durability adhesive label |
| CN110277012A (en) * | 2019-06-20 | 2019-09-24 | 雷特玛(合肥)感压粘合涂层材料有限公司 | A kind of bottomless paper label and preparation method thereof |
| CN111942049A (en) * | 2020-08-28 | 2020-11-17 | 河源市博越彩色印刷有限公司 | Printing method of adhesive label |
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Application publication date: 20190409 |