CN108905305A - Organic silicon defoamer and preparation method thereof - Google Patents
Organic silicon defoamer and preparation method thereof Download PDFInfo
- Publication number
- CN108905305A CN108905305A CN201811088553.1A CN201811088553A CN108905305A CN 108905305 A CN108905305 A CN 108905305A CN 201811088553 A CN201811088553 A CN 201811088553A CN 108905305 A CN108905305 A CN 108905305A
- Authority
- CN
- China
- Prior art keywords
- parts
- organic silicon
- silicon defoamer
- defoamer
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 49
- 239000010703 silicon Substances 0.000 title claims abstract description 49
- 239000013530 defoamer Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 28
- -1 polysiloxanes Polymers 0.000 claims abstract description 27
- 239000003921 oil Substances 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 20
- 239000006071 cream Substances 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 239000010954 inorganic particle Substances 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 14
- 229920000053 polysorbate 80 Polymers 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 238000004945 emulsification Methods 0.000 claims description 3
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000012153 distilled water Substances 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 239000012875 nonionic emulsifier Substances 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 abstract description 14
- 239000002518 antifoaming agent Substances 0.000 abstract description 11
- 239000006260 foam Substances 0.000 abstract description 4
- 230000005764 inhibitory process Effects 0.000 abstract description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract description 2
- 230000003254 anti-foaming effect Effects 0.000 abstract 1
- 239000006210 lotion Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 13
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 229920005573 silicon-containing polymer Polymers 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 230000001804 emulsifying effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000008119 colloidal silica Substances 0.000 description 3
- 239000003517 fume Substances 0.000 description 3
- 238000000053 physical method Methods 0.000 description 3
- QJYNLBLWRIUXTG-UHFFFAOYSA-N FC(F)(F)[Si]CCC Chemical compound FC(F)(F)[Si]CCC QJYNLBLWRIUXTG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Colloid Chemistry (AREA)
- Degasification And Air Bubble Elimination (AREA)
Abstract
The present invention provides a kind of organic silicon defoamers, based on 1000 parts by weight of whole components, 50-500 parts of trifluompropyl methyl polysiloxanes；0-100 parts of hydroxy silicon oils；The inorganic particle of the 3-15 parts of groups containing reactive surfaces；5-15 parts of emulsifiers；0.1-1 parts of thickeners；1-10 parts of dispersing agents；Surplus is water.Specific steps：Organosilicon antifoam composition and white carbon black are mixed to get silicon cream.Silicon cream, emulsifier, water, thickener, dispersing agent are prepared into organic silicon defoamer lotion.Trifluompropyl methyl polysiloxane has lower surface energy, and therefore, for the defoaming agent compared with the preparation of conventional methyl silicone oil, the addition of trifluompropyl methyl polysiloxane reduces the surface tension of antifoaming system, the defoaming of the defoaming agent of raising and foam inhibition function.Again because methyl-silicone oil has certain dissolubility in oily phase, the addition of fluorohydrocarbon base is so that trifluompropyl methyl polysiloxane not readily dissolves the use system range for increasing organic silicon defoamer in oil-based system.
Description
Technical field
The present invention relates to a kind of defoaming agent and preparation method thereof, in particular to a kind of organic silicon defoamer and its preparation side
Method.
Background technique
It is easy to produce in textile sizing, the production process of the industries such as food fermentation, biological medicine, petroleum, chemical industry, coating
Unwanted bubbles can seriously affect the quality of production efficiency and product if eliminating these unwanted bubbles not in time.It defoams at present
Method mainly has physical method and chemical method.Physical method mainly include change bubbling system temperature, rapidly change system pressure,
The two sides of bubble film are made to generate pressure difference.Chemical rule is that defoaming agent is added into system, by the skin covering of the surface for changing foam
Intensity and surface layer tension, to achieve the effect that lather collapse.Physical method can only the short time removing unwanted bubbles, therefore work
Chemical method defoaming is commonly used in industry.Common chemical method is that defoaming agent, organic silicon defoamer and general defoaming agent are added into system
Small compared to surface tension, defoaming capacity is strong, and chemical stability is high, is not easy to chemically react with frothing media, so extensive
Using.
CN103877755A provides a kind of organic silicon defoamer and preparation method thereof, mainly by dimethyl silicone polymer
With hydroxy silicon oil as main defoaming substance, then organic silicon defoamer will be obtained after silicone oil emulsification again.This kind of organosilicon defoaming
It is dimethyl silicone polymer that agent, which mainly defoams substance, although dimethyl silicone polymer have lower surface can, defoaming effect compared with
It is good, but there are still surface can lower, defoaming effect more preferably defoam substance, and polydimethyl siloxane fluid has one in oil-based system
Fixed dissolubility, therefore oil-based system cannot be used in.
Summary of the invention
For dimethyl silicone polymer, the organic silicon defoamer of trifluompropyl methyl polysiloxane preparation has more
Low surface energy, therefore defoam more preferable with suds suppressing properties.Meanwhile fluorine-containing alkyl is insoluble in oil-based system, this makes poly- trifluoropropyl
Methyl siloxane defoaming agent can preferably be used in oil-based system.To achieve the above object, present invention employs following skills
Art scheme：
A kind of organic silicon defoamer, based on 1000 parts by weight of whole components, 50-500 parts of trifluompropyl methyl polysiloxanes；
0-100 parts of hydroxy silicon oils；The inorganic particle of the 3-15 parts of groups containing reactive surfaces；5-15 parts of emulsifiers；0.1-1 parts of thickeners；
1-10 parts of dispersing agents；Surplus is water.
Trifluompropyl methyl polysiloxane viscosity is 100mPa.s~1000mPa.s.
Hydroxy silicon oil viscosity is 50mPa.s~500mPa.s.
The inorganic particle of the group containing reactive surfaces is gas-phase silica, precipitated silica, aerosil, dioxy
Change one of the modified titanium dioxide of titanium, N- (preferably N doping be titanium dioxide total amount 0.5-1%), quartz or
It is several.
Emulsifier is nonionic emulsifier.Select Span-80, Tween-80, one or more of in NP-4, NP-10, cream
HLB=5~15 of agent.
Thickener is selected from one of polyacrylate, polyvinyl alcohol, Sodium Polyacrylate.
Dispersing agent is selected from one of methyl anyl alcohol, cellulose derivative, guar gum
The wet concentration selects one kind of distilled water, deionized water, ultrapure water
A kind of preparation method of organic silicon defoamer, including steps are as follows：
(1) trifluompropyl methyl polysiloxane and hydroxy silicon oil are added in a kettle, then is added and contains into reaction kettle
The inorganic particle of reactive surfaces group, temperature are 100-150 DEG C, mixing speed 100-500r/min, stir 2-4h, are made
Silicon cream.
(2) it takes the silicon cream prepared to be placed in reaction kettle, emulsifier, mixing speed 2500- is added while stirring
3500r/min.Water, thickener and dispersing agent, 60-80 DEG C of emulsification 30-60min is then added and obtains organic silicon defoamer.
Compared with the prior art, the present invention has the advantages that：
(1) trifluompropyl methyl polysiloxane has lower surface energy than conventional use of dimethyl silicone polymer, because
The addition of this trifluompropyl methyl polysiloxane is so that organic silicon defoamer has preferably defoaming and foam inhibition effect.
(2) organic silicon defoamer of dimethyl silicone polymer preparation has certain dissolubility in oily phase, therefore cannot make
For oil-based system, and the addition of fluoropropyl reduces solvent borne of the trifluompropyl methyl polysiloxane in oil-based system, because
The defoaming agent of this trifluompropyl methyl polysiloxane preparation can be used in oil-based system.
(3) trifluompropyl methyl polysiloxane compound with hydroxy silicon oil by the present invention improves defoaming and foam inhibition effect
Fruit reduces costs for the defoaming agent of trifluompropyl methyl polysiloxane preparation is used alone.
Specific embodiment
The technical solution in the present invention is further illustrated below with reference to embodiment.
Embodiment 1
(1) 90g trifluompropyl methyl polysiloxane and 5g hydroxy silicon oil are placed in reaction kettle, poly- trifluoro propyl methyl silicon
The viscosity of oxygen alkane is 500mPa.s, and temperature is set as 120 DEG C, mixing speed 300r/min, then is slowly added into silicone oil
5g fume colloidal silica (specific surface area 450m2/ g), 3h is stirred, silicon cream is made.
(2) the 100g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 65 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 42.5g, and Tween-80 quality is 27.5g.The emulsifier compounded is slowly added to
In silicone oil, the revolving speed of mulser is that the water of 824g is slowly added into reaction kettle by 3000r/min after emulsifier adds,
0.5g polyvinyl alcohol is then added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Embodiment 2
(1) 84g trifluompropyl methyl polysiloxane and 8g hydroxy silicon oil are placed in reaction kettle, poly- trifluoro propyl methyl silicon
The viscosity of oxygen alkane is 500mPa.s, and temperature is set as 150 DEG C, mixing speed 300r/min, then is slowly added into silicone oil
(wherein N doping is the 0.8% of titanium dioxide total amount, specific surface area 300m to 8g N- modified titanium dioxide2/ g), stirring
Silicon cream is made in 3h.
(2) the 100g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 70 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 42.5g, and Tween-80 quality is 27.5g.The emulsifier compounded is slowly added to
In silicone oil, the revolving speed of mulser is that the water of 824g is slowly added into reaction kettle by 3000r/min after emulsifier adds,
0.5g polyvinyl alcohol is then added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Embodiment 3
(1) 85g trifluompropyl methyl polysiloxane and 10g hydroxy silicon oil are placed in reaction kettle, poly- trifluoro propyl methyl
Siloxanes viscosity is 500mPa.s, and the viscosity of hydroxy silicon oil is 100mPa.s, and temperature is set as 120 DEG C, mixing speed 300r/
Min, then 5g titanium dioxide (specific surface area 350m is slowly added into silicone oil2/ g), 3h is stirred, silicon cream is made.
(2) the 100g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 65 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 42.5g, and Tween-80 quality is 27.5g.The emulsifier compounded is slowly added to
In silicone oil, the revolving speed of mulser is that the water of 824g is slowly added into reaction kettle by 3000r/min after emulsifier adds,
0.5g polyvinyl alcohol is then added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Embodiment 4
(1) 170g trifluompropyl methyl polysiloxane and 20g hydroxy silicon oil are placed in reaction kettle, poly- trifluoro propyl methyl
Siloxanes viscosity is 500mPa.s, and the viscosity of hydroxy silicon oil is 100mPa.s, and temperature is set as 120 DEG C, mixing speed 300r/
Min, then 10g hydrophobic silicon dioxide aerogel (specific surface area 550m is slowly added into silicone oil2/ g), stir 3h, system
Obtain silicon cream.
(2) the 200g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 65 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 85g, and Tween-80 quality is 55g.The emulsifier compounded is slowly added to silicone oil
In, the revolving speed of mulser is that the water of 654g is slowly added into reaction kettle, then by 3000r/min after emulsifier adds
0.5g polyvinyl alcohol is added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Comparative example 1
(1) 95g dimethyl silicone polymer is placed in reaction kettle, the viscosity of dimethyl silicone polymer is 500mPa.s, temperature
Degree is set as 120 DEG C, mixing speed 300r/min, then 5g fume colloidal silica is slowly added into silicone oil, stirs 3h, system
Obtain silicon cream.
(2) the 100g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 65 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 42.5g, and Tween-80 quality is 27.5g.The emulsifier compounded is slowly added to
In silicone oil, the revolving speed of mulser is that the water of 824g is slowly added into reaction kettle by 3000r/min after emulsifier adds,
0.5g polyvinyl alcohol is then added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Comparative example 2
(1) 190g dimethyl silicone polymer is placed in reaction kettle, the viscosity of dimethyl silicone polymer is 500mPa.s, temperature
Degree is set as 120 DEG C, mixing speed 300r/min, then 10g fume colloidal silica is slowly added into silicone oil, stirs 3h,
Silicon cream is made.
(2) the 200g silicon cream prepared is taken to be placed in reaction kettle, reaction temperature is set as 65 DEG C, by Span-80 and tween-
80 are compounded, and wherein Span-80 quality is 85g, and Tween-80 quality is 55g.The emulsifier compounded is slowly added to silicone oil
In, the revolving speed of mulser is that the water of 654g is slowly added into reaction kettle, then by 3000r/min after emulsifier adds
0.5g polyvinyl alcohol is added, 5.5g methyl anyl alcohol obtains organic silicon defoamer after emulsifying 40min.
Defoaming agent of the invention is detected, and key data is as follows：
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the scope of the claims of invention.
Claims (9)
1. a kind of organic silicon defoamer, it is characterised in that：Based on 1000 parts by weight of whole components, 50-500 parts of poly- trifluoro propyl first
Radical siloxane；1-10 parts of hydroxy silicon oils；The inorganic particle of the 3-15 parts of groups containing reactive surfaces；5-15 parts of emulsifiers；0.1-1 parts
Thickener；1-10 parts of dispersing agents；Surplus is water.
2. organic silicon defoamer as described in claim 1, it is characterised in that：Trifluompropyl methyl polysiloxane viscosity is
100mPa.s~1000mPa.s.
3. organic silicon defoamer as described in claim 1, it is characterised in that：Hydroxy silicon oil viscosity be 50mPa.s~
500mPa.s。
4. organic silicon defoamer as described in claim 1, it is characterised in that：The inorganic particle of the group containing reactive surfaces is gas
One of phase white carbon black, precipitated silica, aerosil, titanium dioxide, N modified titanium dioxide, quartz or
It is several.
5. organic silicon defoamer as described in claim 1, it is characterised in that：Emulsifier is nonionic emulsifier, including department
Class -80, Tween-80, one or more of in NP-4, NP-10, HLB=5 ~ 15 of emulsifier.
6. organic silicon defoamer as described in claim 1, it is characterised in that：The thickener is selected from polyacrylate, gathers
Any one in vinyl alcohol, Sodium Polyacrylate.
7. organic silicon defoamer as described in claim 1, it is characterised in that：The dispersing agent is selected from methyl anyl alcohol, cellulose
Any one in derivative, guar gum.
8. organic silicon defoamer as described in claim 1, it is characterised in that：The wet concentration selects distilled water, deionized water, ultrapure
Any one in water.
9. the preparation method of the organic silicon defoamer as described in claim 1-8 appoints item, including steps are as follows：
（1）Trifluompropyl methyl polysiloxane and hydroxy silicon oil are added in a kettle, then is added into reaction kettle containing reaction
Property surface group inorganic particle, temperature be 100-150 DEG C, mixing speed 100-500r/min, stir 2-4h, be made silicon
Cream；
（2）It takes the silicon cream prepared to be placed in reaction kettle, emulsifier, mixing speed 2500-3500r/ is added while stirring
Min is then added water, thickener and dispersing agent, 60-80 DEG C of emulsification 30-60min and obtains organic silicon defoamer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811088553.1A CN108905305A (en) | 2018-09-18 | 2018-09-18 | Organic silicon defoamer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811088553.1A CN108905305A (en) | 2018-09-18 | 2018-09-18 | Organic silicon defoamer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108905305A true CN108905305A (en) | 2018-11-30 |
Family
ID=64408169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811088553.1A Pending CN108905305A (en) | 2018-09-18 | 2018-09-18 | Organic silicon defoamer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108905305A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110280051A (en) * | 2019-07-09 | 2019-09-27 | 四川省蜀爱新材料有限公司 | A kind of low silicon defoaming agent |
| CN112774260A (en) * | 2020-12-17 | 2021-05-11 | 新疆水处理工程技术研究中心有限公司 | Polyether defoaming agent and preparation method thereof |
| CN113441101A (en) * | 2020-03-26 | 2021-09-28 | 上海汇友消防技术有限公司 | Novel disposal method for easily-fogging chlorine-containing compound leakage |
| CN114011117A (en) * | 2021-11-29 | 2022-02-08 | 淄博爱迪毅环保技术有限公司 | Defoaming agent and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0905314A2 (en) * | 1997-09-19 | 1999-03-31 | Henkel KGaA | Use of special preparations as defoamers |
| CN102491679A (en) * | 2011-12-02 | 2012-06-13 | 大连化工研究设计院 | Method for preparing defoamer for cement mortar containing rubber emulsion |
| CN103877755A (en) * | 2014-03-11 | 2014-06-25 | 苏州恒康新材料有限公司 | Organic silicon defoaming agent and preparation method thereof |
| CN105384937A (en) * | 2015-12-16 | 2016-03-09 | 江南大学 | Preparation method of hydroxypropylfluorosilicone |
| CN106661496A (en) * | 2014-06-03 | 2017-05-10 | 国际壳牌研究有限公司 | Defoaming agent and associated methods of use |
| CN107737467A (en) * | 2017-10-23 | 2018-02-27 | 付海明 | Delayed coking antifoaming agent and its production and use |
| CN108159738A (en) * | 2017-12-29 | 2018-06-15 | 山东东岳有机硅材料股份有限公司 | It is a kind of for emulsion type fluorine-containing organic silicon defoamer of oil water two phase system and preparation method thereof |
-
2018
- 2018-09-18 CN CN201811088553.1A patent/CN108905305A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0905314A2 (en) * | 1997-09-19 | 1999-03-31 | Henkel KGaA | Use of special preparations as defoamers |
| CN102491679A (en) * | 2011-12-02 | 2012-06-13 | 大连化工研究设计院 | Method for preparing defoamer for cement mortar containing rubber emulsion |
| CN103877755A (en) * | 2014-03-11 | 2014-06-25 | 苏州恒康新材料有限公司 | Organic silicon defoaming agent and preparation method thereof |
| CN106661496A (en) * | 2014-06-03 | 2017-05-10 | 国际壳牌研究有限公司 | Defoaming agent and associated methods of use |
| CN105384937A (en) * | 2015-12-16 | 2016-03-09 | 江南大学 | Preparation method of hydroxypropylfluorosilicone |
| CN107737467A (en) * | 2017-10-23 | 2018-02-27 | 付海明 | Delayed coking antifoaming agent and its production and use |
| CN108159738A (en) * | 2017-12-29 | 2018-06-15 | 山东东岳有机硅材料股份有限公司 | It is a kind of for emulsion type fluorine-containing organic silicon defoamer of oil water two phase system and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 张景河等: "《现代润滑油与燃料添加剂》", 31 December 1991, 北京：中国石化出版社 * |
| 李广宇: "《胶黏剂原材料手册》", 31 August 2004, 国防工业出版社 * |
| 杨成德: "《涂料开发与试验》", 28 February 2015, 科学技术文献出版社 * |
| 袁林等: "《绿色耐火材料》", 31 January 2015, 中国建材工业出版社 * |
| 马洛平: "《消除有害泡沫技术》", 31 December 1987, 北京：化学工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110280051A (en) * | 2019-07-09 | 2019-09-27 | 四川省蜀爱新材料有限公司 | A kind of low silicon defoaming agent |
| CN110280051B (en) * | 2019-07-09 | 2021-07-09 | 四川省蜀爱新材料有限公司 | Low-silicon defoaming agent |
| CN113441101A (en) * | 2020-03-26 | 2021-09-28 | 上海汇友消防技术有限公司 | Novel disposal method for easily-fogging chlorine-containing compound leakage |
| CN113441101B (en) * | 2020-03-26 | 2023-02-10 | 上海汇友消防技术有限公司 | Disposal method for easily-fogging chlorine-containing compound leakage |
| CN112774260A (en) * | 2020-12-17 | 2021-05-11 | 新疆水处理工程技术研究中心有限公司 | Polyether defoaming agent and preparation method thereof |
| CN114011117A (en) * | 2021-11-29 | 2022-02-08 | 淄博爱迪毅环保技术有限公司 | Defoaming agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108905306A (en) | A kind of organic silicon defoamer and preparation method thereof | |
| CN108905305A (en) | Organic silicon defoamer and preparation method thereof | |
| JP5922305B2 (en) | Antifoam formulation containing organopolysiloxane | |
| CN105498305B (en) | A kind of organosilicon defoaming composition | |
| US7550514B2 (en) | Defoamer compositions | |
| JP2009515681A (en) | Silicone defoaming composition | |
| RU2418612C2 (en) | Method of preparing and using compositions controlling foaming | |
| JPH01317505A (en) | Silicone foam control composition | |
| CN108159738B (en) | A kind of emulsion type fluorine-containing organic silicon defoamer and preparation method thereof for oil water two phase system | |
| CN110283322B (en) | Organic silicon composition | |
| JP2006199962A (en) | Defoaming agent composition | |
| JP2000063523A (en) | Linear polyether-polysiloxane-copolymer and production and use thereof | |
| CN103272411A (en) | Foam inhibitor and preparation method thereof | |
| CN102154939A (en) | Anti-foaming agent for papermaking system | |
| CN113577835B (en) | Organic silicon composition | |
| JP2014534046A (en) | Silicone foam control composition and method for producing the same | |
| CN110433534A (en) | A kind of preparation method of organosilicon defoaming lotion | |
| CN105498304A (en) | Defoaming composition and preparation method thereof | |
| CN104436766A (en) | Organosilicone composition | |
| CN109248473A (en) | A kind of deaeration composition | |
| CN111111266A (en) | Modified organic silicon defoaming agent and preparation method thereof | |
| CN103275493B (en) | Organosilicon composition | |
| US3250727A (en) | Defoaming agents containing methylsiloxanes | |
| JPH05271689A (en) | Suds-controlling composition for aqueous composition | |
| JP4495818B2 (en) | Antifoam composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181130 |
|
| RJ01 | Rejection of invention patent application after publication |