CN108755161A - 一种荧光面料的制造方法 - Google Patents
一种荧光面料的制造方法 Download PDFInfo
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- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 16
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- 229920000049 Carbon (fiber) Polymers 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004917 carbon fiber Substances 0.000 claims description 8
- RSEIMSPAXMNYFJ-UHFFFAOYSA-N europium(III) oxide Inorganic materials O=[Eu]O[Eu]=O RSEIMSPAXMNYFJ-UHFFFAOYSA-N 0.000 claims description 8
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Abstract
本发明涉及一种荧光面料的制造方法，将面料基体放置于荧光剂中浸泡，浸泡温度为50～80℃，浸泡时间为3‑5h，浸泡后烘干；在面料基体上涂刷一层防水胶；对混纺面料进行塑化处理，塑化时间为5～10h，塑化温度为150～200℃。本方法制备的荧光面料具有不需要外界的光自身能够进行发光，与面料结合更牢固、不容易脱落的优点。
Description
技术领域
本发明涉及纺织技术领域，具体涉及一种荧光面料的制造方法。
背景技术
荧光产品作为一种具有安全警示防护和识别功能的高能见度产品，其使用范围正不断得到扩展。该产品不仅在交通环卫公安等领域普遍使用，而且夜间作业及特种作业的人员也正逐步使用开来。用于人体穿着的这类产品以涂层居多，这类产品具有良好的荧光效果，但由于它的透气透湿性能较差，使得其使用范围受到限制，尤其是在高温天气状态下，着装者会感到闷湿，进而影响到作业者的身体健康和作业效率。近年来，随着荧光染料的出现，带来了荧光面料的一次换代，以荧光染料染色得到的面料尽管其荧光效果比涂层面料稍差，但其良好的热湿舒适性使其更能广泛应用于对荧光要求不是特别严格的领域。在通过以荧光染料来获得荧光效果的面料中，针织面料在弹性及透气透湿性上比梭织面料更显优势，因此，这里对以荧光染料获得的荧光针织面料进行了探讨，通过对影响能见度效果及服用性能因素的分析与实践，以期能开发出性能良好的荧光针织面料。
荧光是一种光回归反射光学现象，回归反射织物具有将照射到其上的入射光按原入射线大部分返回，提高自身能见度的功能。通常情况下，荧光材料的大多数分子在温室时均处于能量最低的状态，即基态。当它们被紫外线或可见光照射时，其分子吸收了与它所具有的特征频率相一致的光线，由原来的能级跃迁至第一电子激发态或第二电子激发态中各个不同振动能级和转动能级。处于激发态的分子通过振动，内部转换等过程跃迁到分子的第一激发态的最低振动能级，在这一过程中它们和同类分子或其他分子碰撞而消耗了相当于这些能级之间的能量，因而不发光。由第一激发态的最低振动能级继续往下回落至基态的各个振动能级时，则以光的形式释放能量，这时所发出的光即为荧光。通过荧光染料染色所获得的面料具有荧光的效果也是基于这一机理。荧光染料的分子结构是影响荧光效果的最重要的因素，原料、织物组织、整理工艺等都对荧光反光效果有重要的影响。
荧光面料在行人安全、交通安全等方面起到重要作用，夜晚是交通事故多发时间，具有穿着荧光的面料制成的衣物可在夜晚发光使驾驶员注意到路边的行人，从而减少事故的发生，而现有的荧光面料存在结构简单、成本高、功能性单一等缺点，因此，开发新型荧光面料，同时完善其制备工艺，是纺织行业当前需要解决的问题。
发明内容
本发明的目的在于提供一种荧光面料的制造方法，具有不需要外界的光自身能够进行发光，与面料结合更牢固、不容易脱落的优点。
本发明的技术方案是：一种荧光面料的制造方法，将面料基体放置于荧光剂中浸泡，浸泡温度为50～80℃，浸泡时间为3-5h，浸泡后烘干；在面料基体上涂刷一层防水胶；对混纺面料进行塑化处理，塑化时间为5～10h，塑化温度为150～200℃。
所述面料基体的经纱为不锈钢纤维、碳纤维与棉纤维的混纺纱，所述面料基体的纬纱为不锈钢纤维、苎麻纤维与棉纤维的混纺纱。
进一步的，所述面料基体中经纱混纺纱中，不锈钢纤维、碳纤维与棉纤维的含量分别为10-18％、2-5％与77-88％。
进一步的，所纬纱混纺纱中，不锈钢纤维、苎麻纤维与棉纤维的含量分别为8-15％、5-8％与77-87％。
所述荧光剂是由下述重量份的原料组成：邻苯二甲酸二丁脂10～20份、二氧化钛1～2份、二甲基硅油0.02～0.04份、荧光粉60～90份。
所述荧光粉的制备方法为：
(1)按质量比Y2O3：Eu2O3＝100：5～8，将中心粒径为4～5μm的Y2O3和Eu2O3原料的一半投入混料桶中，然后加入原料质量比0.4～0.6％的BaCl2和质量比0.05％-0.1％的H3BO3作为助熔剂，投入剩余的原材料，进行混料20-40小时；将混合均匀的原料装入坩埚中，压实成粉饼，并在压紧的粉饼中间打出圆孔，使粉饼受热均匀，加盖进行高温煅烧，1200～1350℃下保温5～7小时；(2)煅烧后，充分冷却，
取出粉饼进行破碎处理，过筛，筛网目数为80-150目，即可得到荧光粉。
步骤(1)所述的混料，在混料桶加入硬质塑料球，每500公斤原料加20个塑料球，每个塑料球直径6cm，以10～20转/分的转速混料20～40小时。
步骤(2)所述的破碎处理，将粉饼投入颚式破碎机，进行一遍粗破，粗破后的粉体投入辊间距为15～25丝的辊式破碎机进行两遍细破。
本发明的一种荧光面料，具有不需要外界的光自身能够进行发光，与面料结合更牢固、不容易脱落的优点。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。
【实施例1】
1、荧光粉的制备方法：
(1)按质量比Y2O3：Eu2O3＝100:7，将中心粒径为4～5μm的Y2O3和Eu2O3原料的一半投入混料桶中，然后加入原料质量比0.6％的BaCl2和质量比0.1％的H3BO3作为助熔剂，投入剩余的原材料，进行混料20小时；将混合均匀的原料装入坩埚中，压实成粉饼，并在压紧的粉饼中间打出圆孔，使粉饼受热均匀，加盖进行高温煅烧，1350℃下保温7小时；(2)煅烧后，充分冷却，取出粉饼进行破碎处理，过筛，筛网目数为150目，即可得到荧光粉。
2、由下述重量份的原料组成配制荧光剂：邻苯二甲酸二丁脂10份、二氧化钛2份、二甲基硅油0.04份、荧光粉90份。
3、将面料基体放置于荧光剂中浸泡，浸泡温度为80℃，浸泡时间为5h，浸泡后烘干；在面料基体上涂刷一层防水胶；对混纺面料进行塑化处理，塑化时间为10h，塑化温度为200℃；所述面料基体的经纱为不锈钢纤维、碳纤维与棉纤维的混纺纱，所述面料基体的纬纱为不锈钢纤维、苎麻纤维与棉纤维的混纺纱，所述面料基体的中部同一水平面上设有连续均匀排布的微孔结构。所述面料基体的中部同一水平面上设有连续均匀排布的微孔结构。所述面料基体中经纱混纺纱中，不锈钢纤维、碳纤维与棉纤维的含量分别为12％、5％与83％。进一步的，所纬纱混纺纱中，不锈钢纤维、苎麻纤维与棉纤维的含量分别为10％、8％与82％。
【实施例2】
1、荧光粉的制备方法：
(1)按质量比Y2O3:Eu2O3＝100:7，将中心粒径为4μm的Y2O3和Eu2O3原料的一半投入混料桶中，然后加入原料质量比0.4％的BaCl2和质量比0.05％的H3BO3作为助熔剂，投入剩余的原材料，进行混料40小时；将混合均匀的原料装入坩埚中，压实成粉饼，并在压紧的粉饼中间打出圆孔，使粉饼受热均匀，加盖进行高温煅烧，1200℃下保温5小时；(2)煅烧后，充分冷却，取出粉饼进行破碎处理，过筛，筛网目数为80目，即可得到荧光粉。
2、由下述重量份的原料组成配制荧光剂：邻苯二甲酸二丁脂10份、二氧化钛2份、二甲基硅油0.04份、荧光粉90份。
3、将面料基体放置于荧光剂中浸泡，浸泡温度为80℃，浸泡时间为5h，浸泡后烘干；在面料基体上涂刷一层防水胶；对混纺面料进行塑化处理，塑化时间为10h，塑化温度为200℃；所述面料基体的经纱为不锈钢纤维、碳纤维与棉纤维的混纺纱，所述面料基体的纬纱为不锈钢纤维、苎麻纤维与棉纤维的混纺纱，所述面料基体的中部同一水平面上设有连续均匀排布的微孔结构。所述面料基体的中部同一水平面上设有连续均匀排布的微孔结构。所述面料基体中经纱混纺纱中，不锈钢纤维、碳纤维与棉纤维的含量分别为12％、5％与83％。进一步的，所纬纱混纺纱中，不锈钢纤维、苎麻纤维与棉纤维的含量分别为10％、8％与82％。
上述说明已经充分揭露了本发明的具体实施方式。需要指出的是，熟悉该领域的技术人员对本发明的具体实施方式所做的任何改动均不脱离本发明的权利要求书的范围。相应地，本发明的权利要求的范围也并不仅仅局限于前述具体实施方式。
Claims (7)
1.一种荧光面料的制造方法，将面料基体放置于荧光剂中浸泡，浸泡温度为50～80℃，浸泡时间为3-5h，浸泡后烘干；在面料基体上涂刷一层防水胶；对混纺面料进行塑化处理，塑化时间为5～10h，塑化温度为150～200℃；所述面料基体的经纱为不锈钢纤维、碳纤维与棉纤维的混纺纱，所述面料基体的纬纱为不锈钢纤维、苎麻纤维与棉纤维的混纺纱。
2.根据权利要求1所述的荧光面料的制造方法，其特征在于，所述面料基体中经纱混纺纱中，不锈钢纤维、碳纤维与棉纤维的含量分别为10-18％、2-5％与77-88％。
3.根据权利要求1所述的荧光面料的制造方法，其特征在于，所纬纱混纺纱中，不锈钢纤维、苎麻纤维与棉纤维的含量分别为8-15％、5-8％与77-87％。
4.根据权利要求1所述的荧光面料的制造方法，其特征在于，所述荧光剂是由下述重量份的原料组成：邻苯二甲酸二丁脂10～20份、二氧化钛1～2份、二甲基硅油0.02～0.04份、荧光粉60～90份。
5.根据权利要求4所述的荧光面料的制造方法，其特征在于，所述荧光粉的制备方法为：
(1)按质量比Y2O3：Eu2O3＝100：5～8，将中心粒径为4～5μm的Y2O3和Eu2O3原料的一半投入混料桶中，然后加入原料质量比0.4～0.6％的BaCl2和质量比0.05％-0.1％的H3BO3作为助熔剂，投入剩余的原材料，进行混料20-40小时；将混合均匀的原料装入坩埚中，压实成粉饼，并在压紧的粉饼中间打出圆孔，使粉饼受热均匀，加盖进行高温煅烧，1200～1350℃下保温5～7小时；(2)煅烧后，充分冷却，取出粉饼进行破碎处理，过筛，筛网目数为80-150目，即可得到荧光粉。
6.根据权利要求5所述的荧光面料的制造方法，其特征在于，所述的步骤(1)所述的混料，在混料桶加入硬质塑料球，每500公斤原料加20个塑料球，每个塑料球直径6cm，以10～20转/分的转速混料20～40小时。
7.根据权利要求5所述的荧光面料的制造方法，其特征在于，步骤(2)所述的破碎处理，将粉饼投入颚式破碎机，进行一遍粗破，粗破后的粉体投入辊间距为15～25丝的辊式破碎机进行两遍细破。
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| CN102150960A (zh) * | 2010-12-08 | 2011-08-17 | 吴江市合欣转移印花有限公司 | 一种彩色荧光面料 |
| CN104130778A (zh) * | 2014-08-01 | 2014-11-05 | 宜兴银茂荧光材料有限公司 | 超细荧光粉制备方法 |
| CN105862416A (zh) * | 2016-05-16 | 2016-08-17 | 安徽天恩旅行用品科技有限公司 | 儿童书包用荧光面料的制造方法 |
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