CN108557869A - A kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton - Google Patents
A kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton Download PDFInfo
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- CN108557869A CN108557869A CN201810446345.8A CN201810446345A CN108557869A CN 108557869 A CN108557869 A CN 108557869A CN 201810446345 A CN201810446345 A CN 201810446345A CN 108557869 A CN108557869 A CN 108557869A
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- 229920002678 cellulose Polymers 0.000 title claims abstract description 34
- 241000894006 Bacteria Species 0.000 title claims abstract description 33
- 239000001913 cellulose Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 235000010980 cellulose Nutrition 0.000 claims description 31
- 239000000243 solution Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011941 photocatalyst Substances 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002135 nanosheet Substances 0.000 claims description 6
- 238000010189 synthetic method Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 150000001661 cadmium Chemical class 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- 235000011083 sodium citrates Nutrition 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L Cadmium chloride Inorganic materials Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000013033 photocatalytic degradation reaction Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000005342 ion exchange Methods 0.000 abstract description 2
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 239000002086 nanomaterial Substances 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002114 nanocomposite Substances 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000002127 nanobelt Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000002207 thermal evaporation Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000549556 Nanos Species 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000011173 biocomposite Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- QZQVBEXLDFYHSR-UHFFFAOYSA-N gallium(III) oxide Inorganic materials O=[Ga]O[Ga]=O QZQVBEXLDFYHSR-UHFFFAOYSA-N 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- -1 graphite alkene Chemical class 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G11/00—Compounds of cadmium
- C01G11/02—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
Abstract
The present invention relates to a kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton, including step：The pretreatment of bacteria cellulose, the preparation of CdS nanometer sheets.The beneficial effects of the invention are as follows：By simple ion exchange, CdS nanometer sheets have been prepared using the method for hydrothermal synthesis.The CdS so prepared has high activity for photocatalytic degradation.
Description
Technical field
The invention belongs to nano material preparation and applied technical fields, are related to one kind using inorfil skeleton as support level
The method that point prepares CdS nanosheet photocatalysts.
Background technology
Photocatalysis technology, which is increasingly becoming, curbs environmental pollution and one of the technology of most critical of energy shortage problem, and draws
The extensive research of domestic and international scientist is sent out.Many research work concentrate on high efficiency photocatalyst search and it is appropriately designed on,
Because directly carrying out drive response using solar radiation has proved to be a kind of science, the method effectively with green.
In the past few decades, the dimension of nano material and pattern control variation exponentially increase.With not similar shape
The nano material of looks, such as nano particle, nanotube, nano wire, the potential system as scientific research and commercial Application become
It is more and more important.Wherein, two-dimension nano materials such as graphene and transition metal oxide causes broad interest.These two-dimensional nanos
Material is characterized in that its nano level thickness and sub-micron to micron-sized lateral dimension, to have excellent anisotropy
Property and high-specific surface area, this is very important various applications.In addition, for the plural layers weight with pore characteristics
New accumulation, two-dimensional nano piece show huge potentiality, can assign new or enhancing property.For example, catalyzed
HTiNbO5Nanometer sheet and SnO2Nano particle/graphite alkene nanometer sheet can be used as the electrode material of lithium battery.
However, from the perspective of Science and Technology importance, do not have the material (such as ZnO and CdS) of layer structure
It is still a challenge to prepare two-dimensional nano piece.Some typical synthetic methods include liquid-liquid interface growth, object so far
Reason/chemical vapor deposition, the stripping of ultrasonic wave added liquid phase etc. have been developed that.For example, by the thermal evaporation of ZnS powder, Ma
Et al. observe that various ZnS nanostructures include nanometer sheet, the formation of the nanostructures such as nanobelt.By evaporating and aoxidizing GaN
Powder prepares Ga2O3Nanometer sheet and nanobelt.The multilayer ZnO with micron lateral dimension is prepared by thermal evaporation metallic zinc powder
Thin slice.However, these are irregular by the nanometer sheet normally shape and size of gas-phase deposition acquisition；In addition, to being at present
Only not clear atom or ion are rationally assembled into two-dimensional sheet nanostructure rather than other stable forms (such as particle)
Mechanism.Therefore enabling people to prepare, there is the synthetic method of the nano material of predictable form and dimension to be obviously important.
Bacteria cellulose is the large biological molecule by self assembly and nothing with the organized substance of multiple-length layer of structure
Machine nano-particle assembles.The material has supporting structure and hierarchical porosity, is the biology that can be used for preparing CdS nanometer sheets
Nanocomposite.It is realized by template mineralising and double ion exchange and seed growth.This experiment makes in ethanol solution
With caddy and thiocarbamide respectively as Cd2+And S2-The CdS nanometer sheets of precursor, optimization show good degradation property.Biology is received
Nano composite material foam has flexibility, globality and level porosity, it can be achieved that easily separating catalyst, rapid molecular transport
With high reaction surface area, it is very suitable for the extensive use from catalyst to the energy.Petroleum derivation is replaced to polymerize with large biological molecule
Object has shown the sustainability of advanced nanocomposite developing direction.Current work provides a kind of multipurpose and sustainable
Strategy, for produce have " scaffold " structure, grade porosity, numerous compositions Biocomposite material foam.Therefore,
It is especially interesting to study this nano material from one-dimensional to two-dimensional.
Invention content
The technical problem to be solved by the present invention is to：Based on the above issues, the present invention is provided using bacteria cellulose as support
The method that site prepares CdS nanosheet photocatalysts, includes the following steps：
(1) bacteria cellulose is handled：Bacteria cellulose aquagel by Guilin Qi Hong Science and Technology Ltd.s provide, and to its into
Row reprocessing.Bacteria cellulose aquagel is purified in NaOH aqueous solutions, removes the bacterium in striping and Residual reactants, then
It is washed to pH=7.0 using deionized water.Bacteria cellulose after washing is cut into small pieces and is immersed into liquid nitrogen, it is dry to carry out freezing
It is dry, obtain the bacteria cellulose aeroge with layered structure.
(2) preparation of CdS nanometer sheets：0.1M sodium citrates, certain density CdCl are added in the ethanol solution of 100ml2,
It is put into 50mg bacteria celluloses.Ultrasonic 10min makes cadmium salt uniform settlement on cellulose, and it is dense that 0.7ml is then added into solution
Ammonium hydroxide, 0.2M thiocarbamides.Solution is sealed in autoclave, and is heated in an oven, obtained sample with ethanol cleans several times, clearly
It is then dry under vacuum (80 DEG C, 12h) except unsupported CdS up.
Further, the concentration of NaOH solution is 1M in the step (1), and temperature is 90 DEG C.；
Further, the time being freeze-dried in the step (1) is 12h~48h.；
Further, CdCl in the step (2)2Concentration is 0.025M respectively.；
Further, oven temperature is 150 DEG C in the step (2), time 48h.
The application of CdS nanosheet photocatalysts, be used for photocatalytic degradation methylenum careuleum (MB) solution, as steps described below into
Row：
It weighs 30mg catalyst to be put into test tube, 50mL 25mg/L MB solution is added, use 500W mercury lamps as light source, into
Row photocatalytic degradation reacts.Dark reaction time is 40min, after illumination, time sample is taken per 10min, is centrifuged, and then survey its extinction
Degree.
The beneficial effects of the invention are as follows：The preparation method is relatively simple, and preparation condition is easy to control, prepared photocatalysis
Agent uses the biological material of abundance, and prepares nano-scale two-dimensional sheet using the one-dimentional structure of fiber itself
CdS.The catalyst has many advantages, such as pollution-free, high catalytic efficiency, has certain application value.
Description of the drawings
The following further describes the present invention with reference to the drawings.
Fig. 1 is the bacteria cellulose scanning electron microscope (SEM) photograph that the embodiment of the present invention 1 is prepared；
Fig. 2 is the scanning electron microscope (SEM) photograph for the CdS nanometer sheet catalyst that the embodiment of the present invention 1 is prepared；
Fig. 3 is the X-ray diffractogram for the CdS nanometer sheet catalyst that the embodiment of the present invention 1 is prepared；
Fig. 4 is the concentration of the light degradation methylenum careuleum for the CdS nanometer sheet catalyst that the embodiment of the present invention 1 is prepared with illumination
(1~5 corresponds to the CdCl of 0.0125M, 0.025M, 0.05M, 0.1M, 0.2M to time variation diagram respectively2)。
Specific implementation mode
Presently in connection with specific embodiment, the invention will be further described, following embodiment be intended to illustrate invention rather than
Limitation of the invention further.
Embodiment 1
(1) bacteria cellulose is handled：Bacteria cellulose aquagel by Guilin Qi Hong Science and Technology Ltd.s provide, and to its into
Row reprocessing.Bacteria cellulose aquagel is purified in NaOH aqueous solutions, removes the bacterium in striping and Residual reactants, then
It is washed to pH=7.0 using deionized water.Bacteria cellulose after washing is cut into small pieces and is immersed into liquid nitrogen, it is dry to carry out freezing
It is dry, obtain the bacteria cellulose aeroge with layered structure.；
(2) preparation of CdS nanometer sheets：0.1M sodium citrates, certain density CdCl are added in the ethanol solution of 100ml2,
It is put into 50mg bacteria celluloses.Ultrasonic 10min makes cadmium salt uniform settlement on cellulose, and it is dense that 0.7ml is then added into solution
Ammonium hydroxide, 0.2M thiocarbamides.Solution is sealed in autoclave, and is heated in an oven, obtained sample with ethanol cleans several times, clearly
It is then dry under vacuum (80 DEG C, 12h) except unsupported CdS up.；
As Fig. 1,2 surface sweeping electron microscope shown in, present embodiment prepare CdS nanosheet photocatalysts pattern be fiber
CdS nanometer sheets are grown between skeleton, and are distributed more uniform.
CdS Nano lamellites phase structure prepared by embodiment 1 is by Rigaku D/max 2500PC rotation X-ray diffractions
Instrument is analyzed, wherein X-ray is Cu targetsVoltage 40kV, electric current 100mA, step-length are 0.02 °, are swept
Retouch 5 °~80 ° of range.X ray diffracting spectrum is as shown in figure 3, as the characteristic peak of the increase bacteria cellulose of CdS amounts gradually subtracts
Weak, the characteristic peak of CdS gradually increases, therefore can also show that degradation effect is not to become strong with the increase of load capacity.
Such as figure four is later discovered that the CdCl of a concentration of 0.025M by ratio modulation2Degradation effect is best.And without load
Bacteria cellulose adsorption effect than more preferably, being the sample without load because in the catalysis for weighing equal quality after load
Bacterial fibers cellulose content highest in product, exposed adsorption site is most, so adsorbance bigger.But it does not degrade after turning on light
Effect, this load for also having confirmed CdS nanometer sheets have preferable photocatalytic activity.
(3) using the CdS nanometer sheets prepared in embodiment 1 as photocatalyst for degrading methylene blue solution, wherein methylenum careuleum is molten
A concentration of 25mg/L of liquid takes CdS nanometer sheet catalyst 30mg, first dark reaction 40min that solution is made to reach adsorption-desorption and balances, then into
Row ultraviolet catalytic reacts, and using 500W mercury lamps as light source, 3ml reaction solutions are extracted in centrifuge tube every 10min droppers,
Be put into supercentrifuge centrifuge 3min after, after with ultraviolet specrophotometer measure photocatalysis effect.
Claims (5)
1. a kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton, which is characterized in that include the following steps：
(1) bacteria cellulose is handled：Bacteria cellulose aquagel is provided by Guilin Qi Hong Science and Technology Ltd.s, and is carried out again to it
Processing.Bacteria cellulose aquagel is purified in NaOH aqueous solutions, the bacterium in striping and Residual reactants is removed, then uses
Deionized water is washed to pH=7.0.Bacteria cellulose after washing is cut into small pieces and is immersed into liquid nitrogen, is freeze-dried,
Obtain the bacteria cellulose aeroge with layered structure.；
(2) preparation of CdS nanometer sheets：0.1M sodium citrates, certain density CdCl are added in the ethanol solution of 100ml2, it is put into
50mg bacteria celluloses.Ultrasonic 10min makes cadmium salt uniform settlement on cellulose, and the dense ammonia of 0.7ml is then added into solution
Water, 0.2M thiocarbamides.Solution is sealed in autoclave, and is heated in an oven, obtained sample with ethanol cleaning several times, is removed
Unsupported CdS up is then dry under vacuum (80 DEG C, 12h).
2. the synthetic method of bacteria cellulose according to claim 1, it is characterized in that：NaOH is molten in the step (1)
The concentration of liquid is 1M, and temperature is 90 DEG C.
3. the synthetic method of bacteria cellulose according to claim 1, it is characterized in that：Freezing is dry in the step (1)
The dry time is 12h~48h.
4. the preparation method of CdS nanosheet photocatalysts according to claim 1, it is characterized in that：In the step (2)
CdCl2Concentration is 0.025M respectively.
5. the preparation method of CdS nanosheet photocatalysts according to claim 1, it is characterized in that：In the step (2)
Oven temperature is 150 DEG C, time 48h.
Priority Applications (1)
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| CN201810446345.8A CN108557869A (en) | 2018-05-11 | 2018-05-11 | A kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810446345.8A CN108557869A (en) | 2018-05-11 | 2018-05-11 | A kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton |
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| CN108557869A true CN108557869A (en) | 2018-09-21 |
Family
ID=63538606
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| CN201810446345.8A Pending CN108557869A (en) | 2018-05-11 | 2018-05-11 | A kind of CdS nanometer piece preparation methods based on bacteria cellulose skeleton |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109999835A (en) * | 2019-03-27 | 2019-07-12 | 武汉理工大学 | A kind of carbonization bacteria cellulose-cadmium sulfide composite photocatalyst material and its preparation method and application |
| CN110808361A (en) * | 2019-10-09 | 2020-02-18 | 天津大学 | Method for preparing lithium-sulfur battery cathode material based on bacterial cellulose |
| CN112768655A (en) * | 2021-01-11 | 2021-05-07 | 上海应用技术大学 | Preparation method of tin dioxide @ oxidized bacterial cellulose/reduced graphene oxide electrode material |
| CN113663655A (en) * | 2021-08-10 | 2021-11-19 | 常州大学 | Preparation method of high-elasticity PDMS/CBC sponge adsorbing material |
-
2018
- 2018-05-11 CN CN201810446345.8A patent/CN108557869A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| PEIPEI WANG ET AL.: ""ZnxCd1-xS/bacterial cellulose bionanocomposite foams with hierarchical architecture and enhanced visible-light photocatalytic hydrogen production", 《JOURNAL OF MATERIALS CHEMISTRY A》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109999835A (en) * | 2019-03-27 | 2019-07-12 | 武汉理工大学 | A kind of carbonization bacteria cellulose-cadmium sulfide composite photocatalyst material and its preparation method and application |
| CN109999835B (en) * | 2019-03-27 | 2022-05-10 | 武汉理工大学 | Carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material and preparation method and application thereof |
| CN110808361A (en) * | 2019-10-09 | 2020-02-18 | 天津大学 | Method for preparing lithium-sulfur battery cathode material based on bacterial cellulose |
| CN112768655A (en) * | 2021-01-11 | 2021-05-07 | 上海应用技术大学 | Preparation method of tin dioxide @ oxidized bacterial cellulose/reduced graphene oxide electrode material |
| CN113663655A (en) * | 2021-08-10 | 2021-11-19 | 常州大学 | Preparation method of high-elasticity PDMS/CBC sponge adsorbing material |
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Application publication date: 20180921 |