CN108384027B - 一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 - Google Patents
一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 Download PDFInfo
- Publication number
- CN108384027B CN108384027B CN201810424036.0A CN201810424036A CN108384027B CN 108384027 B CN108384027 B CN 108384027B CN 201810424036 A CN201810424036 A CN 201810424036A CN 108384027 B CN108384027 B CN 108384027B
- Authority
- CN
- China
- Prior art keywords
- acetylacetone
- fda
- zinc
- dimethylformamide
- btz
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 239000013384 organic framework Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 37
- 239000013078 crystal Substances 0.000 claims abstract description 14
- CHTHALBTIRVDBM-UHFFFAOYSA-N furan-2,5-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)O1 CHTHALBTIRVDBM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007850 fluorescent dye Substances 0.000 claims abstract description 7
- 230000005595 deprotonation Effects 0.000 claims abstract description 6
- 238000010537 deprotonation reaction Methods 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012964 benzotriazole Substances 0.000 claims abstract description 4
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 4
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 52
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000003446 ligand Substances 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 6
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000013110 organic ligand Substances 0.000 claims description 4
- -1 dimethylamine cation Chemical class 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 239000012621 metal-organic framework Substances 0.000 description 13
- 239000000843 powder Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000002189 fluorescence spectrum Methods 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011540 sensing material Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
- G01N21/643—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" non-biological material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N2021/6417—Spectrofluorimetric devices
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
- G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
- G01N2021/6432—Quenching
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Immunology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Optics & Photonics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Molecular Biology (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810424036.0A CN108384027B (zh) | 2018-05-07 | 2018-05-07 | 一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810424036.0A CN108384027B (zh) | 2018-05-07 | 2018-05-07 | 一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108384027A CN108384027A (zh) | 2018-08-10 |
CN108384027B true CN108384027B (zh) | 2021-03-26 |
Family
ID=63070661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810424036.0A Active CN108384027B (zh) | 2018-05-07 | 2018-05-07 | 一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108384027B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109265701B (zh) * | 2018-10-22 | 2021-03-16 | 江西理工大学 | 一种对乙酰丙酮具有选择性荧光识别的锌基金属有机框架及其制备方法 |
CN110003251B (zh) * | 2019-04-29 | 2021-08-24 | 江西省科学院应用化学研究所 | 一种双荧光响应铕基分子晶态材料的制备及应用 |
CN110218332A (zh) * | 2019-06-17 | 2019-09-10 | 北京石油化工学院 | 一种负载缓蚀剂的锌配合物纳米容器及其制备方法与应用 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8123834B2 (en) * | 2005-10-06 | 2012-02-28 | The Board Of Trustees Of The University Of Illinois | High gain selective metal organic framework preconcentrators |
CN102964365A (zh) * | 2012-03-16 | 2013-03-13 | 长春工业大学 | 具有孔道结构的呋喃二甲酸锌金属有机骨架材料及制备方法 |
CN103242827A (zh) * | 2013-05-31 | 2013-08-14 | 南开大学 | 一种用于锌离子检测的荧光离子探针试剂及其制备方法 |
CN105503912A (zh) * | 2016-01-04 | 2016-04-20 | 辽宁大学 | 一种新型Zn(Ⅱ)金属有机骨架及其合成方法和应用 |
WO2016185679A1 (ja) * | 2015-05-15 | 2016-11-24 | パナソニック株式会社 | 化学センサ |
CN107474060A (zh) * | 2017-08-11 | 2017-12-15 | 南开大学 | 一种具有选择性吸附分离阴离子染料性能的金属‑有机框架材料及其制备方法和应用 |
CN107603602A (zh) * | 2017-10-31 | 2018-01-19 | 江西省科学院应用化学研究所 | 一种锌‑稀土金属‑有机框架荧光传感材料及其合成方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013158484A1 (en) * | 2012-04-18 | 2013-10-24 | King Abdullah University Of Science And Technology | Electrode separator |
-
2018
- 2018-05-07 CN CN201810424036.0A patent/CN108384027B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8123834B2 (en) * | 2005-10-06 | 2012-02-28 | The Board Of Trustees Of The University Of Illinois | High gain selective metal organic framework preconcentrators |
CN102964365A (zh) * | 2012-03-16 | 2013-03-13 | 长春工业大学 | 具有孔道结构的呋喃二甲酸锌金属有机骨架材料及制备方法 |
CN103242827A (zh) * | 2013-05-31 | 2013-08-14 | 南开大学 | 一种用于锌离子检测的荧光离子探针试剂及其制备方法 |
WO2016185679A1 (ja) * | 2015-05-15 | 2016-11-24 | パナソニック株式会社 | 化学センサ |
CN105503912A (zh) * | 2016-01-04 | 2016-04-20 | 辽宁大学 | 一种新型Zn(Ⅱ)金属有机骨架及其合成方法和应用 |
CN107474060A (zh) * | 2017-08-11 | 2017-12-15 | 南开大学 | 一种具有选择性吸附分离阴离子染料性能的金属‑有机框架材料及其制备方法和应用 |
CN107603602A (zh) * | 2017-10-31 | 2018-01-19 | 江西省科学院应用化学研究所 | 一种锌‑稀土金属‑有机框架荧光传感材料及其合成方法 |
Also Published As
Publication number | Publication date |
---|---|
CN108384027A (zh) | 2018-08-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108998007B (zh) | 一种稀土金属有机框架材料的制备方法 | |
CN108440580B (zh) | 一种Zn5簇基金属-有机框架材料及其改性材料的制备方法 | |
Patra et al. | A highly selective benzildihydrazone based Schiff base chromogenic chemosensor for rapid detection of Cu2+ in aqueous solution | |
CN108384027B (zh) | 一种具有乙酰丙酮荧光响应的锌-有机框架及制备方法 | |
CN113234233B (zh) | 一种具有抗生素荧光识别的铕基金属-有机框架材料及制备方法 | |
CN102516270B (zh) | 具有二维层状结构的金属银配位聚合物及其制备与应用 | |
CN111303443A (zh) | 一种锌配位聚合物及其制备方法和应用 | |
CN106188108B (zh) | 一种Cd的金属有机骨架材料和制备方法及其应用 | |
CN111471191A (zh) | 一种Cd-MOF配合物及其制备方法和应用 | |
Shan et al. | A facile, fast responsive and highly selective mercury (II) probe characterized by the fluorescence quenching of 2, 9-dimethyl-1, 10-phenanthroline and two new metal–organic frameworks | |
CN107880274A (zh) | 一种混合金属有机框架材料及其制备方法和应用 | |
Geng et al. | Improvement of the fluorescent sensing biomarker 3-nitrotyrosine for a new luminescent coordination polymer by size regulation | |
CN104592263A (zh) | 一种镉配位聚合物及其在水中对硝基类化合物检测的应用 | |
CN103421030B (zh) | 用作镉离子荧光探针的二元芳香酸铈配合物及其制备方法 | |
Ghosh et al. | Structural, spectroscopic and redox properties of transition metal complexes of dipyrido [3, 2-f: 2′, 3′-h]-quinoxaline (dpq) | |
CN110790941A (zh) | 含内消螺旋链的锌-有机配位聚合物及其制法与应用 | |
CN106317092A (zh) | 一种均苯四甲酸配体的铕配合物、其制备方法及应用 | |
CN108424527B (zh) | 三维混合配体的Zn(II)配合物的合成方法与荧光探针应用 | |
CN110003251A (zh) | 一种双荧光响应铕基分子晶态材料的制备及应用 | |
CN112940279B (zh) | 一种层柱状锌基金属-有机框架材料及制备方法 | |
CN106278920A (zh) | 用作镉离子荧光探针的氨三乙酸钬配合物及其制备方法 | |
CN106167501B (zh) | 一种对苯二甲酸和2,4,5‑三(4‑吡啶基)‑1h‑咪唑混配的铜配合物、其制备方法及应用 | |
Zhao et al. | A 3D metal–organic framework with dual-aerial-octahedral trinucleate building units: Synthesis, structure and fluorescence sensing properties | |
CN111689992B (zh) | 一种含锌keggin型钼多酸化合物、制备方法及催化应用 | |
CN107698776B (zh) | 一种具有阳离子传感性能的Zn-MOF材料及制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information |
Address after: 330031 7777 Changdong Avenue, Qingyun District, Nanchang, Jiangxi Applicant after: Institute of Applied Chemistry, Jiangxi Academy of Sciences Address before: 330046 No. 108, Shang Fang Road, East Lake District, Nanchang, Jiangxi. Applicant before: Institute of Applied Chemistry, Jiangxi Academy of Sciences |
|
CB02 | Change of applicant information | ||
CB02 | Change of applicant information |
Address after: 330031 7777 Changdong Avenue, Nanchang hi tech Development Zone, Jiangxi Applicant after: Institute of Applied Chemistry, Jiangxi Academy of Sciences Address before: 330031 7777 Changdong Avenue, Qingyun District, Nanchang, Jiangxi Applicant before: Institute of Applied Chemistry, Jiangxi Academy of Sciences |
|
CB02 | Change of applicant information | ||
CB03 | Change of inventor or designer information |
Inventor after: You Shengyong Inventor after: Zou Jiyong Inventor after: Li Ling Inventor after: Remarkably Inventor after: Chen Yanhua Inventor before: Zou Jiyong Inventor before: Li Ling Inventor before: You Shengyong Inventor before: Remarkably Inventor before: Chen Yanhua |
|
CB03 | Change of inventor or designer information | ||
GR01 | Patent grant | ||
GR01 | Patent grant |