CN108315060A - No. 91 unleaded aviation gasoline of one kind and its production method - Google Patents

No. 91 unleaded aviation gasoline of one kind and its production method Download PDF

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Publication number
CN108315060A
CN108315060A CN201810123556.8A CN201810123556A CN108315060A CN 108315060 A CN108315060 A CN 108315060A CN 201810123556 A CN201810123556 A CN 201810123556A CN 108315060 A CN108315060 A CN 108315060A
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CN
China
Prior art keywords
aviation gasoline
unleaded aviation
gasoline
alkane
unleaded
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201810123556.8A
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Chinese (zh)
Inventor
刘浩
郑拥军
姬海博
宋立仙
王玥
王杰
刘彪
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HEBEI XINQIYUAN ENERGY TECHNOLOGY DEVELOPMENT Co Ltd
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HEBEI XINQIYUAN ENERGY TECHNOLOGY DEVELOPMENT Co Ltd
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Application filed by HEBEI XINQIYUAN ENERGY TECHNOLOGY DEVELOPMENT Co Ltd filed Critical HEBEI XINQIYUAN ENERGY TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201810123556.8A priority Critical patent/CN108315060A/en
Publication of CN108315060A publication Critical patent/CN108315060A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of No. 91 unleaded aviation gasoline and its production methods, including following component;Technical octane, commercial xylene, industrial isopentane, No. 91 unleaded aviation gasoline of this kind and its production method, pass through 80~90% alkane that will be based on volume basis, 10~20% aromatic hydrocarbons is prepared by reconciling, or technology is refined by petrochemical industry and is prepared, alkane in No. 91 unleaded aviation gasoline of the present invention is based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meet the requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99, high income is at low cost, raw material is simple and easy to get, and preparation method is simple.

Description

No. 91 unleaded aviation gasoline of one kind and its production method
Technical field
The present invention relates to aviation gasoline technical fields, more particularly, to a kind of No. 91 unleaded aviation gasoline and its producer Method.
Background technology
Aviation gasoline has several trades mark.One kind being No. 95, and (95/130, i.e., gasoline-air lean mixture is under Cruise Conditions Motor octane number be 95MON, gasoline-performance number of the air rich mixture when taking off be 130), wherein containing tetraethyl Lead.It is mainly used for the Large-scale Reciprocating aero-engine for having booster.Another kind is No. 75, and (motor octane number is water white 75MON), unleaded gas.It is mainly used for the small-sized piston formula aero-engine of no booster.It is given birth to by catalytic cracking or catalytic reforming The high-knock rating gasoline fraction of production increases octane components and a small amount of anti-knock agent and antioxidant is concocted.The capability of antidetonance is high.Boat Empty gasoline is used as the oil product of piston aviation engine fuel.With sufficiently low crystalline temperature (- 60 DEG C or less) and higher Calorific value, good vapo(u)rability and enough anti-knock properties.Aviation gasoline is a kind of antiknock gasoline for aircraft, also once Through being used in racing car.Aviation gasoline is served only on the aircraft of reciprocating engine, and jet plane and turbine-propeller fly Machine then uses aviation kerosine.
China Aviation gasoline mainly contains the refined component of catalytically cracked gasoline, and adds suitable isopropylbenzene, alkylation The antioxidant of gasoline, technical octane, isopentane and lead tetraethide and 100,000/several, is additionally added a small amount of corrosion suppression sometimes Preparation and a small amount of oil-soluble dyes.Gasoline color is different because of dyestuff.Also No. 100, motor octane number 98.6MON, product Angle value is not less than 130.Also contain lead tetraethide.Different types of aviation gasoline is differentiated for convenience of pilot, aviation gasoline can add Enter dyestuff.80/87 is red, and 100/130 is green, and 100LL is blue.Aviation kerosine, such as JET A1 are colourless in itself Or olive drab(O.D), and it is not added with dyestuff.Aviation gasoline volatility is lower than motor petrol, less easily vaporizes.The aviation vapour of today Gasoline is not distinguished greatly when just being released with generation nineteen fifty and generation nineteen sixty, still pungent to increase by adding highly toxic lead tetraethide Alkane value, this additive just disappear from motor petrol earlier than the 1980's.
Density of the aviation gasoline at 15 degree Celsius is per U.S. 6.02 pounds of gallon, this is also general aircraft weight and center of gravity Numerical value used when EQUILIBRIUM CALCULATION FOR PROCESS.At subzero 40 degree Celsius, density is per U.S. 6.40 pounds of gallon.It is Celsius that temperature often rises five Degree, density will reduce 0. 5 percent.Aviation gasoline is divided into several grades with maximum lead tolerance.Since lead tetraethide is one The expensive additive of kind, is usually only added in seldom deal to aviation gasoline to reach the octane number of requirement, so aviation gasoline Lead tolerance usually all than maximum lead tolerance be it is low.In passing, also other kinds of aviation gasoline, especially military class Type, such as Avgas 115/145.The octane number of aviation gasoline, generally cannot be compared with motor benzine, because of aviation gasoline Octane number is that the entirely different test engines of Yi Yitai are collated and stipulated with test method.First (numerical value is lower) number " lean gas gaseous mixture octane number ", and second higher numerical value, be referred to as " rich gas gaseous mixture octane number " (" poor " and " richness ", Refer to aviation gasoline ratio shared in gaseous mixture).Under opposite, the octane number of motor benzine is usually labeled as " Ulva Pertusa index " is obtained by being averaged with both " research result " and " automotive engine test value ".
But current unleaded aviation gasoline octane number is low, vapour pressure is high, and boiling range is improper, cannot meet aviation gasoline It is required that causing yield not high, cost is high instead, and raw material is not readily available, and preparation method is also complex, brings Big inconvenience.
Invention content
The technical problem to be solved by the present invention is to overcome the existing defects, provides No. 91 unleaded aviation gasoline of one kind and its life Production method, to solve the above problems.
To achieve the above object, the present invention provides the following technical solutions:A kind of No. 91 unleaded aviation gasoline, including below at Point;
Technical octane, commercial xylene, industrial isopentane.
As a preferred technical solution of the present invention, the percentage composition of the technical octane is 60-85%.
As a preferred technical solution of the present invention, the percentage composition of the commercial xylene is 10-25%.
As a preferred technical solution of the present invention, the percentage composition of the industry isopentane is 5-20%.
No. 91 unleaded aviation gasoline of one kind and its production method, include the following steps;
By based on volume basis 80~90% alkane and 10~20% aromatic hydrocarbons prepared by reconciling, or pass through petrochemical industry Refining technology is prepared.
Compared with prior art, the beneficial effects of the invention are as follows:No. 91 unleaded aviation gasoline of this kind and its production method are led to It crosses 80~90% alkane based on volume basis, 10~20% aromatic hydrocarbons is prepared by reconciling, or refines skill by petrochemical industry Art is prepared, and for the alkane in of the invention No. 91 unleaded aviation gasoline based on isoparaffin, octane number is high, and steam forces down, Boiling range is suitable, meets the requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99, high income, and cost Low, raw material is simple and easy to get, and preparation method is simple.
Specific implementation mode
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is only It is a part of the embodiment of the present invention, instead of all the embodiments, based on the embodiments of the present invention, ordinary skill people The every other embodiment that member is obtained without making creative work, shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution:A kind of No. 91 unleaded aviation gasoline, including following component;
Technical octane, commercial xylene, industrial isopentane.
The percentage composition of technical octane is 60-85%, and the percentage composition of commercial xylene is 10-25%, industrial isoamyl The percentage composition of alkane is 5-20%.
No. 91 unleaded aviation gasoline of one kind and its production method, include the following steps;
By based on volume basis 80~90% alkane and 10~20% aromatic hydrocarbons prepared by reconciling, or pass through petrochemical industry Refining technology is prepared.
Embodiment 1:No. 91 unleaded aviation gasoline of one kind and its production method, including following component;Technical octane, industry Dimethylbenzene, industrial isopentane.Technical octane percentage composition is 60%, commercial xylene percentage composition is 20%, industrial isoamyl Alkane percentage composition is 20%, and No. 91 unleaded aviation gasoline of one kind and its production method include the following steps;By will be by volume hundred Divide 80~90% alkane of meter, 10~20% aromatic hydrocarbons to be prepared by reconciling, or technology is refined by petrochemical industry and is prepared, originally For alkane in No. 91 unleaded aviation gasoline of invention based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meets The requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99.
Embodiment 2:No. 91 unleaded aviation gasoline of one kind and its production method, including following component;Technical octane, industry Dimethylbenzene, industrial isopentane.Technical octane percentage composition is 70%, commercial xylene percentage composition is 15%, industrial isoamyl Alkane percentage composition is 15%, and No. 91 unleaded aviation gasoline of one kind and its production method include the following steps;By will be by volume hundred Divide 80~90% alkane of meter, 10~20% aromatic hydrocarbons to be prepared by reconciling, or technology is refined by petrochemical industry and is prepared, originally For alkane in No. 91 unleaded aviation gasoline of invention based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meets The requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99.
Embodiment 3:No. 91 unleaded aviation gasoline of one kind and its production method, including following component;Technical octane, industry Dimethylbenzene, industrial isopentane.Technical octane percentage composition is 80%, commercial xylene percentage composition is 15%, industrial isoamyl Alkane percentage composition is 5%, and No. 91 unleaded aviation gasoline of one kind and its production method include the following steps;By will be by volume hundred Divide 80~90% alkane of meter, 10~20% aromatic hydrocarbons to be prepared by reconciling, or technology is refined by petrochemical industry and is prepared, originally For alkane in No. 91 unleaded aviation gasoline of invention based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meets The requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99.
Embodiment 4:No. 91 unleaded aviation gasoline of one kind and its production method, including following component;Technical octane, industry Dimethylbenzene, industrial isopentane.Technical octane percentage composition is 85%, commercial xylene percentage composition is 10%, industrial isoamyl Alkane percentage composition is 5%, and No. 91 unleaded aviation gasoline of one kind and its production method include the following steps;By will be by volume hundred Divide 80~90% alkane of meter, 10~20% aromatic hydrocarbons to be prepared by reconciling, or technology is refined by petrochemical industry and is prepared, originally For alkane in No. 91 unleaded aviation gasoline of invention based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meets The requirement of aviation gasoline, between the research octane number (RON) of the aviation gasoline is 97~99.
Blend component Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Technical octane 60% 70% 80% 85%
Commercial xylene 20% 15% 15% 10%
Industrial isopentane 20% 15% 5% 5%
Part physical property
Concrete principle:In use, by 80~90% alkane that will be based on volume basis, 10~20% aromatic hydrocarbons passes through It reconciles and prepares, or technology is refined by petrochemical industry, No. 91 unleaded aviation gasoline are prepared.
No. 91 unleaded aviation gasoline of this kind and its production method, by 80~90% alkane that will be based on volume basis, 10~20% aromatic hydrocarbons is prepared by reconciling, or is refined technology by petrochemical industry and be prepared, of the invention No. 91 unleaded aviation vapour For alkane in oil based on isoparaffin, octane number is high, and steam forces down, and boiling range is suitable, meets the requirement of aviation gasoline, the aviation Between the research octane number (RON) of gasoline is 97~99, high income is at low cost, and raw material is simple and easy to get, and preparation method is simple.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's Within protection domain.

Claims (5)

1. a kind of No. 91 unleaded aviation gasoline, which is characterized in that including following component;
Technical octane, commercial xylene, industrial isopentane.
2. a kind of No. 91 unleaded aviation gasoline according to claim 1, which is characterized in that the percentage of the technical octane Content is 60-85%.
3. a kind of No. 91 unleaded aviation gasoline according to claim 1, which is characterized in that the percentage of the commercial xylene Content is 10-25%.
4. a kind of No. 91 unleaded aviation gasoline according to claim 1, which is characterized in that the percentage of the industry isopentane Content is 5-20%.
5. a kind of No. 91 unleaded aviation gasoline according to claim 1 and its production method, which is characterized in that including following Step;
By based on volume basis 80~90% alkane and 10~20% aromatic hydrocarbons prepared by reconciling, or skill refined by petrochemical industry Art is prepared.
CN201810123556.8A 2018-02-07 2018-02-07 No. 91 unleaded aviation gasoline of one kind and its production method Pending CN108315060A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022059A (en) * 2018-08-27 2018-12-18 东营华亚国联航空燃料有限公司 Unleaded aviation piston type engine fuel and preparation method thereof
CN112094672A (en) * 2020-11-03 2020-12-18 东营华亚国联航空燃料有限公司 No. 100 lead-free aviation piston type engine fuel, preparation method and quantitative mixing device
CN115707761A (en) * 2021-08-20 2023-02-21 中国石油化工股份有限公司 No. 95 coal-based aviation gasoline composition and preparation method thereof
WO2024091145A1 (en) * 2022-10-27 2024-05-02 Публичное акционерное общество "Газпром нефть" Unleaded aviation gasoline fuel composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6451075B1 (en) * 1999-12-09 2002-09-17 Texas Petrochemicals Lp Low lead aviation gasoline blend
CN103965974A (en) * 2014-05-16 2014-08-06 中国民用航空总局第二研究所 Lead-free aviation gasoline and preparation method thereof
CN104673410A (en) * 2015-02-14 2015-06-03 德法尔(平原)科技有限公司 Low-lead aviation gasoline and production method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6451075B1 (en) * 1999-12-09 2002-09-17 Texas Petrochemicals Lp Low lead aviation gasoline blend
CN103965974A (en) * 2014-05-16 2014-08-06 中国民用航空总局第二研究所 Lead-free aviation gasoline and preparation method thereof
CN104673410A (en) * 2015-02-14 2015-06-03 德法尔(平原)科技有限公司 Low-lead aviation gasoline and production method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022059A (en) * 2018-08-27 2018-12-18 东营华亚国联航空燃料有限公司 Unleaded aviation piston type engine fuel and preparation method thereof
CN112094672A (en) * 2020-11-03 2020-12-18 东营华亚国联航空燃料有限公司 No. 100 lead-free aviation piston type engine fuel, preparation method and quantitative mixing device
CN112094672B (en) * 2020-11-03 2021-02-05 东营华亚国联航空燃料有限公司 Quantitative mixing device for No. 100 leadless aviation piston engine fuel
WO2022095181A1 (en) * 2020-11-03 2022-05-12 东营华亚国联航空燃料有限公司 Grade-100 lead-free aviation piston-type engine fuel, preparation method, and quantitative mixing apparatus
CN115707761A (en) * 2021-08-20 2023-02-21 中国石油化工股份有限公司 No. 95 coal-based aviation gasoline composition and preparation method thereof
CN115707761B (en) * 2021-08-20 2024-05-17 中国石油化工股份有限公司 No. 95 coal-based aviation gasoline composition and preparation method thereof
WO2024091145A1 (en) * 2022-10-27 2024-05-02 Публичное акционерное общество "Газпром нефть" Unleaded aviation gasoline fuel composition

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Application publication date: 20180724