CN107656380A - A kind of myopia motion Sunglasses lenses sun clips and its production technology - Google Patents
A kind of myopia motion Sunglasses lenses sun clips and its production technology Download PDFInfo
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- CN107656380A CN107656380A CN201711032031.5A CN201711032031A CN107656380A CN 107656380 A CN107656380 A CN 107656380A CN 201711032031 A CN201711032031 A CN 201711032031A CN 107656380 A CN107656380 A CN 107656380A
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- Prior art keywords
- myopia
- sunglasses lenses
- sun clips
- lenses sun
- base
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- 208000001491 myopia Diseases 0.000 title claims abstract description 32
- 230000004379 myopia Effects 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 50
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 239000011248 coating agent Substances 0.000 claims abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000002360 preparation method Methods 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 16
- 239000010445 mica Substances 0.000 claims abstract description 16
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000001055 blue pigment Substances 0.000 claims abstract description 15
- 239000002585 base Substances 0.000 claims description 57
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 36
- 150000004985 diamines Chemical class 0.000 claims description 18
- 125000004122 cyclic group Chemical group 0.000 claims description 17
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 15
- 229920000299 Nylon 12 Polymers 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 239000003963 antioxidant agent Substances 0.000 claims description 14
- 230000003078 antioxidant effect Effects 0.000 claims description 14
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 13
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 12
- 229910052593 corundum Inorganic materials 0.000 claims description 12
- 239000010431 corundum Substances 0.000 claims description 12
- YWDYRRUFQXZJBG-UHFFFAOYSA-N butyl prop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCCCOC(=O)C=C YWDYRRUFQXZJBG-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000000356 contaminant Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 150000003951 lactams Chemical class 0.000 claims description 3
- 230000002045 lasting effect Effects 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000009938 salting Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- KFCDDRTYJQZGKK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enenitrile Chemical compound C=CC#N.CC(=C)C(O)=O KFCDDRTYJQZGKK-UHFFFAOYSA-N 0.000 abstract 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 238000005070 sampling Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- -1 Epoxide alkane Chemical class 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Ophthalmology & Optometry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Eyeglasses (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of myopia motion Sunglasses lenses sun clips and its production technology, due to being the production technology for being strict with base eyeglass, the proportioning and preparation technology of coating liquid, especially make the proportioning of coating liquid, the present invention is based on silica, it with the addition of transparent powder, methacrylate acrylonitrile acid butyl ester is copolymerized, acrylate, the compositions such as mica powder, it is divided into two steps and the first solution and the second solution is made respectively, transparent powder is added on the basis of the second solution, auxiliary agent and blue pigment, and the proportional quantity of the every kind of component of lattice control and the technological parameter of each operation, it is avoided that other reactions occur in process for individual components, the effect for this making that " Synergistic " can be formed between component, increase substantially the quality of coat, after coat being formed on base eyeglass, the hardness of product can be increased substantially（Wearability）, while also there is excellent toughness, impact resistant capability and perspective rate.
Description
Technical field
The present invention relates to resin lens, more particularly to a kind of myopia motion Sunglasses lenses sun clips and its production technology.
Background technology
Resin lens have in light weight and have the characteristics of certain pliability and easy processing, so the eye that resin material makes
Mirror eyeglass has been widely used at present, turns into the main flow of eyeglasses-wearing.But either using made from which kind of resin
Resin lens, it is respectively provided with, and case hardness is not high specially, and only up to 5H or so, and abrasion resistance properties are poor.
In order to overcome above mentioned problem, current most of ways are to coat layer of silicon dioxide stiffened on the surface of resin substrate
Film layer, can so allow the case hardness of eyeglass increase to 7-8H, greatly extend the service life of eyeglass.
The content of the invention
In order to overcome above mentioned problem, the invention provides a kind of myopia motion Sunglasses lenses sun clips and its production technology.
To achieve the above object, technical scheme provided by the invention is：
A kind of myopia motion Sunglasses lenses sun clips, including base eyeglass and coated in the coat on base eyeglass,
The raw material of described base eyeglass include cyclic structure diamines, nylon 12, corundum fine powder, antioxidant, age resistor and
Molecular weight regulator；Described cyclic structure diamines and the mol ratio of nylon 12 are 1：1；
Wherein：Described corundum fine powder, antioxidant, age resistor, molecular weight regulator are respectively cyclic structure diamines and poly- 12
80-120%, 3-5% of lactams mass ratio, 0.02%, 3-5%；
Described coat includes silica 1 8.2-20wt%, acetic acid 0.5-2wt%, transparent powder 7wt%, propyl trimethoxy alkane
21-27wt%, methacrylate-acrylic acid butyl ester copolymer-1 2-18wt%, acrylate 7-8wt%, mica powder 12-15wt% and
Blue pigment 0.5-1.2wt%, remaining is auxiliary agent.
Preferably, between the perspective rate of the base eyeglass is 8-18 ° or between 18-42 °.
Preferably, in base eyeglass, described corundum fine powder, antioxidant, age resistor, molecular weight regulator are respectively ring-type
98%, 3%, 0.02%, the 4% of structure diamines and nylon 12 mass ratio.
Preferably, described coat includes silica 1 9.4wt%, acetic acid 1.3wt%, transparent powder 7wt%, propyl group front three
Epoxide alkane 26wt%, methacrylate-acrylic acid butyl ester copolymer-1 2wt%, acrylate 7.6wt%, mica powder 14wt%, Lan Yan
Expect 0.9wt%, remaining is auxiliary agent.
A kind of production technology of myopia motion Sunglasses lenses sun clips, comprises the following steps：
1）First base eyeglass and coating liquid is made in substep；
2）Obtained base eyeglass is immersed in coating liquid, then by alkali process, rinsing, drying, refrigerating work procedure, makes coating
Liquid forms coat in base lens surface；
3）Base eyeglass with coat is cut, obtains myopia motion Sunglasses lenses sun clips.
Specifically, the preparation of the base eyeglass comprises the following steps：
1）Cyclic structure diamines, nylon 12 and molecular weight regulator are added in reactor, are heated to seething with excitement, so
After neutralize into salt, obtain salting liquid；
2）Antioxidant and age resistor are added in reactor simultaneously and carried out, then under conditions of 60r/min, is slowly added to just
Beautiful fine powder, increasing temperature and pressure is reheated, reactor pressure is maintained at 2.2-3.45Mpa, and temperature in the kettle is 230-260 DEG C, keeps 5-
10min；
3）Reactor is depressured with 0.01-0.03 Mpa/min speed, until normal pressure, then carries out heating up for second,
Make temperature in the kettle that 1.2-2h be exhausted at a temperature of being maintained at 280-320 DEG C, add CO2, kettle internal pressure power is maintained at 0.1-
0.4Mpa, discharge blank, obtains base lens blank；
4）Base eyeglass is obtained after being surface-treated to base lens blank.
More specifically, in step 2）In, the pressure of the reactor is 2.8Mpa, and temperature in the kettle is 245 DEG C, keeps 5-
10min。
More specifically, in step 3）In, the secondary temperature elevation temperature of the reactor is maintained at 300 DEG C, and kettle internal pressure, which is tried hard to keep, holds
In 0.3Mpa.
Specifically, the preparation of the coating liquid comprises the following steps：
1）Silica and acetic acid are well mixed, mica powder is then added and carries out heating mixing, until formation pH value is
4-5 the first solution, lasting stirring；
2）Propyl trimethoxy alkane, methyl-acrylate-butyl acetate copolymer and acrylate are mixed, mixed
Add in the first solution under stirring after uniformly, persistently stirred under conditions of 40-60 DEG C, form the second solution；
3）Transparent powder, auxiliary agent and blue pigment are added in the second solution in sequence, 3-4h is stirred under conditions of 70r/min,
Coating liquid is obtained after filtering solid contaminants.
More specifically, in step 1）In, the temperature of the mixing is 65 DEG C, mixing time 42min.
More specifically, in step 2）In, described whipping temp is 52 DEG C.
More specifically, in step 3）In, described mixing time is 3.2h.
Above-mentioned technical proposal is beneficial in that：
It is first obtained special base eyeglass and coating the invention provides a kind of myopia motion Sunglasses lenses sun clips and its production technology
Liquid, then using makes base eyeglass be impregnated in coating liquid, then by alkali process, rinsing, drying, refrigerating work procedure, coating liquid is existed
Base lens surface forms coat, then it is cut, you can obtains myopia motion Sunglasses lenses sun clips；Due to being to be strict with base
The production technology of eyeglass, the proportioning of coating liquid and preparation technology, especially make the proportioning of coating liquid, and the present invention is with silica
Based on, the compositions such as transparent powder, the copolymerization of methacrylate-acrylic acid butyl ester, acrylate, mica powder are with the addition of, are divided into two
The first solution and the second solution is made in individual step respectively, and transparent powder, auxiliary agent and blue pigment are added on the basis of the second solution, and
The proportional quantity of the every kind of component of lattice control and the technological parameter of each operation, it is anti-to be avoided that other occur in process for individual components
Should, with the effect that this makes form " Synergistic " between component, increase substantially the quality of coat, the formation painting on base eyeglass
After coating, the hardness of product can be increased substantially（Wearability）, while also there is excellent toughness, impact resistant capability and perspective
Rate.
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that retouched
The embodiment stated is part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to protection of the present invention
Scope.
Embodiment
Embodiment 1
A kind of myopia motion Sunglasses lenses sun clips, including base eyeglass and coated in the coat on base eyeglass,
The raw material of described base eyeglass include cyclic structure diamines, nylon 12, corundum fine powder, antioxidant, age resistor and
Molecular weight regulator；Described cyclic structure diamines and the mol ratio of nylon 12 are 1：1；
Wherein：Described corundum fine powder, antioxidant, age resistor, molecular weight regulator are respectively cyclic structure diamines and poly- 12
98%, 3%, 0.02%, the 4% of lactams mass ratio；
Described coat includes silica 1 9.4wt%, acetic acid 1.3wt%, transparent powder 7wt%, propyl trimethoxy alkane
26wt%, methacrylate-acrylic acid butyl ester copolymer-1 2wt%, acrylate 7.6wt%, mica powder 14wt%, blue pigment
0.9wt%, remaining is auxiliary agent.
Preferably, between the perspective rate of the base eyeglass is 8-18 ° or between 18-42 °.
A kind of production technology of myopia motion Sunglasses lenses sun clips, comprises the following steps：
1）First base eyeglass and coating liquid is made in substep；
2）Obtained base eyeglass is immersed in coating liquid, then by alkali process, rinsing, drying, refrigerating work procedure, makes coating
Liquid forms coat in base lens surface；
3）Base eyeglass with coat is cut, obtains myopia motion Sunglasses lenses sun clips.
Specifically, the preparation of the base eyeglass comprises the following steps：
1）Cyclic structure diamines, nylon 12 and molecular weight regulator are added in reactor, are heated to seething with excitement, so
After neutralize into salt, obtain salting liquid；
2）Antioxidant and age resistor are added in reactor simultaneously and carried out, then under conditions of 60r/min, is slowly added to just
Beautiful fine powder, increasing temperature and pressure is reheated, reactor pressure is maintained at 2.8Mpa, and temperature in the kettle is 245 DEG C, keeps 5-10min；
3）Reactor is depressured with 0.01-0.03 Mpa/min speed, until normal pressure, then carries out heating up for second,
Make temperature in the kettle that 1.2-2h be exhausted at a temperature of being maintained at 300 DEG C, add CO2, kettle internal pressure power is maintained at 0.3Mpa, go out
Expect blank, obtain base lens blank；
4）Base eyeglass is obtained after being surface-treated to base lens blank.
Specifically, the preparation of the coating liquid comprises the following steps：
1）Silica and acetic acid are well mixed, mica powder is then added and carries out heating mixing, until formation pH value is
4-5 the first solution, lasting stirring；
2）Propyl trimethoxy alkane, methyl-acrylate-butyl acetate copolymer and acrylate are mixed, mixed
Add in the first solution under stirring after uniformly, persistently stirred under conditions of 50 DEG C, form the second solution；
3）Transparent powder, auxiliary agent and blue pigment are added in the second solution in sequence, 3.2h is stirred under conditions of 70r/min,
Coating liquid is obtained after filtering solid contaminants.
Preferably, in step 1）In, the temperature of the mixing is 65 DEG C, mixing time 42min.
Embodiment 2
A kind of myopia motion Sunglasses lenses sun clips and its production technology as described in Example 1, which part process can also use with
Lower technique：
In base eyeglass, described corundum fine powder, antioxidant, age resistor, molecular weight regulator be respectively cyclic structure diamines and
88%, 4%, 0.02%, the 3% of nylon 12 mass ratio；
In coat, it includes silica 1 8.8wt%, acetic acid 1.7wt%, transparent powder 7wt%, propyl trimethoxy alkane
22wt%, methacrylate-acrylic acid butyl ester copolymer-1 6wt%, acrylate 7.2wt%, mica powder 15wt%, blue pigment
0.6wt%, remaining is auxiliary agent.
The preparation of base eyeglass：
In step 2）In, the reactor pressure is maintained at 3.2Mpa, and temperature in the kettle is 250 DEG C, keeps 5-10min.
In step 3）In, described temperature in the kettle is maintained at 310 DEG C of temperature, and kettle internal pressure power is maintained at 0.1Mpa.
The preparation of coating liquid：
In step 2）In, described whipping temp is 45 DEG C.
In step 3）In, described mixing time is 3.7h.
Embodiment 3
A kind of myopia motion Sunglasses lenses sun clips and its production technology as described in Example 1, which part process can also use with
Lower technique：
In base eyeglass, described corundum fine powder, antioxidant, age resistor, molecular weight regulator be respectively cyclic structure diamines and
120%, 3%, 0.02%, the 5% of nylon 12 mass ratio；
In coat, it include silica 1 8.2wt%, acetic acid 2wt%, transparent powder 7wt%, propyl trimethoxy alkane 21wt%,
Methacrylate-acrylic acid butyl ester copolymer-1 8wt%, acrylate 7wt%, mica powder 15wt%, blue pigment 0.5wt%, remaining is
Auxiliary agent.
The preparation of base eyeglass：
In step 2）In, the reactor pressure is maintained at 3.45Mpa, and temperature in the kettle is 230 DEG C, keeps 5-10min.
In step 3）In, described temperature in the kettle is maintained at 280 DEG C of temperature, and kettle internal pressure power is maintained at 0.4Mpa.
The preparation of coating liquid：
In step 2）In, described whipping temp is 40 DEG C.
In step 3）In, described mixing time is 4h.
Embodiment 4
A kind of myopia motion Sunglasses lenses sun clips and its production technology as described in Example 1, which part process can also use with
Lower technique：
In base eyeglass, described corundum fine powder, antioxidant, age resistor, molecular weight regulator be respectively cyclic structure diamines and
80%, 5%, 0.02%, the 3% of nylon 12 mass ratio；
In coat, it include silica 20wt%, acetic acid 0.5wt%, transparent powder 7wt%, propyl trimethoxy alkane 27wt%,
Methacrylate-acrylic acid butyl ester copolymer-1 2wt%, acrylate 8wt%, mica powder 12wt%, blue pigment 1.2wt%, remaining is
Auxiliary agent.
The preparation of base eyeglass：
In step 2）In, the reactor pressure is maintained at 2.2Mpa, and temperature in the kettle is 260 DEG C, keeps 5-10min.
In step 3）In, described temperature in the kettle is maintained at 320 DEG C of temperature, and kettle internal pressure power is maintained at 0.1Mpa.
The preparation of coating liquid：
In step 2）In, described whipping temp is 60 DEG C.
In step 3）In, described mixing time is 3h.
The technical scheme is that special base eyeglass and coating liquid is first made, base is then made using ordinary operation mode
Eyeglass impregnates in coating liquid, then by alkali process, rinsing, drying, refrigerating work procedure, coating liquid is formed in base lens surface and apply
Coating, then it is cut, you can obtain myopia motion Sunglasses lenses sun clips；It is technically characterized in that to be the life for being strict with base eyeglass
The proportioning and preparation technology of production. art, coating liquid, especially make the proportioning of coating liquid, the present invention be based on silica,
The compositions such as transparent powder, the copolymerization of methacrylate-acrylic acid butyl ester, acrylate, mica powder are with the addition of, are divided into two steps point
Not Zhi get the first solution and the second solution, transparent powder, auxiliary agent and blue pigment are added on the basis of the second solution, and lattice control is every
The proportional quantity of kind component and the technological parameter of each operation, are avoided that other reactions occur in process for individual components, are made with this
The effect of " Synergistic " can be formed between component, increases substantially the quality of coat, after forming coat on base eyeglass, energy
Enough increase substantially the hardness of product（Wearability）, while also there is excellent perspective rate, further, since being to use cyclic structure
Then diamines, nylon 12 with the addition of corundum fine powder, can so increase substantially the tough of product as key component
Property and impact resistant capability, specific performance is as described in following performance test.
Performance test：
Experiment one
Test objective：Tested for the wearability of final lens product.
Test sample：It is produced by the present invention myopia motion Sunglasses lenses sun clips, using common hardening liquid coat after Sunglasses lenses sun clips,
Common Sunglasses lenses sun clips（Without hardening liquid）.
Test method：Execution standard GB10810.5-2012 of the present invention, tested in strict accordance with standard requirement.
Standard requirement：After grinding operations, should not there are visible cut abrasion and wear surface in the range of eyeglass friction, and
Eyeglass with " wear-resisting " requirement, haze value answer≤0.8%.
Result of the test：After grinding operations, the haze value of each eyeglass is as shown in table 1：
Table 1
In being tested more than, the wherein equal no marking in four repeated sampling surfaces and wear surface of product one and product two, product three
Surface there is obvious cut.
Note：Products of the repetition 1-4 of product one obtained by aforementioned four embodiment of the present invention, the repetition 1-4 of product two
For using four repeated samplings of the Sunglasses lenses sun clips after the coating of common hardening liquid, the repetition 1-4 of product three is common Sunglasses lenses sun clips
Four repeated samplings.
Conclusion (of pressure testing)：
By result of the test as can be seen that by the myopia motion Sunglasses lenses sun clips obtained by the present invention, i.e. coat proportioning includes
Silica 1 8.2-20wt%, acetic acid 0.5-2wt%, transparent powder 7wt%, propyl trimethoxy alkane 21-27wt%, methacrylic acid
Ester-butyl acrylate copolymer-1 2-18wt%, acrylate 7-8wt%, mica powder 12-15wt% and blue pigment 0.5-1.2wt%, its
Remaining is auxiliary agent；In the preparation of base eyeglass, in step 2）In, the pressure of the reactor is 2.2-3.45Mpa, and temperature in the kettle is
230-260 DEG C, 5-10min is kept, in step 3）In, the secondary temperature elevation temperature of the reactor is maintained at 280-320 DEG C, in kettle
Pressure is maintained at 0.1-0.4Mpa；In the preparation of coating liquid, in step 1）In, the temperature of the mixing is 65 DEG C, is stirred
It is 42min to mix the time, in step 2）In, described whipping temp is 40-60 DEG C, in step 3）In, described mixing time is
3-4h；The wearability of obtained myopia motion Sunglasses lenses sun clips is above existing product, wherein with scheme system described in embodiment 1
The lens performance obtained is optimal, and haze value only reaches 0.2, obvious compared to existing product, lifting.
Experiment two
Test objective：Tested for the coat adhesive force of final lens product.
Test sample：Myopia motion Sunglasses lenses sun clips produced by the present invention.
Test method：Execution standard GB10810.4-2012 of the present invention, tested in strict accordance with standard requirement.
Standard requirement：After experiment, there should not be any one grid to be entirely stripped, the number of squares for having part to peel off answers ＜ 15%.
Result of the test：Result of the test is as shown in table 2.
Table 2
Note：In being tested more than, serial 1-4 is respectively the product obtained by four embodiments of the invention, and it is each implementation to repeat 1-4
Four repeated samplings of product obtained by example.
Conclusion (of pressure testing)：
By result of the test as can be seen that meeting state through product, its coat adhesive force obtained by four embodiments of the invention
Family's standard requirement, wherein the technical scheme described in embodiment one, i.e. coat proportioning include silica 1 9.4wt%, second
Sour 1.3wt%, transparent powder 7wt%, propyl trimethoxy alkane 26wt%, methacrylate-acrylic acid butyl ester copolymer-1 2wt%, propylene
Acid esters 7.6wt%, mica powder 14wt%, blue pigment 0.9wt%, remaining is auxiliary agent；In the preparation of base eyeglass, in step 2）In, institute
The pressure for stating reactor is 2.8Mpa, and temperature in the kettle is 245 DEG C, 5-10min is kept, in step 3）In, the two of the reactor
Secondary warming temperature is maintained at 300 DEG C, and kettle internal pressure power is maintained at 0.3Mpa；In the preparation of coating liquid, in step 1）In, it is described mixed
The temperature for closing stirring is 65 DEG C, mixing time 42min, in step 2）In, described whipping temp is 52 DEG C, in step 3）
In, described mixing time is 3.2h；The performance of obtained product is optimal.
In addition, low-temperature test and high temperature are carried out to four kinds of motion Sunglasses lenses sun clips obtained by four embodiments of the invention simultaneously
Experiment, the equal no cracking of lens surface after experiment, phenomena such as coming off, also correspond to standard requirement.
Claims (10)
- A kind of 1. myopia motion Sunglasses lenses sun clips, it is characterised in that：It is using PA12 as base eyeglass, and is coated with base eyeglass The coat of base eyeglass abrasive resistance can be improved.
- A kind of 2. myopia motion Sunglasses lenses sun clips as claimed in claim 1, it is characterised in that：The raw material of described base eyeglass include cyclic structure diamines, nylon 12, corundum fine powder, antioxidant, age resistor and Molecular weight regulator；Described cyclic structure diamines and the mol ratio of nylon 12 are 1：1；Wherein：Described corundum fine powder, antioxidant, age resistor, molecular weight regulator are respectively cyclic structure diamines and poly- 12 80-120%, 3-5% of lactams mass ratio, 0.02%, 3-5%；Described coat includes silica 1 8.2-20wt%, acetic acid 0.5-2wt%, transparent powder 7wt%, propyl trimethoxy alkane 21-27wt%, methacrylate-acrylic acid butyl ester copolymer-1 2-18wt%, acrylate 7-8wt%, mica powder 12-15wt% and Blue pigment 0.5-1.2wt%, remaining is auxiliary agent.
- A kind of 3. myopia motion Sunglasses lenses sun clips as claimed in claim 2, it is characterised in that：The perspective rate of the base eyeglass is 8- Between 18 ° or between 18-42 °.
- A kind of 4. myopia motion Sunglasses lenses sun clips as claimed in claim 2, it is characterised in that：In base eyeglass, described corundum Fine powder, antioxidant, age resistor, molecular weight regulator be respectively cyclic structure diamines and nylon 12 mass ratio 98%, 3%、0.02%、4%。
- A kind of 5. myopia motion Sunglasses lenses sun clips as claimed in claim 2, it is characterised in that：Described coat includes titanium dioxide Silicon 19.4wt%, acetic acid 1.3wt%, transparent powder 7wt%, propyl trimethoxy alkane 26wt%, methacrylate-acrylic acid butyl ester are total to Poly- 12wt%, acrylate 7.6wt%, mica powder 14wt%, blue pigment 0.9wt%, remaining is auxiliary agent.
- 6. the production technology of a kind of myopia motion Sunglasses lenses sun clips as claimed in claim 1, it is characterised in that including following step Suddenly：1）First base eyeglass and coating liquid is made in substep；2）Obtained base eyeglass is immersed in coating liquid, then by alkali process, rinsing, drying, refrigerating work procedure, makes coating Liquid forms coat in base lens surface；3）Base eyeglass with coat is cut, obtains myopia motion Sunglasses lenses sun clips.
- 7. the production technology of a kind of myopia motion Sunglasses lenses sun clips as claimed in claim 6, it is characterised in that the base eyeglass Preparation comprises the following steps：1）Cyclic structure diamines, nylon 12 and molecular weight regulator are added in reactor, are heated to seething with excitement, so After neutralize into salt, obtain salting liquid；2）Antioxidant and age resistor are added in reactor simultaneously and carried out, then under conditions of 60r/min, is slowly added to just Beautiful fine powder, increasing temperature and pressure is reheated, reactor pressure is maintained at 2.2-3.45Mpa, and temperature in the kettle is 230-260 DEG C, keeps 5- 10min；3）Reactor is depressured with 0.01-0.03 Mpa/min speed, until normal pressure, then carries out heating up for second, Make temperature in the kettle that 1.2-2h be exhausted at a temperature of being maintained at 280-320 DEG C, add CO2, kettle internal pressure power is maintained at 0.1- 0.4Mpa, discharge blank, obtains base lens blank；4）Base eyeglass is obtained after being surface-treated to base lens blank.
- A kind of 8. production technology of myopia motion Sunglasses lenses sun clips as claimed in claim 7, it is characterised in that：In step 2）In, The pressure of the reactor is 2.8Mpa, and temperature in the kettle is 245 DEG C, keeps 5-10min.
- A kind of 9. production technology of myopia motion Sunglasses lenses sun clips as claimed in claim 7, it is characterised in that：In step 3）In, The secondary temperature elevation temperature of the reactor is maintained at 300 DEG C, and kettle internal pressure power is maintained at 0.3Mpa.
- A kind of 10. production technology of myopia motion Sunglasses lenses sun clips as claimed in claim 6, it is characterised in that the coating liquid Preparation comprise the following steps：1）Silica and acetic acid are well mixed, mica powder is then added and carries out heating mixing, until formation pH value is 4-5 the first solution, lasting stirring；2）Propyl trimethoxy alkane, methyl-acrylate-butyl acetate copolymer and acrylate are mixed, mixed Add in the first solution under stirring after uniformly, persistently stirred under conditions of 40-60 DEG C, form the second solution；3）Transparent powder, auxiliary agent and blue pigment are added in the second solution in sequence, 3-4h is stirred under conditions of 70r/min, Coating liquid is obtained after filtering solid contaminants.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504072A (en) * | 2018-07-23 | 2019-03-22 | 广州市辉乐医药科技有限公司 | A kind of eyeglass of high visible light multistage protection laser |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201698107U (en) * | 2010-06-12 | 2011-01-05 | 厦门腾诺光学科技有限公司 | Wear-resistant spectacles lens structure |
| CN103381684A (en) * | 2012-05-04 | 2013-11-06 | 埃西勒国际通用光学公司 | Abrasion-resistant film and ophthalmic lens containing same |
| CN104133300A (en) * | 2014-08-06 | 2014-11-05 | 瑞安市嘉崎偏光镜片有限公司 | Eyeglasses of sunglasses |
| CN105487255A (en) * | 2015-12-31 | 2016-04-13 | 奥特路（漳州）光学科技有限公司 | Sterilization wear-resisting lens and manufacturing method thereof |
| CN105860401A (en) * | 2016-06-21 | 2016-08-17 | 浙江工贸职业技术学院 | Wear-resistant resin spectacle lens and preparation technology thereof |
| CN107065043A (en) * | 2016-11-14 | 2017-08-18 | 吴国强 | A kind of anti-dizzy optical complex optics and preparation method |
| CN107286836A (en) * | 2017-06-02 | 2017-10-24 | 广东北玻电子玻璃有限公司 | A kind of anti-glare coating liquid and preparation method thereof |
-
2017
- 2017-10-29 CN CN201711032031.5A patent/CN107656380B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201698107U (en) * | 2010-06-12 | 2011-01-05 | 厦门腾诺光学科技有限公司 | Wear-resistant spectacles lens structure |
| CN103381684A (en) * | 2012-05-04 | 2013-11-06 | 埃西勒国际通用光学公司 | Abrasion-resistant film and ophthalmic lens containing same |
| CN104133300A (en) * | 2014-08-06 | 2014-11-05 | 瑞安市嘉崎偏光镜片有限公司 | Eyeglasses of sunglasses |
| CN105487255A (en) * | 2015-12-31 | 2016-04-13 | 奥特路（漳州）光学科技有限公司 | Sterilization wear-resisting lens and manufacturing method thereof |
| CN105860401A (en) * | 2016-06-21 | 2016-08-17 | 浙江工贸职业技术学院 | Wear-resistant resin spectacle lens and preparation technology thereof |
| CN107065043A (en) * | 2016-11-14 | 2017-08-18 | 吴国强 | A kind of anti-dizzy optical complex optics and preparation method |
| CN107286836A (en) * | 2017-06-02 | 2017-10-24 | 广东北玻电子玻璃有限公司 | A kind of anti-glare coating liquid and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504072A (en) * | 2018-07-23 | 2019-03-22 | 广州市辉乐医药科技有限公司 | A kind of eyeglass of high visible light multistage protection laser |
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Effective date of registration: 20190717 Address after: Wenyuan Industrial Park, Taiwanese Investment Zone, Zhangzhou City, Fujian Province, 363100 Applicant after: Zhangzhou Jie Ao Optical Technology Co., Ltd. Address before: Room 902, 234 Jiangshnli, Huli District, Xiamen City, Fujian Province, 361000 Applicant before: Wu Guoqiang |
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