CN107215011A - 一种基于石墨烯复合纤维的复合织物及其制作方法 - Google Patents
一种基于石墨烯复合纤维的复合织物及其制作方法 Download PDFInfo
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Abstract
一种基于石墨烯复合纤维的复合织物及制作方法,织物由表面层、中间粘合层和基布功能层组成,表面层为3D直立棉泡沫,中间粘合层为SBS树脂,基布功能层为相变纤维和石墨烯复合纤维混合的水刺非织造材料,方法包括步骤:将石墨烯复合纤维和相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以0/100、20/80、50/50、80/20、100/0不同配比称重;混合、开松、均匀梳理平行铺网;水刺后烘干;将3D直立棉固定在玻璃板上,将打孔钢板压在3D直立棉上并用刷子均匀涂刮最后烘干;将复合材料在190℃以下重复两次定位冷压压模;将压模处理后的物料经修剪制成模杯。本发明织物具有手感柔软、透气性好、吸湿性好,不易黄变,穿着舒适的优点,且兼具远红外、防紫外线、防静电,满足功能需求。
Description
技术领域:
本发明属于纺织技术复合材料领域,具体涉及一种基于石墨烯复合纤维的复合织物及其制作方法。
背景技术:
随着生活水平的提高,女性对内衣的诉求已不单单停留在外观上,而是更加关注内衣的健康、安全、舒适。模杯文胸罩杯材质多为海绵,传统的海绵主要是以聚氨酯为主材料制成,生产过程中会挥发大量有毒刺激性气体,生产工艺不环保,而且不能回收利用,难以处理,对环境的危害极大。其次产品的透气性、散热性能较差以及在除臭、抗菌、抗硬化和抗氧化等方面的功能不足。随着人们环保意识的增强和对舒适性要求的提高,它的应用受到了一些新型替代材料的挑战。
石墨烯/再生纤维素复合纤维较普通再生纤维素纤维除具有更优异的机械性能和热稳定性能,还具有良好的功能性,比如良好的防紫外线性能、阻燃性能、抗静电性能和远红外性能,在功能纺织品领域展示出良好的应用前景。
相变纤维可以利用相变材料的固-液、固-固相变的热转换从周围环境吸收或释放大量的热量,从而保持自身温度相对恒定,减缓皮肤温度的变化,使穿着者具有舒适感。
3D立体直立棉非织造材料的主体纤维网不是水平排列,而是垂直上下排列。与传统衬垫材料海绵相比,具有不黄变、透气性好、尺寸稳定等特点,它的废弃物可回收利用,适应环保低碳社会的消费理念,但由于其功能性的缺乏限制其进一步的应用。
目前,各大内衣品牌推出的新型环保文胸,是在传统软质聚氨酯原料中加入大豆油、蓖麻油等天然植物油,与质地更加柔软,耐黄性更好,制成的模杯文胸更加环保舒适。或者采用喷胶棉与针刺棉材料来代替海绵泡沫材料,但应用效果不是很理想,有待完善。也有直接以3D直立棉作为衬垫,虽然透气性好,且不易黄变,但存在舒适性不足,稳定性差等方面的缺点,而且大部分此类材料没有具备一定的功能性,无法满足终端产品的一些功能性需求。
因此,针对上述技术问题,有必要提供一种新型的基于石墨烯复合纤维的复合织物及其制作方法,以解决现有技术中的问题。
发明内容:
本发明的目的在于提供一种基于石墨烯复合纤维的复合织物及其制作方法,该复合材料具有手感柔软、透气性好、吸湿性好,不易黄变,穿着舒适的优点,且兼具远红外、防紫外线、防静电功能。
为实现上述目的,本发明采取的技术方案为:一种基于石墨烯复合纤维的复合织物,其由表面层、中间粘合层和基布功能层组成,所述表面层为3D直立棉泡沫,所述中间粘合层为SBS树脂,所述基布功能层为相变纤维和石墨烯复合纤维混合形成的具有一定面密度的水刺非织造材料。
本发明中的一种基于石墨烯复合纤维的复合织物进一步设置为:所述的3D直立棉泡沫为一种环保型非织造立体材料,材料具有海绵状的三维立体构造的直立纤维网结构或蜂窝状纤维网结构。
本发明中的一种基于石墨烯复合纤维的复合织物进一步设置为:所述的3D直立棉的基础重量为270g/m2。
本发明中的一种基于石墨烯复合纤维的复合织物进一步设置为:所述基布功能层为相变纤维和石墨烯复合纤维以一定配比混合形成的水刺非织造材料,其中,相变纤维和石墨烯复合纤维的配比的选择是0/100或20/80或50/50或80/20或100/0。
本发明中的一种基于石墨烯复合纤维的复合织物进一步设置为:所述基布功能层的基础重量范围是从50g/m2到100g/m2。
本发明中的一种基于石墨烯复合纤维的复合织物进一步设置为:所述水刺非织造材料为平行铺网所得。
为实现上述目的,本发明采取的制作方法技术方案为:一种基于石墨烯复合纤维的复合织物的制作方法,该方法包括以下步骤:
a.将石墨烯复合纤维和相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以0/100、20/80、50/50、80/20、100/0五种不同配比进行称重;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯。
与现有技术相比,本发明具有如下有益效果:制取的多功能复合材料以3D直立棉作为表层,具有良好的吸湿透气性、手感柔软,而且采用石墨烯水刺布作为功能基布层,增加了材料的远红外、防紫外线、防静电性能,同时生产工艺简单,易于操作,便于大批量生产。
附图说明:
图1为本发明基于石墨烯复合纤维的复合织物的结构模型。
具体实施方式:
本发明公开了一种基于石墨烯复合纤维的复合织物及其制作方法,该复合材料具有手感柔软、透气性好、吸湿性好,不易黄变,穿着舒适的优点,且兼具远红外、防紫外线、防静电功能。
下面通过具体实施例对本发明所述的一种基于石墨烯复合纤维的复合织物作进一步的详细描述。
如图1所示,一种基于石墨烯复合纤维的复合织物,其由表面层、中间粘合层和基布功能层组成,所述表面层为3D直立棉泡沫,所述中间粘合层为无毒无害透气柔软的SBS树脂,所述基布功能层为相变纤维和石墨烯复合纤维混合形成的具有一定面密度的水刺非织造材料。该复合织物具有手感柔软、透气性好、吸湿性好,不易黄变,穿着舒适的优点,且兼具远红外、防紫外线、防静电,满足功能需求。
所述的3D直立棉为一种新型的环保型非织造立体材料,材料具有如海绵状的三维立体构造的直立纤维网结构或蜂窝状纤维网结构。所述的3D直立棉的基础重量为270g/m2。
所述的基布功能层为相变纤维和石墨烯复合纤维以一定配比混合形成的水刺非织造材料,其中,相变纤维和石墨烯复合纤维的配比的选择是0/100或20/80或50/50或80/20或100/0,所述基布功能层的基础重量范围是从50g/m2到100g/m2。
所述的中间粘合层选用的SBS树脂,安全环保,无毒无害,轻薄柔软透气。所述水刺非织造材料为平行铺网所得。
本发明还公开了一种上述的基于石墨烯复合纤维的复合织物的制作方法,该方法包括以下步骤:
a.将石墨烯复合纤维和相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以0/100、20/80、50/50、80/20、100/0五种不同配比进行称重;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯。
另一种优化方案,由于上述采用的石墨烯复合纤维石墨烯含量为0.5%,功能性有限,故采用了石墨烯含量为1%的石墨烯复合纤维,与相变纤维以50/50配比进行上述a-f步骤。
图1所示的基于石墨烯复合纤维的复合织物,其表层3D直立棉由昆山腾飞科技有限公司提供,功能层中相变纤维和石墨烯复合纤维均由山东海龙股份有限公司提供。石墨烯复合纤维38mm×1.87dtex,石墨烯含量0.5%;石墨烯复合纤维38mm×1.87dtex,石墨烯含量1%;相变纤维为38mm×1.67dtex。中间层SBS树脂由杭州汉特化工有限公司提供。
下面将通过几个具体的实施例对本发明的技术方案进行详细说明。
实施例一
所述功能层基布为100%相变纤维水刺非织造材料,不含石墨烯复合纤维,这组主要作为对比试样,具体操作步骤如下
a.将相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以0/100配比进行称重,具体分别称取11.7g、15.6g、19.5g;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯,并对其编号为1-1#、1-2#、1-3#。
实施例二,
所述功能层基布为20%/80%石墨烯复合纤维/相变纤维水刺非织造材料,具体操作步骤如下:
a.将石墨烯复合纤维和相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以20%/80%配比进行称重,具体分别称取2.36g/9.36g、3.12g/12.48g、3.9g/156g;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干。其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯,并对其编号为2-1#、2-2#、2-3#。
实施例三
所述功能层基布为50%/50%石墨烯复合纤维/相变纤维水刺非织造材料,具体操作步骤如下:
a.将石墨烯复合纤维相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以50%/50%配比进行称重,具体分别称取5.85g/5.85g、7.8g/7.8g、9.75g/9.75g;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯,并对其编号为3-1#、3-2#、3-3#。
实施例四
所述功能层基布为80%/20%石墨烯复合纤维/相变纤维水刺非织造材料,具体操作步骤如下:
a.将石墨烯复合纤维相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以80%/20%配比进行称重,具体分别称取9.36g/2.34g、12.48g/3.12g、15.6g/3.9g;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干。其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯,并对其编号为4-1#、4-2#、4-3#。
实施例五
所述功能层基布为100%石墨烯复合纤维水刺非织造材料,具体操作步骤如下:
a.将石墨烯复合纤维按照60g/m2、80g/m2、100g/m2的平方米克重以80%/20%配比进行称重,具体分别称取11.7g、15.6g、19.5g;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到Fieissner Aquajet型水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动,否则胶粘剂将会出现不匀;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯,并对其编号为5-1#、5-2#、5-3#。
应用例
对实施例1~5制备的复合材料进行性能测试,测试方法如下:
其中远红外性能测试依据GB/T 30127-2013《纺织品远红外性能的检测和评价》;防紫外线性能依据GB/T 18830-2002《纺织品防紫外线性能的评定》;静电性能依据GB/T12703.1-2008《纺织品静电性能的评定静电压半衰期》;透气性测试依据GB/T 5453-1997芯吸效应依据FZ/T 01071-2008《纺织品毛细效应试验方法》;根据GB/T 18318-2001对试样进行测试柔软性。依据GB/T 11048-2008《纺织品生理舒适性稳态条件下热阻和湿阻的测定》。
结果参见表1,表1为本发明实施例及比较例制备的复合材料的性能测试结果。
表1本发明实施例及比较例制备的复合试样的性能测试结果
由表1可知,本发明提供的实施例4和实施例5的基于石墨烯的多功能复合材料在远红外性能、抗紫外辐射性能、防静电性能等方面具有较大的提高。
与现有技术相比,本发明具有如下有益效果:制取的多功能复合材料以3D直立棉作为表层,具有良好的吸湿透气性、手感柔软,而且采用石墨烯水刺布作为功能基布层,增加了材料的远红外、防紫外线、防静电性能,同时生产工艺简单,易于操作,便于大批量生产。
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下还可以作出若干改进,这些改进也应视为本发明的保护范围。
Claims (7)
1.一种基于石墨烯复合纤维的复合织物,其特征在于:其由表面层、中间粘合层和基布功能层组成,所述表面层为3D直立棉泡沫,所述中间粘合层为SBS树脂,所述基布功能层为相变纤维和石墨烯复合纤维混合形成的具有一定面密度的水刺非织造材料。
2.如权利要求1所述的一种基于石墨烯复合纤维的复合织物,其特征在于:所述的3D直立棉泡沫为一种环保型非织造立体材料,材料具有海绵状的三维立体构造的直立纤维网结构或蜂窝状纤维网结构。
3.如权利要求2所述的一种基于石墨烯复合纤维的复合织物,其特征在于:所述的3D直立棉的基础重量为270g/m2。
4.如权利要求1所述的一种基于石墨烯复合纤维的复合织物,其特征在于:所述基布功能层为相变纤维和石墨烯复合纤维以一定配比混合形成的水刺非织造材料,其中,相变纤维和石墨烯复合纤维的配比的选择是0/100或20/80或50/50或80/20或100/0。
5.如权利要求4所述的一种基于石墨烯复合纤维的复合织物,其特征在于:所述基布功能层的基础重量范围是从50g/m2到100g/m2。
6.如权利要求1所述的一种基于石墨烯复合纤维的复合织物,其特征在于:所述水刺非织造材料为平行铺网所得。
7.一种基于石墨烯复合纤维的复合织物的制作方法,其特征在于:该方法包括以下步骤:
a.将石墨烯复合纤维和相变纤维按照60g/m2、80g/m2、100g/m2的平方米克重以0/100、20/80、50/50、80/20、100/0五种不同配比进行称重;
b.将称好的纤维在梳理机上进行混合、开松、均匀梳理平行铺网,其中梳理道数为3道;
c.将铺好的纤网送到水刺机水刺,采用5道水刺头水刺,第一道为预湿水刺,剩下4道为正反面水刺,最后烘干,其中水针板的规格为孔距0.6mm、孔径0.12mm,喷水孔形状使用的是圆锥收缩型;
d.将3D直立棉放平并且固定在玻璃板上,将所需打孔钢板压在3D直立棉上,然后用刷子将配好的胶粘剂按照单位面积涂胶量100g/m2在打孔钢板上均匀涂刮一层,将打孔钢板移开,再将水刺非织造材料平放置在3D直立棉泡沫上,加轻压,最后烘干,用刷子刷涂时注意匀速操作,刷子的左右两端要同步运动;
e.将c中贴合好的复合材料在190℃以下定位冷压压模,重复两次冷压压模处理,每次2-3分钟;
f.将d中压模处理后的物料经修剪制成模杯。
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---|---|---|---|---|
CN110344178A (zh) * | 2019-07-24 | 2019-10-18 | 深圳全棉时代科技有限公司 | 模杯针刺成型方法、模杯针刺模具及模杯针刺设备 |
CN111005161A (zh) * | 2019-12-24 | 2020-04-14 | 广州市中诚新型材料科技有限公司 | 一种石墨烯多功能超细纤维多层次无纺布及其制备方法 |
CN111041710A (zh) * | 2019-12-24 | 2020-04-21 | 广州市中诚新型材料科技有限公司 | 一种石墨烯多功能超细纤维多层次无纺布及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101713121A (zh) * | 2008-10-07 | 2010-05-26 | 东纶科技实业有限公司 | 双组份复合纤维弹性非织造布及其加工方法 |
CN103431529A (zh) * | 2013-08-16 | 2013-12-11 | 苏州美山子制衣有限公司 | 一种高温水浆印文胸模杯及其制作方法 |
CN104146356A (zh) * | 2014-07-30 | 2014-11-19 | 滁州惠智科技服务有限公司 | 一种多功能服装材料及其制造方法 |
CN104432600A (zh) * | 2014-11-28 | 2015-03-25 | 苏州美山子制衣有限公司 | 一种内设佳美兜的文胸模杯及其制作方法 |
CN104451925A (zh) * | 2014-11-21 | 2015-03-25 | 东华大学 | 一种水溶性聚合物/石墨烯复合纤维及其制备方法和应用 |
CN106319710A (zh) * | 2016-09-30 | 2017-01-11 | 无锡市长安曙光手套厂 | 一种复合纺织材料及制备方法 |
CN106435814A (zh) * | 2016-09-09 | 2017-02-22 | 泉州信和石墨烯研究院有限公司 | 一种石墨烯保暖内衣面料的制备方法 |
-
2017
- 2017-05-08 CN CN201710317950.0A patent/CN107215011A/zh active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101713121A (zh) * | 2008-10-07 | 2010-05-26 | 东纶科技实业有限公司 | 双组份复合纤维弹性非织造布及其加工方法 |
CN103431529A (zh) * | 2013-08-16 | 2013-12-11 | 苏州美山子制衣有限公司 | 一种高温水浆印文胸模杯及其制作方法 |
CN104146356A (zh) * | 2014-07-30 | 2014-11-19 | 滁州惠智科技服务有限公司 | 一种多功能服装材料及其制造方法 |
CN104451925A (zh) * | 2014-11-21 | 2015-03-25 | 东华大学 | 一种水溶性聚合物/石墨烯复合纤维及其制备方法和应用 |
CN104432600A (zh) * | 2014-11-28 | 2015-03-25 | 苏州美山子制衣有限公司 | 一种内设佳美兜的文胸模杯及其制作方法 |
CN106435814A (zh) * | 2016-09-09 | 2017-02-22 | 泉州信和石墨烯研究院有限公司 | 一种石墨烯保暖内衣面料的制备方法 |
CN106319710A (zh) * | 2016-09-30 | 2017-01-11 | 无锡市长安曙光手套厂 | 一种复合纺织材料及制备方法 |
Non-Patent Citations (2)
Title |
---|
宗亚宁: "《纺织材料学》", 30 June 2013 * |
曹国兰等: "浅谈新材料在文胸中的应用", 《国际纺织导报》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110344178A (zh) * | 2019-07-24 | 2019-10-18 | 深圳全棉时代科技有限公司 | 模杯针刺成型方法、模杯针刺模具及模杯针刺设备 |
CN110344178B (zh) * | 2019-07-24 | 2024-04-16 | 深圳全棉时代科技有限公司 | 模杯针刺成型方法、模杯针刺模具及模杯针刺设备 |
CN111005161A (zh) * | 2019-12-24 | 2020-04-14 | 广州市中诚新型材料科技有限公司 | 一种石墨烯多功能超细纤维多层次无纺布及其制备方法 |
CN111041710A (zh) * | 2019-12-24 | 2020-04-21 | 广州市中诚新型材料科技有限公司 | 一种石墨烯多功能超细纤维多层次无纺布及其制备方法 |
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