CN107128045A - A kind of new Grass Silage Films - Google Patents

A kind of new Grass Silage Films Download PDF

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Publication number
CN107128045A
CN107128045A CN201710272558.9A CN201710272558A CN107128045A CN 107128045 A CN107128045 A CN 107128045A CN 201710272558 A CN201710272558 A CN 201710272558A CN 107128045 A CN107128045 A CN 107128045A
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CN
China
Prior art keywords
masterbatch
top layer
intermediate layer
grass silage
ldpe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710272558.9A
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Chinese (zh)
Inventor
彭秀菊
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Xinchang Ruisen Agricultural Products Co Ltd
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Xinchang Ruisen Agricultural Products Co Ltd
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Filing date
Publication date
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Priority to CN201710272558.9A priority Critical patent/CN107128045A/en
Publication of CN107128045A publication Critical patent/CN107128045A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/71Resistive to light or to UV
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

Landscapes

  • Storage Of Harvested Produce (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to agricultural film production technical field, and in particular to a kind of new Grass Silage Films.The film is made up of intermediate layer (2) and first, second top layer (1,3);Linear metallocene low density polyethylene (LDPE), 12 21% modified thickening masterbatch, 3 5% anti-aging mother material composition of the intermediate layer (2) by mass fraction for 76 85%;First, second top layer (1,3) is by 66 75% linear metallocene low density polyethylene (LDPE), and 8 12% rutile-type brightens shading masterbatch, 5 12% anti-aging mother material, 2 5% weather-proof masterbatch, 2 5% ultraviolet-resistance masterbatch composition.

Description

A kind of new Grass Silage Films
Technical field
The present invention relates to agricultural film production technical field, and in particular to a kind of new Grass Silage Films.
Background technology
Grass silage is the fermentation using microorganism, long-term one kind for preserving green forage nutrition it is simple, economical and Reliable method, is the effective measures for ensureing domestic animal stable market supply roughage all the year round.China is in the Yuan Dynasty《Wang Zhennong books》Deng in book Just there is the record of alfalfa ensilage fermentation process, ensiling turns into an important technology in animal husbandry now.
Grass silage has many good qualities:It can not only be preserved with the mode of modulation hay, it is also possible to which the mode of ensiling is carried out Storage;The loss of nutriment can be reduced, if silage facilities are advanced, technical operation is suitable, and the loss of nutrition is usually no more than 15%, and keep in green grass more than 90% carrotene;Ensilage can improve the palatability and digestibility of domestic animal, through micro- life Ensiling herbage after thing fermentation has sour fragrance, and soft and succulency, palatability is good, can stimulate the appetite of domestic animal, lactic acid is to intestines in addition The stimulation of stomach significantly improves digestibility, and ensiling can make herbage be maintained at blue or green fresh state for a long time, rich in protein, Duo Zhongwei Raw element and mineral matter, can provide the feed of high nutritive value for domestic animal all the year round;The limit of the manufacturing process of ensiling not climate condition System, overcast and rainy season or bad weather, it is difficult to when modulating hay, make ensiling influence smaller.
The key of grass silage process is to maintain anaerobic environment, and if air penetrates into, saccharomycete and mould will breed, The not only sugar and lactic acid in consumption ensiling herbage, and decomposition of cellulose and other cell wall constituents, produces harmful metabolism Material, causes temperature and pH value to rise, makes the dry and nutrient of ensiling herbage all by very big loss.The light transmittance of membrane material Also the effect of grass silage is influenceed, transmitted light can promote the loss of some nutriments, herbage is used as with transparent plastic sheeting Ensiling film is failure.Therefore, the plastic sheeting for grass silage plays very important effect to the effect of grass silage. But, the grass silage film sold in the market has that tensile strength is not high, paracentesis resistance is poor, thickness and uneven thickness, Tack is bad, the shortcomings of causing that broken rate is very high, sealing is poor, light transmittance is strong, effectively can not keep anaerobic environment.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of tensile strength is high, paracentesis resistance and good seal performance Grass silage dedicated film.
To realize object above, the present invention is achieved by the following technical programs:
A kind of new Grass Silage Films, the film is made up of intermediate layer and first, second top layer;The intermediate layer is by quality Fraction is 76-85% linear metallocene low density polyethylene (LDPE), 12-21% modified thickening masterbatch, 3-5% anti-aging mother material Composition;First, second top layer is by 66-75% linear metallocene low density polyethylene (LDPE), 8-12% rutile-type increasing White shading masterbatch, 5-12% anti-aging mother material, 2-5% weather-proof masterbatch, 2-5% ultraviolet-resistance masterbatch composition.
Further, the intermediate layer is by linear metallocene low density polyethylene (LDPE), 15- of the mass fraction for 78-82% 18% modified thickening masterbatch, 3-4% anti-aging mother material composition;First, second top layer by 69-73% linear cyclopentadienyl Metal low density polyethylene (LDPE), 9-11% rutile-type brightens shading masterbatch, and 6-10% anti-aging mother material, 3-5%'s is weather-proof Masterbatch, 3-5% ultraviolet-resistance masterbatch composition.
Further, the intermediate layer by mass fraction for 80.5% linear metallocene low density polyethylene (LDPE), 15.7% Modified thickening masterbatch, 3.8% anti-aging mother material composition;First, second top layer by 72.3% linear metallocene Low density polyethylene (LDPE), 9.5% rutile-type brightens shading masterbatch, 8.4% anti-aging mother material, 4.9% weather-proof masterbatch, 4.9% ultraviolet-resistance masterbatch composition.
Further, the film is arranged in order composition by the first top layer, intermediate layer and the second top layer;The film is by the first table The thickness ratio on layer, intermediate layer and the second top layer is 1-2:1-3:1-2.
Further, the film is arranged in order composition by the first top layer, intermediate layer and the second top layer;The film is by the first table The thickness ratio on layer, intermediate layer and the second top layer is 1:2:1.
Further, the thickness of the film is 0.023-0.028mm.
Beneficial effects of the present invention are:
1. the Grass Silage Films surfaces externally and internally toughness that the present invention is provided, packs airtight, waterproof, inside can be formed Anaerobic environment, can contribute to animal digestion, improves dairy fat content by the controlled anaerobic fermentation of ensiling into the feed of high nutrition, Highest can per day milk-increasing quantity 5-7kg/ heads.
2. the Grass Silage Films tensile strength that the present invention is provided is high, elongation is big, and paracentesis resistance is strong, it is ensured that grass silage It is not damaged in journey, feed qualitative change is prevented effectively from, goes mouldy or nutriment is lost in and causes economic loss.
3. the grass silage thickness that the present invention is provided is uniform, light transmittance is low, it is to avoid heat accumulation;PH value temperature, service life It is long, it can be exposed to greatest extent in ultraviolet 3 years.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, come for those of ordinary skill in the art Say, on the premise of not paying creative work, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is structural representation of the invention.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the implementation of the present invention Example, the technical scheme in the embodiment of the present invention is clearly and completely described.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under the premise of creative work is not made, belongs to protection of the present invention Scope.
Embodiment 1:
A kind of new Grass Silage Films, thickness ratio is 1:2:Arrange successively on 1 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;Linear metallocene low density polyethylene (LDPE), 15.7% modified thickening of the intermediate layer 2 by mass fraction for 80.5% Masterbatch, 3.8% anti-aging mother material composition;Gather by 72.3% linear metallocene low-density on first, second top layer 1,3 Ethene, 9.5% rutile-type brightens shading masterbatch, 8.4% anti-aging mother material, 4.9% weather-proof masterbatch, 4.9% it is anti- Ultraviolet masterbatch is constituted, and the new grass silage film thickness of product is 0.025mm.
Embodiment 2:
A kind of new Grass Silage Films, thickness ratio is 1:3:Arrange successively on 1 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 78% linear metallocene low density polyethylene (LDPE), 18% modified thickening it is female Material, 4% anti-aging mother material composition;First, second top layer 1,3 by 69% linear metallocene low density polyethylene (LDPE), 11% rutile-type brightens shading masterbatch, 10% anti-aging mother material, 5% weather-proof masterbatch, 5% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.023mm.
Embodiment 3:
A kind of new Grass Silage Films, thickness ratio is 1:1:Arrange successively on 1 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 76% linear metallocene low density polyethylene (LDPE), 21% modified thickening it is female Material, 3% anti-aging mother material composition;First, second top layer 1,3 by 66% linear metallocene low density polyethylene (LDPE), 12% rutile-type brightens shading masterbatch, 12% anti-aging mother material, 5% weather-proof masterbatch, 5% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.028mm.
Embodiment 4:
A kind of new Grass Silage Films, thickness ratio is 2:1:Arrange successively on 2 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 82% linear metallocene low density polyethylene (LDPE), 15% modified thickening it is female Material, 3% anti-aging mother material composition;First, second top layer 1,3 by 73% linear metallocene low density polyethylene (LDPE), 9% rutile-type brightens shading masterbatch, 8% anti-aging mother material, 5% weather-proof masterbatch, 5% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.024mm.
Embodiment 5:
A kind of new Grass Silage Films, thickness ratio is 2:3:Arrange successively on 2 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 85% linear metallocene low density polyethylene (LDPE), 12% modified thickening it is female Material, 3% anti-aging mother material composition;First, second top layer 1,3 by 74% linear metallocene low density polyethylene (LDPE), 12% rutile-type brightens shading masterbatch, 10% anti-aging mother material, 2% weather-proof masterbatch, 2% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.027mm.
Embodiment 6:
A kind of new Grass Silage Films, thickness ratio is 1:2:Arrange successively on 2 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 80% linear metallocene low density polyethylene (LDPE), 15% modified thickening it is female Material, 5% anti-aging mother material composition;First, second top layer 1,3 by 74% linear metallocene low density polyethylene (LDPE), 8% rutile-type brightens shading masterbatch, 10% anti-aging mother material, 5% weather-proof masterbatch, 3% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.024mm.
Embodiment 7:
A kind of new Grass Silage Films, thickness ratio is 2:3:Arrange successively on 1 the first top layer 1, the top layer 3 of intermediate layer 2 and second Row composition;The intermediate layer 2 by mass fraction for 77% linear metallocene low density polyethylene (LDPE), 18% modified thickening it is female Material, 5% anti-aging mother material composition;First, second top layer 1,3 by 75% linear metallocene low density polyethylene (LDPE), 11% rutile-type brightens shading masterbatch, 6% anti-aging mother material, 3% weather-proof masterbatch, 5% ultraviolet-resistance masterbatch group Into the new grass silage film thickness of product is 0.028mm.
Performance test is carried out to Grass Silage Films made from previous embodiment, test execution standard is as follows:
Tensile strength and elongation at break perform standard using UNE-EN-ISO 527-1/3;Tearing strength uses UNE 53220, part.2 perform standard;Impact strength uses 53219, method A to perform standard;To greatest extent exposed to ultraviolet Line performs standard using SGS;Stiction force performs standard using SUV;The performance test results are as shown in the table:
Application Example is as follows:By (dry and wet) herbage, maize straw, melon seedling, peanut seedling etc. crush and rub, compress bundling Afterwards, the herbage film cladding of longitudinal direction appropriate size, laterally winds 4-5 layers, between layers overlapping 15-20cm, if moistureproof storage After dry month, you can change into the animal feed of high nutrition, the Silaging method is realized compared with horizental silo for economic benefit, the former Extra earning Euro/ox more than 170 more than the latter.
Beneficial effects of the present invention are:
1. the Grass Silage Films surfaces externally and internally toughness that the present invention is provided, packs airtight, waterproof, internal anaerobism is formed Environment, can contribute to animal digestion, improves dairy fat content, highest by the controlled anaerobic fermentation of ensiling into the feed of high nutrition Can per day milk-increasing quantity 5-7kg/ heads.
2. the Grass Silage Films tensile strength that the present invention is provided is high, elongation is big, and paracentesis resistance is strong, it is ensured that grass silage It is not damaged in journey, feed qualitative change is prevented effectively from, goes mouldy or nutriment is lost in and causes economic loss.
3. the grass silage thickness that the present invention is provided is uniform, light transmittance is low, it is to avoid heat accumulation;PH value temperature, service life It is long, it can be exposed to greatest extent in ultraviolet 3 years.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a kind of new Grass Silage Films, it is characterised in that the film is by intermediate layer (2) and first, second top layer (1,3) group Into;Modification of the intermediate layer (2) by mass fraction for 76-85% linear metallocene low density polyethylene (LDPE), 12-21% is viscosified Masterbatch, 3-5% anti-aging mother material composition;First, second top layer (1,3) is low close by 66-75% linear metallocene Polyethylene is spent, 8-12% rutile-type brightens shading masterbatch, 5-12% anti-aging mother material, 2-5% weather-proof masterbatch, 2- 5% ultraviolet-resistance masterbatch composition.
2. new Grass Silage Films as claimed in claim 1, it is characterised in that the intermediate layer (2) is 78- by mass fraction 82% linear metallocene low density polyethylene (LDPE), 15-18% modified thickening masterbatch, 3-4% anti-aging mother material composition;It is described First, second top layer (1,3) is by 69-73% linear metallocene low density polyethylene (LDPE), and 9-11% rutile-type brightens screening Light masterbatch, 6-10% anti-aging mother material, 3-5% weather-proof masterbatch, 3-5% ultraviolet-resistance masterbatch composition.
3. new Grass Silage Films as claimed in claim 1, it is characterised in that the intermediate layer (2) is by mass fraction 80.5% linear metallocene low density polyethylene (LDPE), 15.7% modified thickening masterbatch, 3.8% anti-aging mother material composition;Institute First, second top layer (1,3) is stated by 72.3% linear metallocene low density polyethylene (LDPE), 9.5% rutile-type brightens screening Light masterbatch, 8.4% anti-aging mother material, 4.9% weather-proof masterbatch, 4.9% ultraviolet-resistance masterbatch composition.
4. the new Grass Silage Films as any one of claim 1-3, it is characterised in that the film is by the first top layer (1), intermediate layer (2) and the second top layer (3) are arranged in order composition;The film is by the first top layer (1), intermediate layer (2) and the second table The thickness ratio of layer (3) is 1-2:1-3:1-2.
5. new Grass Silage Films as described in any of claims 4, it is characterised in that the film by the first top layer (1), Intermediate layer (2) and the second top layer (3) are arranged in order composition;The film is by the first top layer (1), intermediate layer (2) and the second top layer (3) Thickness ratio be 1:2:1.
6. the new Grass Silage Films as any one of claim 1-3, it is characterised in that the thickness of the film is 0.023-0.028mm。
CN201710272558.9A 2017-04-24 2017-04-24 A kind of new Grass Silage Films Pending CN107128045A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN107826030A (en) * 2017-12-04 2018-03-23 上官余博 A kind of structure, formula and the work flow of goods vehicle rain-proof film
CN111016370A (en) * 2019-12-24 2020-04-17 厦门聚富塑胶制品有限公司 Silage packaging film and preparation method thereof
CN114619739A (en) * 2022-03-11 2022-06-14 揭阳市千田塑胶有限公司 Rainproof reflective film for truck and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107826030A (en) * 2017-12-04 2018-03-23 上官余博 A kind of structure, formula and the work flow of goods vehicle rain-proof film
CN107826030B (en) * 2017-12-04 2023-05-30 上官余博 Structural formula of rain-proof film for freight automobile
CN111016370A (en) * 2019-12-24 2020-04-17 厦门聚富塑胶制品有限公司 Silage packaging film and preparation method thereof
CN114619739A (en) * 2022-03-11 2022-06-14 揭阳市千田塑胶有限公司 Rainproof reflective film for truck and preparation method thereof
CN114619739B (en) * 2022-03-11 2023-12-19 揭阳市千田塑胶有限公司 Rainproof reflective film for trucks and preparation method thereof

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Application publication date: 20170905