CN105906972B - A kind of preparation method of bathroom temperature-sensitive slipmat - Google Patents
A kind of preparation method of bathroom temperature-sensitive slipmat Download PDFInfo
- Publication number
- CN105906972B CN105906972B CN201610258058.5A CN201610258058A CN105906972B CN 105906972 B CN105906972 B CN 105906972B CN 201610258058 A CN201610258058 A CN 201610258058A CN 105906972 B CN105906972 B CN 105906972B
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- raw material
- slipmat
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010408 film Substances 0.000 claims description 22
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 10
- 238000002845 discoloration Methods 0.000 claims description 10
- 238000007639 printing Methods 0.000 claims description 10
- 229920002799 BoPET Polymers 0.000 claims description 6
- 229960000892 attapulgite Drugs 0.000 claims description 6
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 6
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 6
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 6
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052625 palygorskite Inorganic materials 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 4
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000010409 thin film Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- -1 benzene Diformazan dioctyl phthalate Chemical compound 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000001291 vacuum drying Methods 0.000 claims description 2
- 239000010721 machine oil Substances 0.000 claims 1
- 238000004804 winding Methods 0.000 abstract description 4
- 241000446313 Lamella Species 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 230000003628 erosive effect Effects 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011540 sensing material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Cosmetics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Floor Finish (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of preparation method of bathroom temperature-sensitive slipmat, the slipmat of the present invention is exclusively used in bathroom, using color shifting ink as printed film, hot water is flowed on the pad as the change of temperature becomes other colors, it can effectively prevent from scalding, slipmat of the present invention has good stability and hydrophobicity, stable pattern is formed on Corvic surface, it is the pattern resistance to erosion, resistance to greasy dirt, heat-resist, polymer molecular chain cross winding in raw material of the present invention improves the mechanical property and weathering stability of finished product in the lamella of modified filler.
Description
Technical field
The invention mainly relates to the bathroom Slippery proof foot pad in plastic applications, more particularly to a kind of system of bathroom temperature-sensitive slipmat
Preparation Method.
Background technology
Slipmat is modern house, and bathroom durable commodity indispensable in arranging, it, which is not only acted as, prevents user
Sliding effect, more it is increasingly becoming a part for household bathroom Integral decoration.
Igelite：Its poor heat resistance, intensity are affected by temperature larger, and intensity when at -20 DEG C than 20 DEG C declines
80%.Therefore, film article is not easy to take care of at low temperature and used；Soft goods temperature in use is no more than 45 DEG C, and boardy product is no more than
60 DEG C, during long-term illumination can aging become fragile, heat endurance is poor, is contacted with insect prevention medicaments such as organic solvent and naphthalenes, can produce it is tacky,
Phenomena such as fusing, and easily absorb peculiar smell.In bath mat industry, the raw material be used to prepare bath mats.
Heat discoloration pigment：It is a kind of pigment that color change occurs at a certain temperature, due to pigment manufacture craft phase
Complicated and temperature-sensitive molecule is enlivened, so causing use cost generally more much higher than general pigment.With regard in bath mats industry, adopting
With traditional temperature-sensitive slipmat preparation method such as：Silk-screen, bat printing (reference：201420535514.2《Slipmat》), oil spout or
Among preparation process, temperature-sensitive toner is directly added to (reference among product：200920263461.2《A kind of heat discoloration bath
Pad》), Exterior color of products unshapeliness can be all caused etc. technique, service life is short, and defective products rate is high and does not meet economic benefit
Height prepares cost.Wiping among immersion or routine use such as through long-time warm water can all cause the sense being attached on bath mats
Adiabator comes off, desalination, or even the failure of bath mats temperature sensing function；Also part producing business sets groove to inlay on common anti-slip pad
Embedding temperature-sensitive color lump and then paste layer of transparent film on surface and come off problem to solve temperature-sensitive layer, but this method complex production process is answered
It is miscellaneous, and the possibility to come off be present in the film that surface is covered, so not meeting economic effect prepared by large-scale production now equally
Benefit.
PET transfer films:It is recyclable with excellent physical property, chemical property and dimensional stability, the transparency, ink
Property, easy adherence is good, is easy to print, is easy to be molded, and stamping resistance is good, fabulous ink adhesion and repeatability, using temperature-sensitive
Changing colour, the transfer film prepared is temperature sensitive, and color is gorgeous well-balanced, and sensitive pigments are fully utilized.
The content of the invention
The object of the invention is just to provide a kind of preparation method of bathroom temperature-sensitive slipmat.
The present invention is achieved by the following technical solutions：
A kind of preparation method of bathroom temperature-sensitive slipmat, it is characterised in that comprise the following steps：
(1) printed film is prepared：Heat discoloration ink is injected in the oil groove of large-sized print machine, using corresponding printing technology
Deposited to according to predetermined pattern in PET film, after being completed for printing, PET film is sent into baking oven and dried, taken out, it is then more right,
Recycle Special-purpose cutting machine device that printing thin film sub-cut into predetermined size, is produced the heat discoloration printed film；
(2) it is molded：What the raw material that injection uses was made up of the raw material of following weight parts：Polyvinyl chloride resin powder 50-60,
DOTP 20-30, soybean oil 10-12, dibutyl sebacate 5-7, naphthenic soap 1-2, modified filler 1-2；
Described modified filler is made up of the raw material of following weight parts：
Formamide 3-4, attapulgite 50-60, silane coupler kh560 0.1-0.2, hydroxypropyl methyl cellulose 5-7；
Above-mentioned hydroxypropyl methyl cellulose is added in 20-26 times of deionized water of its weight, stirred, adds formyl
Amine, warming temperature are 50-60 DEG C, add attapulgite, insulated and stirred 1-2 hours, add above-mentioned silane coupler kh560,
600-700 revs/min of stirring 4-10 minute, filtering, vacuum drying 20-30 minutes at 100-105 DEG C will be deposited in, must be modified and fill out
Material；
Above-mentioned injection raw material is mixed, stirred, hopper is sent into, screw in injection molding machine temperature is heated to 165-180 DEG C,
The above-mentioned printed film cut is attached on mould, by above-mentioned injection raw material by being injected into the above-mentioned mould for posting printed film
In, pressurize matched moulds, solidifies, and the demoulding, pet films is torn, trim unnecessary flash, produce the finished product.
What described heat discoloration ink was made up of the raw material of following weight parts：The carbon diacetylenic acid 10- of 10,12- 25
20th, tung oil 50-60, rosin 1-2, precipitated calcium carbonate 17-20, barium sulfate 10-13, lignin 0.3-0.5, pigment 2-3.
It is an advantage of the invention that：
The slipmat of the present invention is exclusively used in bathroom, using color shifting ink as printed film, makes color shifting ink by injection
Melt with the high warm of slipmat inserts and mix, lamella of the polymer molecular chain cross winding after cooling in raw material in slipmat
In.The colour change function of slipmat of the present invention is provided with good stability and wear-resisting because heat melts rear strand cross winding
Property, in the art pattern of slipmat surface set, resistance to erosion, easy cleaning, temperature sensing material use and remain to keep its active throughout the year
Colour change function is constant.
Consumer, such as infant or old man are damaged in order to avoid too high or too low due to shower water temperature, passed
Unite on the basis of the anti-skidding design of bath mats, slipmat is occurred under particular water temperature using the characteristic of heat discoloration ink set
Color or the pre- pattern for first passing through Art Design can play a part of warning and beautifying bathroom to user.Whole product exists
20 DEG C -60 DEG C change with the change of water temperature, can become different color or predetermined pattern, so that consumer is washing one's hair
Pleasant easily mood is produced among bath process.
Polymer molecular chain cross winding in raw material of the present invention improves the power of finished product again in the lamella of modified filler
Learn performance and resistance to oxidation stability.The technique productions cost is low, and product yield is high.
Embodiment
Embodiment 1
A kind of preparation method of bathroom temperature-sensitive slipmat, comprises the following steps：
(1) printed film is prepared：Prepare printed film：By in the oil groove of heat discoloration ink injection large-sized print machine, use
Corresponding printing technology is deposited in PET film according to predetermined pattern, after being completed for printing, PET film is sent into baking oven and dried, is taken
Go out, it is then more right, recycle Special-purpose cutting machine device that printing thin film sub-cut into predetermined size, is produced the heat discoloration stamp
Film；
(2) it is molded：What the raw material that injection uses was made up of the raw material of following weight parts：It is polyvinyl chloride resin powder 60, right
Dioctyl phthalate 30, soybean oil 12, dibutyl sebacate 7, naphthenic soap 2, modified filler 1；
Described modified filler is made up of the raw material of following weight parts：
Formamide 4, attapulgite 60, silane coupler kh560 0.2, hydroxypropyl methyl cellulose 7；
Above-mentioned hydroxypropyl methyl cellulose is added in 26 times of deionized waters of its weight, stirred, adds formamide,
Warming temperature is 60 DEG C, adds attapulgite, insulated and stirred 2 hours, adds above-mentioned silane coupler kh560,600 revs/min are stirred
Mix 10 minutes, filter, will be deposited at 105 DEG C and be dried in vacuo 30 minutes, obtain modified filler；
Above-mentioned injection raw material is mixed, stirred, hopper is sent into, screw in injection molding machine temperature is heated to 180 DEG C, will be upper
State the printed film cut to be attached on mould, by above-mentioned injection raw material by being injected into the above-mentioned mould for posting printed film, add
Press-fitting mould, solidify, the demoulding, pet films are torn, trim unnecessary flash, produce the finished product.
Claims (1)
1. a kind of preparation method of bathroom temperature-sensitive slipmat, it is characterised in that comprise the following steps：
(1) printed film is prepared：By heat discoloration ink injection large-sized print machine oil groove in, using corresponding printing technology according to
Predetermined pattern is deposited in PET film, after being completed for printing, PET film is sent into baking oven and dried, taken out, then proofread, then
Printing thin film sub-cut is produced the heat discoloration printed film into predetermined size using Special-purpose cutting machine device；
(2) it is molded：What the raw material that injection uses was made up of the raw material of following weight parts：Polyvinyl chloride resin powder 50-60, to benzene
Diformazan dioctyl phthalate 20-30, soybean oil 10-12, dibutyl sebacate 5-7, naphthenic soap 1-2, modified filler 1-2；
Described modified filler is made up of the raw material of following weight parts：
Formamide 3-4, attapulgite 50-60, silane coupler kh560 0.1-0.2, hydroxypropyl methyl cellulose 5-7；
Above-mentioned hydroxypropyl methyl cellulose is added in 20-26 times of deionized water of its weight, stirred, adds formamide,
Warming temperature is 50-60 DEG C, adds attapulgite, insulated and stirred 1-2 hours, adds above-mentioned silane coupler kh560,600-
700 revs/min of stirring 4-10 minutes, filtering, vacuum drying 20-30 minutes at 100-105 DEG C will be deposited in, obtain modified filler；
Above-mentioned injection raw material is mixed, stirred, hopper is sent into, screw in injection molding machine temperature is heated to 165-180 DEG C, will be upper
State the printed film cut to be attached on mould, by above-mentioned injection raw material by being injected into the above-mentioned mould for posting printed film, add
Press-fitting mould, solidify, the demoulding, pet films are torn, trim unnecessary flash, produce the finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610258058.5A CN105906972B (en) | 2016-04-21 | 2016-04-21 | A kind of preparation method of bathroom temperature-sensitive slipmat |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610258058.5A CN105906972B (en) | 2016-04-21 | 2016-04-21 | A kind of preparation method of bathroom temperature-sensitive slipmat |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105906972A CN105906972A (en) | 2016-08-31 |
| CN105906972B true CN105906972B (en) | 2018-03-30 |
Family
ID=56751844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610258058.5A Active CN105906972B (en) | 2016-04-21 | 2016-04-21 | A kind of preparation method of bathroom temperature-sensitive slipmat |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105906972B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115519865A (en) * | 2022-10-19 | 2022-12-27 | 东莞市悠悠美居家居制造有限公司 | Three-dimensional printing tablecloth and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10296767A (en) * | 1997-02-28 | 1998-11-10 | Chuko Kasei Kogyo Kk | Press cushioning material |
| CN101240097B (en) * | 2007-02-06 | 2010-08-25 | 中国石油化工股份有限公司 | Special-purpose material for automatic foot-mat and preparation method thereof |
| CN102259518B (en) * | 2011-06-11 | 2013-06-05 | 东莞晨光印刷有限公司 | Process suitable for printing thermochromic pattern on complex surfaces and tableware |
| CN103205901B (en) * | 2013-04-08 | 2015-05-20 | 浙江深蓝轻纺科技有限公司 | Burnt discoloration synthetic leather and preparation method thereof |
| CN104194459A (en) * | 2014-08-06 | 2014-12-10 | 明光市国星凹土有限公司 | Modified attapulgite packing for coating and preparation method thereof |
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2016
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Effective date of registration: 20200527 Address after: 528300 Guangdong province Foshan city Shunde District Daliang Masahiro Road No. 16 Patentee after: FOSHAN CITY SHUNDE DISTRICT YIDE PLASTIC PRODUCTS Co.,Ltd. Address before: 528300 Guangdong province Foshan city Shunde District Daliang Street South Lake Garden Scenery Xingui Road No. 12 Patentee before: Cai Qixuan |