CN105779159A - 一种柔顺洗衣凝珠及其制备方法 - Google Patents
一种柔顺洗衣凝珠及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种柔顺洗衣凝珠及其制备方法,该洗衣凝珠包括25~35%异构C13脂肪醇聚氧乙烯醚、10~20%脂肪醇聚氧乙烯醚(9EO)、10~20%脂肪醇聚氧乙烯醚硫酸钠、5~10%脂肪醇聚氧乙烯醚(7EO)、1.5~2.5%洗涤增效剂WR、1.5~2.5%异构醇聚氧乙烯醚、0.8~1.5%阳离子柔顺剂、0.02~0.05%杀菌剂、0.5~1.0%微胶囊香精、0.01‑0.03%碱性蛋白酶和20~38%溶剂(丙二醇),具有较强的赋香性、使用安全方便、洗涤能力和柔顺效果较好等特点。
Description
技术领域
本发明涉及一种浓缩型洗衣液,具体地涉及一种柔顺洗衣凝珠。
背景技术
洗衣凝珠是一种专为机洗设计,操作简单,方便不脏手,小小一颗洗衣凝珠能洗一筒衣服。气味芬芳,质地软滑浓稠适中性质温和不伤衣物,特有的低泡浓缩锁色配方,更易漂洗,凝珠遇水即溶无残留,还能有效快速去除顽固污渍让衣物洁净如新。洗衣凝珠的外膜能承受15公斤的重压,同时又遇水即溶、能迅速将"冷艳浓缩"精华中的冷水酶和用于去除深色顽渍的艳色螯合剂融入水中。2010年,由碧浪推出其全新浓缩型洗衣液,这是碧浪进入中国市场来首次推出作为高端洗涤品类的洗衣液。目前国内研究开发出来的洗衣凝珠,其赋香性、洗涤能力和柔顺效果欠佳。因此,开发高效、赋香性和柔顺效果好的洗衣凝珠是必要的,此外,普通液体洗涤剂利用常规表面活性剂和碱性助剂,仅具有洗涤清洁作用,柔顺效果欠佳。
发明内容
针对上述问题,本发明提供了种柔顺洗衣凝珠,解决了洗涤能力和柔顺效果较差的缺点。
为解决上述技术问题,本发明所采用的技术方案是:一种柔顺洗衣凝珠,其包括25~35%异构C13 脂肪醇聚氧乙烯醚、10~20%脂肪醇聚氧乙烯醚(9EO)、10~15%脂肪醇聚氧乙烯醚硫酸钠、5~10%脂肪醇聚氧乙烯醚(7EO)、1.5~2.5 %洗涤增效剂WR、1.5~2.5 %异构醇聚氧乙烯醚、1.0~2.0%阳离子柔顺剂、0.02~0.05%杀菌剂、0.5~1.0%微胶囊香精、0.01-0.03%碱性蛋白酶和20~38 %溶剂(丙二醇)。
进一步地,所述洗涤增效剂选为洗涤增效剂WR和异构醇聚氧乙烯醚混合而成。
进一步地,所述杀菌剂优选为三氯羟基二苯醚或4-氯-3,5-二甲基苯酚。
进一步地,所述阳离子柔顺剂选自山嵛酰胺丙基乙基二甲基胺乙基硫酸盐、季铵盐型、脂肪酸酯型、右蜡型、聚乙烯型、有机硅树脂型等。
一种柔顺洗衣凝珠优选30%异构C13 脂肪醇聚氧乙烯醚、15%脂肪醇聚氧乙烯醚(9EO)、12%脂肪醇聚氧乙烯醚硫酸钠、8%脂肪醇聚氧乙烯醚(7EO)、2%洗涤增效剂WR、2 %异构醇聚氧乙烯醚、1.5%阳离子柔顺剂、0.03%杀菌剂、0.8%微胶囊香精、0.02%碱性蛋白酶和28.65 %溶剂(丙二醇)。
一种上所述的柔顺洗衣凝珠的制备方法,其特征在于包括如下步骤;分别将定量好的脂肪醇聚氧乙烯醚(9EO)、脂肪醇聚氧乙烯醚(7EO)、山嵛酰胺丙基乙基二甲基胺乙基硫酸盐置于烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;分别将定量好的异构C13 脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚硫酸钠、丙二醇、洗涤增效剂WR、异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入定量好的杀菌剂、碱性蛋白酶、微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
由上述对本发明结构的描述可知,和现有技术相比,本发明具有如下优点:
这其中,微胶囊香精是把香精完全包封在一层膜中形成微胶囊的一种技术,直径一般为1~1000纳米,微胶囊香精是微胶囊技术中的一个重要分支,也是微胶囊技术的一个颇为典型的应用,香精香料微胶囊的壁材可依芯材而定,一般要求是材料性能稳定、无毒、无副作用、无刺激性、有配伍性、不影响香精香料的作用,并且要有符合要求的粘度、渗透性、有一定强度和可塑性等,香精经微胶囊化后,由于囊壁的密封作用能够有效抑制香精的挥发损失,提高香精的贮藏和使用的稳定性;能够保护敏感成分,大大提高耐氧、耐光和耐热的能力,增加其在衣物表面中的稳定性,能够使香精具有缓慢释放功能。
洗涤增效剂是通过一系列实验证明有效表面活性剂、洗涤增效剂WR和异构醇聚氧乙烯醚的比例30:1:1时,其洗涤效果可提高35~50%。
阳离子柔顺剂选自山嵛酰胺丙基乙基二甲基胺乙基硫酸盐、季铵盐型、脂肪酸酯型、右蜡型、聚乙烯型、有机硅树脂型等,通过实验发现山嵛酰胺丙基乙基二甲基胺乙基硫酸盐在本配方中柔顺效果最好;
综上本发明具有较强的赋香性、使用安全方便、洗涤能力和柔顺效果较好等特点。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
通过下面说明将对本发明作进一步的了解,但本发明的保护范围不限于此。
异构C13 脂肪醇聚氧乙烯醚属绿色表面活性剂,产品经全球领先的质量和安全服务公司Intertek国际权威检测试认证,符合欧盟、美国及日本的环保要求;性能优良的非离子表面活性剂,可广泛应用于洗涤日化、纺织、皮革以及其他化工行业;是高效的乳化剂、渗透剂和润湿剂,是壬基酚聚氧乙烯醚、三聚磷酸钠等的优良替代品,且与天然醇醚相比其性能也更加优异。
脂肪醇聚氧乙烯醚(9EO)和脂肪醇聚氧乙烯醚(7EO)是一种与其他表面活性剂的配伍性好。对硬水不敏感,低温洗涤性能好的表面活性剂。洗涤行业作为非离子表面活性剂,起乳化,发泡、去污作用。是洗手液、洗衣液、沐浴露、洗衣粉、洗 洁精、金属清洗剂的主要活性成分。
脂肪醇聚氧乙烯醚硫酸钠,易溶于水,具有优良的去污、乳化、发泡性能和抗硬水性能,温和的洗涤性质不会损伤皮肤。使用时请注意:在不含粘度调节剂的情况下,如果要把其稀释为含有30%或60%活性物质的水溶液,常会导致一种粘性高的凝胶。为避免这一现象,正确的方法是将高活性产品加到规定数量的水中去,同时加以搅拌。而不要将水加到高活性原料,否则便可能导致凝胶的形成。
洗涤增效剂WR具有独特的清洁能力,耐酸、耐碱,在各种环境中都能表现出极佳的去垢性能,脱脂力强,具有良好的抗油污再沉积能力和生物降解性。
异构醇聚氧乙烯醚为无色或淡黄色液体,易溶于水,具有优良的乳化、净洗性能。属非离子表面活性剂。可用作分散剂、润湿剂、 渗透剂、 洗涤剂,广泛用于家用洗涤领域。
山嵛酰胺丙基乙基二甲基胺乙基硫酸盐属阳离子表面活性剂,易溶于异丙醇,乙醇,可溶于水,加热后能与其它表面活性剂形成透明溶液,并能与阴离子、阳离子、非离子和两性表面活性剂配伍,具有柔软、抗静电、去污、发泡性能,对液洗、护发产品体系中的油脂、硅油具有显著增效吸附作用,它在广泛的PH范围内都具有良好的稳定性,是一种新型柔顺剂。
4-氯-3,5-二甲基苯酚是防腐剂、杀菌剂。应用于医药、乳剂、化妆品、油墨、胶合板、塑料中,耐热性和耐候性好,该品低毒。小鼠口服LD50为3450mg/kg。
碱性蛋白酶是目前市场上流行的洗涤添加剂,能大幅度提高洗涤去污能力,特别对血渍、汗渍、奶渍、油渍等蛋白类污垢,具有独特的洗涤效果。碱性蛋白酶在技术上采用细菌原生质体诱变处理方法,从国内碱性蛋白菌生产菌2709枯草杆菌中研究选育出若干稳定高性能菌株,在后处理上,采用去渣盐析沉淀法,减少了蛋白酶的杂质含量和产品特有的气味,提高了溶解速度,与洗涤剂有更好的配伍性,延长了保质期。
丙二醇与水、乙醇及多种有机溶剂混溶。在化妆品、牙膏和香皂中可与甘油或山梨醇配合用作润湿剂。在染发剂中用作调湿、匀发剂,也用作防冻剂。在本配方主要作用是防止表活遇水凝胶。
本发明公开了一种柔顺洗衣凝珠,其包括25~35%异构C13 脂肪醇聚氧乙烯醚、10~20%脂肪醇聚氧乙烯醚(9EO)、10~15%脂肪醇聚氧乙烯醚硫酸钠、5~10%脂肪醇聚氧乙烯醚(7EO)、1.5~2.5 %洗涤增效剂WR、1.5~2.5 %异构醇聚氧乙烯醚、1.0~2.0%阳离子柔顺剂、0.02~0.05%杀菌剂、0.5~1.0%微胶囊香精、0.01-0.03%碱性蛋白酶和20~38 %溶剂(丙二醇);所述洗涤增效剂选为洗涤增效剂WR和异构醇聚氧乙烯醚混合而成;所述杀菌剂优选为三氯羟基二苯醚或4-氯-3,5-二甲基苯酚;所述阳离子柔顺剂选自山嵛酰胺丙基乙基二甲基胺乙基硫酸盐、季铵盐型、脂肪酸酯型、右蜡型、聚乙烯型、有机硅树脂型等。
一种上所述的柔顺洗衣凝珠的制备方法,其特征在于包括如下步骤;分别将定量好的脂肪醇聚氧乙烯醚(9EO)、脂肪醇聚氧乙烯醚(7EO)、山嵛酰胺丙基乙基二甲基胺乙基硫酸盐置于烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;分别将定量好的异构C13 脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚硫酸钠、丙二醇、洗涤增效剂WR、异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入定量好的杀菌剂、碱性蛋白酶、微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
实施例
1
分别称取1.5kg脂肪醇聚氧乙烯醚(9EO)、800g脂肪醇聚氧乙烯醚(7EO)、150g山嵛酰胺丙基乙基二甲基胺乙基硫酸盐于3L烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;
分别称取3kg异构C13 脂肪醇聚氧乙烯醚、1.2kg脂肪醇聚氧乙烯醚硫酸钠、2.87kg丙二醇、200g洗涤增效剂WR、200g异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入3g杀菌剂、2g碱性蛋白酶、80g微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;
打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
实施例
2
分别称取1.5kg脂肪醇聚氧乙烯醚(9EO)、800g脂肪醇聚氧乙烯醚(7EO)、150g山嵛酰胺丙基乙基二甲基胺乙基硫酸盐于3L烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;
分别称取3kg异构C13 脂肪醇聚氧乙烯醚、1.2kg脂肪醇聚氧乙烯醚硫酸钠、2.87kg丙二醇、200g洗涤增效剂WR、200g异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入3g杀菌剂、2g碱性蛋白酶、100g普通香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;
打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
实施例
3
分别称取1.5kg脂肪醇聚氧乙烯醚(9EO)、800g脂肪醇聚氧乙烯醚(7EO)、150g季铵盐型阳离子柔顺剂于3L烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;
分别称取3kg异构C13 脂肪醇聚氧乙烯醚、1.2kg脂肪醇聚氧乙烯醚硫酸钠、2.87kg丙二醇、200g洗涤增效剂WR、200g异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入3g杀菌剂、2g碱性蛋白酶、80g微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;
打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
实施例
4
分别称取1.5kg脂肪醇聚氧乙烯醚(9EO)、800g脂肪醇聚氧乙烯醚(7EO)、150g季铵盐型阳离子柔顺剂于3L烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;
分别称取3kg异构C13 脂肪醇聚氧乙烯醚、1.2kg脂肪醇聚氧乙烯醚硫酸钠、2.87kg丙二醇、400g洗涤增效剂WR依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入3g杀菌剂、2g碱性蛋白酶、80g微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;
打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
实施例
5
将实施例1、2、3、4中制得的柔顺洗衣凝珠与市售的碧浪牌洗衣凝珠对比,得到的结果如表1所示:
表1 洗衣凝珠技术性能指标对比分析表
上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受上述实施例的限
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。
Claims (5)
1.一种柔顺洗衣凝珠,其特征在于:其包括25~35%异构C13 脂肪醇聚氧乙烯醚、10~20%脂肪醇聚氧乙烯醚、10~15%脂肪醇聚氧乙烯醚硫酸钠、5~10%脂肪醇聚氧乙烯醚、1.5~2.5 %洗涤增效剂WR、1.5~2.5 %异构醇聚氧乙烯醚、1.0~2.0%阳离子柔顺剂、0.02~0.05%杀菌剂、0.5~1.0%微胶囊香精、0.01-0.03%碱性蛋白酶和20~38 %溶剂。
2.根据权利要求1所述一种柔顺洗衣凝珠,其特征在于:所述洗涤增效剂为洗涤增效剂WR和异构醇聚氧乙烯醚混合而成。
3.根据权利要求1所述一种柔顺洗衣凝珠,其特征在于:所述杀菌剂为三氯羟基二苯醚或4-氯-3,5-二甲基苯酚。
4.根据权利要求1所述一种柔顺洗衣凝珠,其特征在于:所述阳离子柔顺剂选自山嵛酰胺丙基乙基二甲基胺乙基硫酸盐、季铵盐型、脂肪酸酯型、右蜡型、聚乙烯型、有机硅树脂型的其中一种或两种以上。
5.一种如权利要求1所述的柔顺洗衣凝珠的制备方法,其特征在于包括如下步骤;分别将定量好的脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚、山嵛酰胺丙基乙基二甲基胺乙基硫酸盐置于烧杯中,置于45℃水浴锅加热,用玻璃棒搅拌均匀,备用;分别将定量好的异构C13 脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚硫酸钠、丙二醇、洗涤增效剂WR、异构醇聚氧乙烯醚依次加入搅拌桶中,搅拌30分钟,在搅拌下缓慢加入上述烧杯中混合均匀料液,加完搅拌10分钟后依次加入定量好的杀菌剂、碱性蛋白酶、微胶囊香精,搅拌30分钟后停止搅拌,将料液倒入塑料桶中,密封备用;打开塑料桶密封盖,将料液加到洗衣凝珠自动包装机加料口中,进行生产包装。
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101514306A (zh) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | 一种含稳定生物酶络合物和低活性物的织物污垢预处理剂及其制备方法 |
-
2016
- 2016-04-09 CN CN201610216176.XA patent/CN105779159A/zh active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101514306A (zh) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | 一种含稳定生物酶络合物和低活性物的织物污垢预处理剂及其制备方法 |
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