CN105418055B - A kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics and preparation method thereof - Google Patents
A kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics and preparation method thereof Download PDFInfo
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Abstract
The present invention provides a kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics and preparation method thereof, the ceramics are made up of 15 30 parts of nano-calcium carbonate, 35 45 parts of natural clay, sepiolite 24 30, aluminium silicate powder 15 20, barium sulfate 8 12,5 12 parts of paraffin, 25 parts of beeswax, 14 parts of polyethylene, it is frangible to solve conventional domestic ceramics, matter weight, aesthetics not enough etc. technical problem, to improve the performance of traditional ceramics product, reach the intensity for improving ceramics, reduce weight, aesthetics is improved, it is more green.
Description
Technical field
The present invention relates to field of household ceramic, and in particular to a kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics and its
Preparation method.
Background technology
In China, ceramics have very long history, many fields have nowadays been used in, particularly in commodity
In, ceramic is even more to be seen everywhere, and its preparation technology also widely uses in worldwide already, and ceramic ware for daily use is solemn
So turn into a part, panoramic tableware, tea set, all kinds of sanitary equipment etc. indispensable in people's daily life everywhere may be used
See, these ceramics elegant in appearance, various shapes, and mostly different according to purposes, heatproof, wear resistant corrosion resistant can also be prepared
Ceramics, be well received by consumers, but ceramic product universal existence is crisp, not impact resistance, poor toughness, glaze colours are uneven easily de-
Fall, matter weight, the shortcomings of energy consumption is big, lead-indium alloy is higher, cause it damaged tighter in production and transport and application process
Weight, so as to increase production cost, causes to pollute and wastes, therefore there is an urgent need to be improved to its performance, promotes domestic ceramics
Industry develops to high intensity, green direction.Nano-calcium carbonate has the applicating history of 50 years abroad, is widely used in
The industries such as rubber, plastics, papermaking, chemical building material, ink, coating, fluid sealant and adhesive, ceramic row it is not widely used in
Industry, play its advantageous feature.
The content of the invention
It is an object of the present invention to provide a kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics and preparation method thereof,
The conventional domestic ceramics of solution is frangible, matter weight, the technical problems such as aesthetics is inadequate, to improve the performance of traditional ceramics product, reaches
The intensity of ceramics is improved, reduces weight, improves aesthetics, green purpose, to realize the technique effect, the present invention uses
Technical scheme it is as follows:
A kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics is made up of the raw material of following parts by weight:Nano-calcium carbonate
15-30 parts, natural clay 35-45 parts, sepiolite 24-30, aluminium silicate powder 15-20, barium sulfate 8-12, paraffin 5-12 parts, beeswax
2-5 parts, polyethylene 1-4 parts.
A kind of preferable composite nano-calcium carbonate light-weight environment-friendly domestic ceramics is made up of the raw material of following parts by weight:Nanometer
Calcium carbonate 20-25 parts, natural clay 35-40 parts, sepiolite 25-28, aluminium silicate powder 18-20, barium sulfate 10-12, paraffin 8-12
Part, beeswax 3-5 parts, polyethylene 2-4 parts.
A kind of preferred composite nano-calcium carbonate light-weight environment-friendly domestic ceramics is made up of the raw material of following parts by weight:Receive
22 parts of calcium carbonate of rice, 38 parts of natural clay, sepiolite 26, aluminium silicate powder 20, barium sulfate 10,10 parts of paraffin, 4 parts of beeswax, poly- second
2 parts of alkene.
The invention also discloses a kind of preparation method of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics, and it includes following
Step:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh
Sieve;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
Preferred preparation method is:
(1)First sepiolite is crushed, crosses 100 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 350 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-13 hours at a temperature of 1200-1300 DEG C, got product after drying, cleaning, glazing.
The advantage of the invention is that:Using the special performance of nano-calcium carbonate, ceramic intensity and toughness are substantially increased,
With other materials coordinate made of ceramics there is good performance, it is light, uniform color, be also effectively reduced sintering time,
Production power consumption has been saved, it is more environmentally-friendly, without toxic substance, using more trusting.
Therefore, the ceramic that prepared by the present invention is more excellent compared with conventional ceramic performance, and production technology is more simple, has
Wide application value.
Embodiment
Embodiment 1
Take nano-calcium carbonate 15-30 parts, natural clay 35-45 parts, sepiolite 24-30, aluminium silicate powder 15-20, barium sulfate
8-12, paraffin 5-12 parts, beeswax 2-5 parts, polyethylene 1-4 parts, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh
Sieve;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
Embodiment 2
Take nano-calcium carbonate 20-25 parts, natural clay 35-40 parts, sepiolite 25-28, aluminium silicate powder 18-20, barium sulfate
10-12, paraffin 8-12 parts, beeswax 3-5 parts, polyethylene 2-4 parts, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh
Sieve;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
Embodiment 3
Take 22 parts of nano-calcium carbonate, 38 parts of natural clay, sepiolite 26, aluminium silicate powder 20, barium sulfate 10,10 parts of paraffin,
4 parts of beeswax, 2 parts of polyethylene, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh
Sieve;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
Embodiment 4
Take 15 parts of nano-calcium carbonate, 45 parts of natural clay, sepiolite 24, aluminium silicate powder 20, barium sulfate 12,5 parts of paraffin, honeybee
2 parts of wax, 4 parts of polyethylene, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh
Sieve;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
Embodiment 5
Take 22 parts of nano-calcium carbonate, 38 parts of natural clay, sepiolite 26, aluminium silicate powder 20, barium sulfate 10,10 parts of paraffin,
4 parts of beeswax, 2 parts of polyethylene, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 100 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 350 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-13 hours at a temperature of 1200-1300 DEG C, got product after drying, cleaning, glazing.
Embodiment 6
Take nano-calcium carbonate 15-30 parts, natural clay 35-45 parts, sepiolite 24-30, aluminium silicate powder 15-20, barium sulfate
8-12, paraffin 5-12 parts, beeswax 2-5 parts, polyethylene 1-4 parts, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 100 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 350 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-13 hours at a temperature of 1200-1300 DEG C, got product after drying, cleaning, glazing.
Embodiment 7
Take nano-calcium carbonate 20-25 parts, natural clay 35-40 parts, sepiolite 25-28, aluminium silicate powder 18-20, barium sulfate
10-12, paraffin 8-12 parts, beeswax 3-5 parts, polyethylene 2-4 parts, ceramics are prepared using following method:
(1)First sepiolite is crushed, crosses 100 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 350 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, mixing is equal
It is even, add water that embryo material is made, idiosome is obtained through moulding;
(4)Idiosome sinters 10-13 hours at a temperature of 1200-1300 DEG C, got product after drying, cleaning, glazing.
The preferred embodiment for the present invention is explained in detail above, but the invention is not restricted to above-mentioned embodiment,
In those of ordinary skill in the art's possessed knowledge, it can also be made on the premise of present inventive concept is not departed from various
Change, these changes are related to correlation technique well-known to those skilled in the art, and these both fall within the protection model of patent of the present invention
Enclose.
Many other changes and remodeling can be made by not departing from the spirit and scope of the present invention.
It should be appreciated that the invention is not restricted to specific embodiment, the scope of the present invention is defined by the following claims.
Claims (5)
1. a kind of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics, it is characterised in that the ceramics are by the original of following parts by weight
Material is made:Nano-calcium carbonate 15-30 parts, natural clay 35-45 parts, sepiolite 24-30, aluminium silicate powder 15-20, barium sulfate 8-
12nd, paraffin 5-12 parts, beeswax 2-5 parts, polyethylene 1-4 parts.
A kind of 2. composite nano-calcium carbonate light-weight environment-friendly domestic ceramics according to claim 1, it is characterised in that the ceramics
It is made up of the raw material of following parts by weight:Nano-calcium carbonate 20-25 parts, natural clay 35-40 parts, sepiolite 25-28, alumina silicate
Powder 18-20, barium sulfate 10-12, paraffin 8-12 parts, beeswax 3-5 parts, polyethylene 2-4 parts.
A kind of 3. composite nano-calcium carbonate light-weight environment-friendly domestic ceramics according to claim 1, it is characterised in that the ceramics
It is made up of the raw material of following parts by weight:22 parts of nano-calcium carbonate, 38 parts of natural clay, sepiolite 26, aluminium silicate powder 20, sulfuric acid
Barium 10,10 parts of paraffin, 4 parts of beeswax, 2 parts of polyethylene.
4. according to a kind of any described composite nano-calcium carbonate light-weight environment-friendly domestic ceramicses of claim 1-3, its preparation method
Comprise the steps of:
(1)First sepiolite is crushed, crosses 80-120 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 300-400 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, it is well mixed, adds
Embryo material is made in water, and idiosome is obtained through moulding;
(4)Idiosome sinters 10-15 hours at a temperature of 1180-1350 DEG C, got product after drying, cleaning, glazing.
5. a kind of preparation method of composite nano-calcium carbonate light-weight environment-friendly domestic ceramics according to claim 4 includes following
Step:
(1)First sepiolite is crushed, crosses 100 mesh sieves;
(2)Natural clay, sepiolite, aluminium silicate powder, barium sulfate mixing, add in ball mill and grind, cross 350 mesh sieves;
(3)Nano-calcium carbonate, paraffin, beeswax, polyethylene are added into step(1)With(2)In obtained material, it is well mixed, adds
Embryo material is made in water, and idiosome is obtained through moulding;
(4)Idiosome sinters 10-13 hours at a temperature of 1200-1300 DEG C, got product after drying, cleaning, glazing.
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