CN105314947A - Double-component white polymer cement waterproof mortar - Google Patents

Double-component white polymer cement waterproof mortar Download PDF

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Publication number
CN105314947A
CN105314947A CN201510776403.XA CN201510776403A CN105314947A CN 105314947 A CN105314947 A CN 105314947A CN 201510776403 A CN201510776403 A CN 201510776403A CN 105314947 A CN105314947 A CN 105314947A
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China
Prior art keywords
white
component
bicomponent
parts
polymer cement
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CN201510776403.XA
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Chinese (zh)
Inventor
沈恒
王会元
刘金景
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TANGSHAN DONGFANG YUHONG WATERPROOF TECHNOLOGY Co Ltd
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TANGSHAN DONGFANG YUHONG WATERPROOF TECHNOLOGY Co Ltd
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Priority to CN201510776403.XA priority Critical patent/CN105314947A/en
Publication of CN105314947A publication Critical patent/CN105314947A/en
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  • Paints Or Removers (AREA)

Abstract

The invention discloses double-component white polymer cement waterproof mortar which comprises polymer emulsion, an antifoaming agent, a cosolvent, quartz sand, white cement, cellulose ether, and a mildewproof anti-algae agent, wherein a component A comprises the following raw materials in parts by weight: 65-85 parts of polymer emulsion, 1-3 parts of an antifoaming agent, and 6-8 parts of a cosolvent; a component B comprises the following raw materials in parts by weight: 40-60 parts of white cement, 60-65 parts of quartz sand, 0.02-0.05 part of cellulose ether, 0.5-1 part of a water reducing agent and 0.5-1 part of a mildewproof anti-algae agent. The double-component white polymer cement waterproof mortar has excellent bonding strength, waterproof effect and crack resistance, is easy for color modulation, resists mildew and algaes, and is used for decorating and coating various parts soaked in water for a long time.

Description

A kind of bicomponent white Polymer cement materials
Technical field
The present invention relates to construction water proof material field, be specifically related to a kind of bicomponent white Polymer cement materials.
Background technology
Polymer cement materials is for primary structure material with polymer emulsion and cement, interpolation various surfactants stablizes the waterproof paint that filling powder is made through moisture evaporation and hydration reaction, this series products is generally used for the hidden waterproofing work coordinating facing operator guards, such as, for solving roof substrate, waterproof layer, matching between thermal insulation layer and protective layer combines the not high problem of bonding, prevent interlaminar separation and the problem causing heat-insulating property to reduce, denomination of invention is disclose a kind of waterproof polymer mortar in the patent document of " thermal insulation and water proof integrated system of roof covering and constructional method thereof " (Authorization Notice No. is CN101311456B), this mortar has good water resistance, at the northern area of roofing environment relatively dry, the performance of this thermal insulation and water proof integrated system of roof covering waterproof is good, but, in the south that humidity is rainy, when particularly plum rain season arrives, although this thermal insulation and water proof integrated system of roof covering can obtain certain waterproof effect, but owing to being exposed in water for a long time, its waterproof effect and work-ing life will have a greatly reduced quality, and then interlaminar separation can be caused and destroy overall water-repellancy and attractive in appearance.
Summary of the invention
For the defect of prior art, applicant improves system component, by selecting the combination of different polymer emulsion, quartz sand graduation, white cement, under the prerequisite meeting water-proof function requirement, realize toning and the decoration functions of waterproof mortar, simultaneously by adjustment mildew-resistant, algae-resistant material, bicomponent white Polymer cement materials is applicable to soak for a long time the coating moulding at position and decoration.
For achieving the above object, the present invention is achieved through the following technical solutions: this white polymer cement waterproofing mortar is two-component materials, component A is by polymer emulsion, defoamer, solubility promoter forms, B component is by quartz sand, white cement, ether of cellulose, water reducer, the agent of mildew-resistant algae forms, during use, respectively first by component A and B component premix, and then two components are mixed, wherein each constituent mass number is as follows: polymer emulsion 65 ~ 85 parts, defoamer 1 ~ 3 part, solubility promoter 6 ~ 8 parts, quartz sand 60 ~ 65 parts, white cement 40 ~ 60 parts, ether of cellulose 0.02 ~ 0.05 part, water reducer 0.5 ~ 1 part, mildew-resistant algae agent 0.5 ~ 1 part.Above-mentioned composition can meet the technical requirementss such as waterproof, moulding, mildew-resistant, anti-algae simultaneously.
Polymer emulsion available in component A has a variety of, applicant preferably 65 ~ 85 parts polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion or the mixture of the two, this polymer emulsion is the polymer emulsion of being spent by second-order transition temperature-10.The test-results display low-temperature performance of polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion or the mixture of the two, water tolerance and weathering resistance are all good.
B component is mainly another important component part of polymer cement waterproof paint: mineral filler, as cement, quartz sand etc.Wherein, cement is the filler that a kind of activity is larger, the most remarkable to the Effect on Mechanical Properties of water-proof coating.White cement is generally high-alumina cement, and the metal-salt of high price is stronger with the active group crosslinked action of polymkeric substance, and better to the modification of polymkeric substance, therefore, applicant selects 40 ~ 60 parts of white cements, and preferred white cement is Heng Shi whiteness more than 87 32.5 white cement.Applicant selects 60 ~ 65 parts of quartz sands, the mixture of the wherein preferred following combination of quartz sand: 20 ~ 40 order quartz sands, 40 ~ 80 order quartz sands, 80 ~ 120 order quartz sands, 200 order silica powders, 600 order silica powders.
As one of the starting material of waterproof paint, the consumption of auxiliary agent is usually little, but effect is very large.It add defect and the paint marketing that not only can avoid producing much coating, the production of waterproof paint and construction process can be made again to be easy to control simultaneously.And the interpolation of some auxiliary agent can give waterproof paint some special functions.Conventional auxiliary agent has water reducer, solubility promoter, defoamer, antimildew disinfectant etc.Wherein, the defoamer preferably waterborne organic silicon emulsion defoamer of 1 ~ 3 part in component A; Solubility promoter preferably 6 ~ 8 parts propylene glycol, ethanol or both mixtures, in B component, water reducer preferably polycarboxylate water-reducer, the naphthalene water reducer of 0.5 ~ 1 part; Ether of cellulose is 20000 viscosity HEMC, the 60000 viscosity HPMC of 0.02 ~ 0.05 part or the mixture of the two preferably; The agent of mildew-resistant algae preferably 0.5 ~ 1 part pyridines, thiazoles, zinc oxide any one or two or more mixture arbitrarily.
The invention also discloses the preparation method of the said products, comprise the steps: first polymer emulsion, defoamer, solubility promoter to be carried out premix in proportion, make component A; By quartz sand, white cement, ether of cellulose, mildew-resistant algae agent premix in proportion, make B component; Before using, A, B component are carried out used in combination according to ratio requirement.
The invention also discloses the using method of described product, in use product be coated in the surface of cement matrix or by pattern, product carried out coating moulding on cement matrix; After products solidifying, firmly waterproof is overall, to reach the requirement of impervious waterproof and coating decoration moulding to form one at substrate surface; Realize opposing external microbe apposition growth simultaneously, keep the long-acting multiple effect attractive in appearance of decoration.
Applicant by being grouped into the one-tenth of bicomponent white Polymer cement materials, proportioning content improves and optimizes, make the cohesive strength of this waterproof mortar, cracking resistance, waterproof, anti-mildew, anti-algae performance significantly improves, in addition, this waterproof mortar also possesses decoration functions, can meet the demand of the cracking resistance at long-term immersion position, waterproof, anti-mildew, anti-algae, coating moulding and decoration.Meanwhile, bicomponent white Polymer cement materials disclosed by the invention is simple with its preparation technology, easy construction, can directly use on wet base, has good market application foreground and economic benefit.
Embodiment
Embodiment 1:
Prefabricated component A: by Celanese 1350 emulsion of 30kg, the BASF S400 emulsion of 55kg, the defoamer of 2kg, the propylene glycol of 8kg, low speed mixing 20 minutes, packs as component A in dispersator.
Prefabricated B component: by the polycarboxylate water-reducer of the Mierocrystalline cellulose of the white cement of 80 ~ 120 order quartz sands of 40 ~ 80 order quartz sands of 15kg, 40kg, 40kg, 0.03kg, 1kg, the mildew-resistant algae agent of 0.2kg horizontal mixer high speed premix 15 minutes, pack as B component.
The bicomponent white Polymer cement materials that component A and B component constitute, when constructing, carrying out Site according to A:B weight component ratio 1:2.5 and mixing rear use.
Embodiment 2:
Prefabricated component A: by the BASF S400 emulsion of 80kg, the defoamer of 2kg, the propylene glycol of 6kg, the ethanol of 2kg, low speed mixing 20 minutes, packs as component A in dispersator.
Prefabricated B component: by the polycarboxylate water-reducer of the Mierocrystalline cellulose of the white cement of 80 ~ 120 order quartz sands of 40 ~ 80 order quartz sands of 15kg, 40kg, 40kg, 0.02kg, 1kg, the mildew-resistant algae agent of 1kg horizontal mixer high speed premix 15 minutes, pack as B component.
The bicomponent white Polymer cement materials that component A and B component constitute, when constructing, carrying out Site according to A:B weight component ratio 1:3.5 and mixing rear use.
Embodiment 3:
Prefabricated component A: by BASF S400 emulsion, the defoamer of 3kg, the propylene glycol of 8kg of 85kg, low speed mixing 20 minutes, packs as component A in dispersator.
Prefabricated B component: by the polycarboxylate water-reducer of the Mierocrystalline cellulose of the white cement of 80 ~ 120 order quartz sands of 40 ~ 80 order quartz sands of 30kg, 35kg, 50kg, 0.02kg, 1kg, the mildew-resistant algae agent of 0.2kg horizontal mixer high speed premix 15 minutes, pack as B component.
The bicomponent white Polymer cement materials that component A and B component constitute, when constructing, carrying out Site according to A:B weight component ratio 1:4 and mixing rear use.
Mechanical experimental results:
Bicomponent white Polymer cement materials prepared by above-described embodiment 1-3 carry out normal temperature bending property, bonding strength, impervious measure of merit, testing method according to JC/T2090-2011 polymer cement waterproof slurry detection method, as table 1:
Table 1 mechanical experimental results
Project Normal temperature bending property (Ф 10mm) Bonding strength (MPa) Impervious (upstream face MPa)
Embodiment 1 Without cracking 2.20 2.0MPa, 168h, without infiltration
Embodiment 2 Without cracking 2.40 2.0MPa, 168h, without infiltration
Embodiment 3 Without cracking 2.00 2.0MPa, 168h, without infiltration
By above-described embodiment and Mechanics Performance Testing test display thereof, the cohesive strength of waterproof mortar provided by the invention, cracking resistance, waterproof, anti-mildew, anti-algae excellent property and possess decoration functions, can meet the demand of the cracking resistance at long-term immersion position, waterproof, anti-mildew, anti-algae, coating moulding and decoration.Meanwhile, bicomponent white Polymer cement materials disclosed by the invention is simple with its preparation technology, easy construction, can directly use on wet base, has good market application foreground and economic benefit.
Embodiments of the present invention do not limit by above-described embodiment, the change made, modification, substitute, simplify and all should be equivalent embodiment under other any does not deviate from spirit of the present invention and principle, are included within protection scope of the present invention.

Claims (10)

1. a bicomponent white Polymer cement materials, it is characterized in that, this white polymer cement waterproofing mortar is two-component materials, component A is made up of polymer emulsion, defoamer, solubility promoter, B component is made up of quartz sand, white cement, ether of cellulose, water reducer, the agent of mildew-resistant algae, during use, respectively first by component A and B component premix, and then two components are mixed, wherein each constituent mass number is as follows:
Polymer emulsion 65 ~ 85 parts
Defoamer 1 ~ 3 part
Solubility promoter 6 ~ 8 parts
Quartz sand 60 ~ 65 parts
White cement 40 ~ 60 parts
Ether of cellulose 0.02 ~ 0.05 part
Water reducer 0.5 ~ 1 part
Mildew-resistant algae agent 0.5 ~ 1 part.
2. bicomponent white Polymer cement materials according to claim 1, is characterized in that described polymer emulsion is polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion or the mixture of the two.
3. bicomponent white Polymer cement materials according to claim 2, is characterized in that described polymer emulsion is the polymer emulsion of being spent by second-order transition temperature-10.
4. bicomponent white Polymer cement materials according to claim 1, is characterized in that described defoamer is waterborne organic silicon emulsion defoamer.
5. bicomponent white Polymer cement materials according to claim 1, is characterized in that described solubility promoter is propylene glycol, ethanol or both mixtures.
6. bicomponent white Polymer cement materials according to claim 1, is characterized in that described quartz sand is selected from the mixture of following combination: 20 ~ 40 order quartz sands, 40 ~ 80 order quartz sands, 80 ~ 120 order quartz sands, 200 order silica powders, 600 order silica powders.
7. bicomponent white Polymer cement materials according to claim 1, is characterized in that white cement is Heng Shi whiteness more than 87 32.5 white cement.
8. bicomponent white Polymer cement materials according to claim 1, is characterized in that described ether of cellulose is 20000 viscosity HEMC, 60000 viscosity HPMC or the mixture of the two.
9. bicomponent white Polymer cement materials according to claim 1, is characterized in that described water reducer is polycarboxylate water-reducer or naphthalene water reducer.
10. bicomponent white Polymer cement materials according to claim 1, is characterized in that the agent of described mildew-resistant algae is any one or two or more mixture arbitrarily in pyridines, thiazoles, zinc oxide.
CN201510776403.XA 2015-11-13 2015-11-13 Double-component white polymer cement waterproof mortar Pending CN105314947A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106013582A (en) * 2016-07-13 2016-10-12 深圳市奇信建设集团股份有限公司 Construction method for gypsum plaster board ceiling
CN106396572A (en) * 2016-08-30 2017-02-15 福州金博建材有限公司 Coating product for exterior wall decoration
CN106866070A (en) * 2017-02-20 2017-06-20 广州梵竹水性涂料有限公司 A kind of colored polymer cement underwater paint and preparation method thereof
CN107418322A (en) * 2017-06-14 2017-12-01 徐州卧牛山新型防水材料有限公司 A kind of aqueous waterproofing paint of root-resistant puncturing
CN107673687A (en) * 2016-08-02 2018-02-09 北京悦筑新天节能科技有限公司 A kind of flexible water mortar and its preparation method and application
CN109456629A (en) * 2018-11-13 2019-03-12 广东顺德三和化工有限公司 A kind of water-repellent paint and preparation method thereof
CN110386788A (en) * 2019-08-05 2019-10-29 广州丽天防水材料有限公司 A kind of JS cement base anti-counterfeit paint, Preparation method and use
CN110982315A (en) * 2019-12-26 2020-04-10 安徽瑞和新材料有限公司 Hydraulic concrete surface protective agent suitable for alpine regions and preparation method thereof
CN112662243A (en) * 2020-12-29 2021-04-16 山西中涂交通科技股份有限公司 Cement-based water-based marking paint
CN113336500A (en) * 2021-06-25 2021-09-03 亚士漆(上海)有限公司 Adhesive mortar and preparation method and application thereof
CN115448667A (en) * 2022-09-29 2022-12-09 科顺民用建材有限公司 Anti-sagging waterproof mortar composition, anti-sagging waterproof mortar and preparation method and application thereof
CN115785710A (en) * 2022-12-26 2023-03-14 奥泰利新技术集团有限公司 Concrete anti-carbonization coating and preparation method and application thereof

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106013582A (en) * 2016-07-13 2016-10-12 深圳市奇信建设集团股份有限公司 Construction method for gypsum plaster board ceiling
CN107673687A (en) * 2016-08-02 2018-02-09 北京悦筑新天节能科技有限公司 A kind of flexible water mortar and its preparation method and application
CN106396572A (en) * 2016-08-30 2017-02-15 福州金博建材有限公司 Coating product for exterior wall decoration
CN106866070A (en) * 2017-02-20 2017-06-20 广州梵竹水性涂料有限公司 A kind of colored polymer cement underwater paint and preparation method thereof
CN107418322B (en) * 2017-06-14 2019-10-01 徐州卧牛山新型防水材料有限公司 A kind of aqueous waterproofing paint of root-resistant puncturing
CN107418322A (en) * 2017-06-14 2017-12-01 徐州卧牛山新型防水材料有限公司 A kind of aqueous waterproofing paint of root-resistant puncturing
CN109456629A (en) * 2018-11-13 2019-03-12 广东顺德三和化工有限公司 A kind of water-repellent paint and preparation method thereof
CN110386788A (en) * 2019-08-05 2019-10-29 广州丽天防水材料有限公司 A kind of JS cement base anti-counterfeit paint, Preparation method and use
CN110386788B (en) * 2019-08-05 2021-11-09 丽天防水科技有限公司 JS cement-based anti-counterfeiting coating, preparation method and application
CN110982315A (en) * 2019-12-26 2020-04-10 安徽瑞和新材料有限公司 Hydraulic concrete surface protective agent suitable for alpine regions and preparation method thereof
CN112662243A (en) * 2020-12-29 2021-04-16 山西中涂交通科技股份有限公司 Cement-based water-based marking paint
CN113336500A (en) * 2021-06-25 2021-09-03 亚士漆(上海)有限公司 Adhesive mortar and preparation method and application thereof
CN115448667A (en) * 2022-09-29 2022-12-09 科顺民用建材有限公司 Anti-sagging waterproof mortar composition, anti-sagging waterproof mortar and preparation method and application thereof
CN115785710A (en) * 2022-12-26 2023-03-14 奥泰利新技术集团有限公司 Concrete anti-carbonization coating and preparation method and application thereof

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