CN104478611A - Synergisticanti-caking agent for macroelement WSF (water-soluble fertilizer) - Google Patents
Synergisticanti-caking agent for macroelement WSF (water-soluble fertilizer) Download PDFInfo
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- CN104478611A CN104478611A CN201410804169.2A CN201410804169A CN104478611A CN 104478611 A CN104478611 A CN 104478611A CN 201410804169 A CN201410804169 A CN 201410804169A CN 104478611 A CN104478611 A CN 104478611A
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- China
- Prior art keywords
- caking agent
- soluble fertilizer
- water
- hard caking
- silicon
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 59
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 52
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 230000002195 synergetic effect Effects 0.000 claims abstract description 29
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 claims abstract description 18
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229960000304 folic acid Drugs 0.000 claims abstract description 9
- 235000019152 folic acid Nutrition 0.000 claims abstract description 9
- 239000011724 folic acid Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- WXTBYSIPOKXCPM-YFKPBYRVSA-N (4r)-3-acetyl-1,3-thiazolidine-4-carboxylic acid Chemical compound CC(=O)N1CSC[C@H]1C(O)=O WXTBYSIPOKXCPM-YFKPBYRVSA-N 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- ZBJKOZDGZGTMJX-UHFFFAOYSA-N 2,2,4,4-tetramethylpentanedioic acid Chemical compound OC(=O)C(C)(C)CC(C)(C)C(O)=O ZBJKOZDGZGTMJX-UHFFFAOYSA-N 0.000 claims abstract description 4
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims abstract description 4
- 108010020346 Polyglutamic Acid Proteins 0.000 claims abstract description 4
- IXVMHGVQKLDRKH-KNBKMWSGSA-N brassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@@H](O)[C@H](O)[C@@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-KNBKMWSGSA-N 0.000 claims abstract description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 4
- 229920000805 Polyaspartic acid Polymers 0.000 claims abstract description 3
- 108010064470 polyaspartate Proteins 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000013543 active substance Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 6
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- 206010020843 Hyperthermia Diseases 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 230000036031 hyperthermia Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- MSSXOMSJDRHRMC-UHFFFAOYSA-N 9H-purine-2,6-diamine Chemical compound NC1=NC(N)=C2NC=NC2=N1 MSSXOMSJDRHRMC-UHFFFAOYSA-N 0.000 claims description 2
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- -1 sodium alkyl benzene Chemical class 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- CJUUXVFWKYRHAR-UHFFFAOYSA-M 1-Naphthaleneacetic acid sodium salt Chemical compound [Na+].C1=CC=C2C(CC(=O)[O-])=CC=CC2=C1 CJUUXVFWKYRHAR-UHFFFAOYSA-M 0.000 abstract 1
- 229960003237 betaine Drugs 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- 239000013078 crystal Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011573 trace mineral Chemical class 0.000 description 5
- 235000013619 trace mineral Nutrition 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 241000220324 Pyrus Species 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000005543 nano-size silicon particle Substances 0.000 description 4
- 235000021017 pears Nutrition 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- 239000001692 EU approved anti-caking agent Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/20—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a synergisticanti-caking agent for a macroelement WSF (water-soluble fertilizer). Theanti-caking agent is prepared from raw materials in parts by weight as follows: 50-100 parts of a synergistic component and 0.5-2 parts of an anti-caking component, wherein the synergistic component is selected from one or a mixture of some of polyaspartic acid, polyglutamic acid, brassinolide, glycine betaine, N-acetyl-thioproline, folic acid, sodium naphthalene-1-acetate, 6-benzylaminoamidopurine and tetramethylglutaric acid; theanti-caking component consists of a silicon dioxide series product and a surfactant; the silicon dioxide series product is selected from one or a mixture of some of nanoscale silicon dioxide, gas-phase hydrophilicsilicon dioxide and gas-phase hydrophobicsilicon dioxide. The invention further discloses a preparation method of the synergisticanti-caking agent for the macroelement WSF. The anti-caking agent can prevent the macroelement WSF from caking, contains silicon required by promotion of crop growth and plays a role in increasing the fertilizer efficiency.
Description
Technical field
The present invention relates to a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, belong to technical field of fertilizers.
Background technology
Macroelement Water soluble fertilizer (Water Soluble Fertilizer is called for short WSF), be a kind of polyelement composite fertilizer that can be completely water-soluble, it can promptly be dissolved in the water, more easily absorbed by crops, and its absorption rate is relatively high.
The outstanding problem that current solid, water soluble fertilizer exists aborning is that product easily occurs that the moisture absorption is lumpd, and especially in processing, caking, more easily appears in accumulating in transportation.The easy moisture absorption caking of the general product containing urea, potassium primary phosphate, magnesium sulfate (band crystal water), chelated microelement.Fertilizer is in processing, and in storage and transport process, due to the fertilizer crystal grain generation moisture absorption of microcosmic, surface dissolution (deliquescence) evaporates, and recrystallize, forms brilliant bridge in this process, causes small-particle become macrobead and lump.The reason of caking is caused to be many-sided, mainly relevant with moisture absorption, the water content (or crystal water) of raw material, the factors such as ballast amount, the relative humidity of production environment, the water-absorbent of wrapping material of piling, be specially:
First, produce fertilizer material usually used as ammonium salt, phosphoric acid salt, trace element salt, sylvite etc., major part all contains crystal water, and easy moisture absorption caking, as ammonium sulfate easily lumps, phosphoric acid salt meets with trace element and easily lumps and become material not soluble in water, urea runs into microelement kind salt and easily separates out moisture and lump, and mainly urea displaces the crystal water in trace element salt and becomes paste, and then lumps.
The second, fertiliser production is generally non-airtight production, and in process of production, atmospheric moisture is larger, and the easier moisture absorption caking of fertilizer, dry weather or oven dry starting material, fertilizer is with regard to prevented from caking.
3rd, room temperature is higher, is beneficial to dissolving, and general material dissolution causes caking in the crystal water of self.When nitrogen temperature is higher, moisture evaporates, again prevented from caking, and this temperature is general all more than 50 DEG C, and we will heat usually just can reach this temperature.
4th, the pressure additional to fertilizer is larger, is more easy to the contact between crystal and crystal, more easily lumps; Impressed pressure is less, more prevented from caking.
5th, fertilizer more long being more easy to storage period of producing is lumpd, and storage period is shorter, more prevented from caking.
Through years development, preventing blocking technology has multiple, such as improve the packing of product, production unit technique, adjustment fertilizer formulation, change fertilizer composition, improve storage condition and add the methods such as anti-hard caking agent, wherein adding anti-hard caking agent is that comparatively simple and effective method is generally acknowledged in market.But because water-soluble fertilizer is to the requirement of water-insoluble finite quantity, the anti-caking agent be added in conventional compound manure can not be used for water-soluble fertilizer usually.
Summary of the invention
For above-mentioned the deficiencies in the prior art, the object of this invention is to provide a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, this anti-hard caking agent can prevent macroelement water-soluble fertilizer from luming, and again containing the element silicon promoted required for plant growth, plays the effect increasing fertilizer efficiency simultaneously.
Another object of the present invention is to provide the preparation method of this Synergistic type macroelement water-soluble fertilizer anti-hard caking agent.
For achieving the above object, the present invention adopts following technical proposals:
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent is made up of the raw material of following weight part:
Building component 50-100 part, anticaking compound 0.5-2 part;
Described building component is selected from a kind of or several arbitrarily mixture in poly aspartic acid, polyglutamic acid, brassinolide, trimethyl-glycine, N-acetyl thio proline(Pro), folic acid, a-Nafusaku, 6-Bian aminoadenine, tetramethyl-pentanedioic acid;
Described anticaking compound by silicon-dioxide series product and tensio-active agent in mass ratio 1:3-5 form;
Described silicon-dioxide series product is selected from a kind of or several arbitrarily mixture in nanometer grade silica, gas phase hydrophilic silicon dioxide, gas phase water drain silica;
Described tensio-active agent is sodium alkyl benzene sulfonate or the benzene sulfonamide acid potassium salt of C12-C18;
Preferably, described building component is the mixture of N-acetyl thio proline(Pro) and folic acid 49-99:1 composition in mass ratio;
Preferably, described anticaking compound by silicon-dioxide series product and tensio-active agent in mass ratio 1:4 form;
Preferably, described silicon-dioxide series product is nanometer grade silica;
Preferably, described tensio-active agent is pelopon A.
The preparation method of this Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, comprises the following steps:
(1) joined by tensio-active agent in the deionized water of 80-90 DEG C, mass ratio 1:50, stirs, and makes clear colloidal liquid, in this step, the selection of temperature is very crucial, if temperature is lower than 80 DEG C, the solution of preparation is not clarified, and higher than 90 DEG C, solution then becomes pasty state;
(2) add silicon-dioxide series product in the colloidal solution prepared to step (1), 30-40 DEG C stirs, and hyperthermia drying, obtains anticaking compound;
(3) mixed under 20-30 DEG C of condition with building component by anticaking compound prepared by step (2), to obtain final product, in this step, temperature condition is very crucial, and temperature by sex change, loses synergism higher than 30 DEG C of synergistic agent.
Beneficial effect of the present invention:
(1) the Synergistic type macroelement water-soluble fertilizer anti-hard caking agent prepared of the present invention, at reduction macroelement water-soluble fertilizer caking rate simultaneously, add effect of fertilizer, improve the resistance of crop, wherein element silicon contained by anti-hard caking agent is the useful unit of plant growth.
(2) to have addition few, simple to operate for anti-hard caking agent of the present invention, the advantage that preventing blocking effect is outstanding, and product caking rate 0%, water-insoluble meets macroelement product national standard.
(3) the present invention be domestic at present uniquely fertilizer synergist and anti-hard caking agent with the use of combined prod, substantially increase service efficiency.
Embodiment
Below by specific examples, the present invention will be further elaborated, should be noted that following explanation is only to explain the present invention, not limiting its content.
Embodiment 1
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, be made up of following raw material:
1 kilogram, folic acid, N-acetyl thio proline-4 9 kilograms, Sodium dodecylbenzene sulfonate 0.1 kilogram, nano silicon 0.4 kilogram.
Method for making:
(1) fertilizer synergistic component preparation: 1kg folic acid and 49kgN-acetyl thio proline(Pro) are obtained 50kg fertilizer synergistic component at pears formula stirrer for mixing 10min;
(2) anticaking compound preparation: 0.1kg Sodium dodecylbenzene sulfonate is joined in the deionized water of 80 DEG C, 80 DEG C are stirred 60min, make clear colloidal liquid for subsequent use;
In colloidal solution, add 0.4kg particle diameter 15 ± 5nm nano silicon, 30 DEG C are stirred 60min, and namely 100 DEG C of hyperthermia dryings obtain 0.5kg anti-hard caking agent;
(3) import in pears formula stirrer by (1) and (2), temperature controls at 20 DEG C, stirs 30min and namely can be made into Synergistic type fertilizer anti-caking agents of the present invention.
Anti-hard caking agent prepared by the present embodiment is generally used in the high macroelement water-soluble fertilizer of potassium content.
Embodiment 2
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, be made up of following raw material:
1 kilogram, folic acid, N-acetyl thio proline(Pro) 99 kilograms, Sodium dodecylbenzene sulfonate 0.4 kilogram, nano silicon 1.6 kilograms.
Method for making:
(1) fertilizer synergistic component preparation: 1kg folic acid and 99kgN-acetyl thio proline(Pro) are obtained 100kg fertilizer synergistic component at pears formula stirrer for mixing 10min;
(2) anticaking compound preparation: 0.4kg Sodium dodecylbenzene sulfonate is joined in the deionized water of 90 DEG C, 90 DEG C are stirred 60min, make clear colloidal liquid for subsequent use;
In colloidal solution, add 1.6kg particle diameter 15 ± 5nm nano silicon, 30 DEG C are stirred 60min, and namely 90 DEG C of hyperthermia dryings obtain 2.0kg anti-hard caking agent;
(3) import in pears formula stirrer by (1) and (2), temperature controls at 30 DEG C, stirs 30min and namely can be made into Synergistic type fertilizer anti-caking agents of the present invention.
Anti-hard caking agent prepared by the present embodiment is generally used in the high macroelement water-soluble fertilizer of nitrogen content.
Embodiment 3
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, be made up of following raw material:
Brassinolide 1 kilogram, a-Nafusaku 80 kilograms, Sodium dodecylbenzene sulfonate 0.3 kilogram, gas phase hydrophilic silicon dioxide 1.5 kilograms.
Preparation method, with embodiment 1, repeats no more.
Embodiment 4
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, be made up of following raw material:
Trimethyl-glycine 1 kilogram, polyglutamic acid 74 kilograms, Sodium dodecylbenzene sulfonate 0.2 kilogram, gas phase hydrophilic silicon dioxide 1.4 kilograms.
Preparation method, with embodiment 1, repeats no more.
Embodiment 5
A kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, be made up of following raw material:
Tetramethyl-pentanedioic acid 50 kilograms, Sodium dodecylbenzene sulfonate 0.1 kilogram, gas phase hydrophilic silicon dioxide 0.4 kilogram.
Preparation method, with embodiment 1, repeats no more.
Effect test 1:
(1) experiment purpose: investigate the anti-hard caking agent of the embodiment of the present invention 1 preparation to high potassium type macroelement product caking performance impact.
(2) experimental raw: the anti-hard caking agent of urea (powdery, fine granularity), potassium primary phosphate, saltpetre, the embodiment of the present invention 1 preparation, commercially available anti-hard caking agent A (principle anhydrous magnesium sulfate), commercially available anti-hard caking agent B (oily)
Experiment water-soluble fertilizer proportioning: 14-4-30+TE.Wherein N content 14%, P
2o
5content 4%, K
2o content 30%, TE represents trace element, this proportioning medium trace element Zn0.3%, B0.2%.(above-mentioned be mass percentage)
Amount of preparation: 6kg
(3) experimental technique:
Process 1: add Synergistic type anti-hard caking agent 0.6kg of the present invention
Process 2: add 0.6kg anti-hard caking agent A
Process 3: add 0.6kg anti-hard caking agent B
Process 4: do not add anti-hard caking agent product of the present invention
Do pressurized tests under 50kg pressure 30 days, sample is taken out, the sample after pressurized is freely fallen twice (top and bottom respectively once) from 1m eminence.Above-mentioned sample is weighed, is designated as m
0, sieve sample with the sieve of 7mm, sieving time is 3min.Improve quality with electronic balance scale sieve, be designated as m1, caking rate=m
1/ m
0× 100%.
(4) experimental result:
The effect test result of anti-hard caking agent prepared by table 1 embodiment 1
Result shows to add this anti-hard caking agent product caking rate 0%, and preventing blocking effect is obvious.
Effect test 2-5:
Test method is with effect test 1, and test the preventing blocking effect of anti-hard caking agent prepared by embodiment 2-5 respectively, result shows, the caking rate adding anti-hard caking agent product prepared by embodiment 2-5 is 0%, shows anti-hard caking agent Be very effective of the present invention.
Water insoluble substance determination is tested:
To the macroelement water-soluble fertilizer water insoluble substance determination adding anti-hard caking agent of the present invention, water insoluble substance determination method is carried out according to water insoluble substance determination method in NY/T1115 " water-soluble fertilizer water insoluble matter content and pH value bioassay standard ".Measurement result is as following table:
Table 2 adds embodiment 1-5 macroelement fertilizer water insoluble substance determination result
As can be seen from Table 2, be added with the macroelement water-soluble fertilizer of anti-hard caking agent of the present invention, its water insoluble matter content, all below 1%, meets the standard-required of the Ministry of Agriculture, and therefore, anti-hard caking agent prepared by the present invention is applicable to be added in macroelement water-soluble fertilizer.
Claims (8)
1. a Synergistic type macroelement water-soluble fertilizer anti-hard caking agent, is characterized in that, is to be made up of the raw material of following weight part:
Building component 50-100 part, anticaking compound 0.5-2 part;
Described building component is selected from a kind of or several arbitrarily mixture in poly aspartic acid, polyglutamic acid, brassinolide, trimethyl-glycine, N-acetyl thio proline(Pro), folic acid, a-Nafusaku, 6-Bian aminoadenine, tetramethyl-pentanedioic acid;
Described anticaking compound by silicon-dioxide series product and tensio-active agent in mass ratio 1:3-5 form;
Described silicon-dioxide series product is selected from a kind of or several arbitrarily mixture in nanometer grade silica, gas phase hydrophilic silicon dioxide, gas phase water drain silica.
2. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 1, it is characterized in that, described tensio-active agent is C
12-C
18sodium alkyl benzene sulfonate or benzene sulfonamide acid potassium salt.
3. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 1, is characterized in that, described building component is the mixture of N-acetyl thio proline(Pro) and folic acid 49-99:1 composition in mass ratio.
4. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 1, is characterized in that, described anticaking compound by silicon-dioxide series product and tensio-active agent in mass ratio 1:4 form.
5. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 1, is characterized in that, described silicon-dioxide series product is nanometer grade silica.
6. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 2, it is characterized in that, described tensio-active agent is pelopon A.
7. a kind of Synergistic type macroelement water-soluble fertilizer anti-hard caking agent as claimed in claim 5, it is characterized in that, the particle diameter of described nanometer grade silica is 15 ± 5nm.
8. the preparation method of the Synergistic type macroelement water-soluble fertilizer anti-hard caking agent described in any one of claim 1-7, is characterized in that, comprise the following steps:
(1) tensio-active agent is joined in the deionized water of 80-90 DEG C, stir, make clear colloidal liquid;
(2) add silicon-dioxide series product in the colloidal solution prepared to step (1), 30-40 DEG C stirs, and hyperthermia drying, obtains anticaking compound;
(3) anticaking compound prepared by step (2) is mixed with building component under 20-30 DEG C of condition, to obtain final product.
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| CN106747857A (en) * | 2015-11-19 | 2017-05-31 | 金正大诺泰尔化学有限公司 | It is a kind of to prevent and treat water-soluble pesticide-fertilizer of black scurf of potato and preparation method and application |
| CN107056484A (en) * | 2017-05-22 | 2017-08-18 | 金正大生态工程集团股份有限公司 | A kind of fertilizer synergist containing DCPTA and preparation method and application |
| CN107344887A (en) * | 2016-05-06 | 2017-11-14 | 河北绿色农华科技有限公司 | A kind of solid a great number of elements Water soluble fertilizer of siliceous agglomeration resistance and preparation method thereof |
| CN107793216A (en) * | 2017-10-17 | 2018-03-13 | 湖北富邦科技股份有限公司 | A kind of fertilizer anti-caking agents and its preparation method and application |
| CN109400394A (en) * | 2018-12-29 | 2019-03-01 | 成都云图控股股份有限公司 | A kind of compound fertilizer anticaking agent and preparation method thereof and compound fertilizer as made from it |
| CN109694283A (en) * | 2019-03-12 | 2019-04-30 | 东莞德盛肥料科技有限公司 | A kind of solid water-soluble fertilizer anti-caking block method and anti-caking solid water-soluble fertilizer |
| CN111763115A (en) * | 2020-07-08 | 2020-10-13 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
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| CN106747857A (en) * | 2015-11-19 | 2017-05-31 | 金正大诺泰尔化学有限公司 | It is a kind of to prevent and treat water-soluble pesticide-fertilizer of black scurf of potato and preparation method and application |
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| CN107793216A (en) * | 2017-10-17 | 2018-03-13 | 湖北富邦科技股份有限公司 | A kind of fertilizer anti-caking agents and its preparation method and application |
| CN109400394A (en) * | 2018-12-29 | 2019-03-01 | 成都云图控股股份有限公司 | A kind of compound fertilizer anticaking agent and preparation method thereof and compound fertilizer as made from it |
| CN109694283A (en) * | 2019-03-12 | 2019-04-30 | 东莞德盛肥料科技有限公司 | A kind of solid water-soluble fertilizer anti-caking block method and anti-caking solid water-soluble fertilizer |
| CN111763115A (en) * | 2020-07-08 | 2020-10-13 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
| CN111763115B (en) * | 2020-07-08 | 2022-06-10 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
| CN113929535A (en) * | 2021-12-02 | 2022-01-14 | 安徽富瑞雪化工科技股份有限公司 | Environment-friendly anti-blocking agent for compound fertilizer and preparation method thereof |
| CN114097790A (en) * | 2021-12-14 | 2022-03-01 | 中国热带农业科学院南亚热带作物研究所 | Litchi cold-resistant regulator and application thereof |
| CN114097790B (en) * | 2021-12-14 | 2023-10-03 | 中国热带农业科学院南亚热带作物研究所 | Litchi cold-resistant regulator and application thereof |
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| CN116063127A (en) * | 2023-02-10 | 2023-05-05 | 河北冀森生物科技有限公司 | Efficient anti-caking agent for water-soluble fertilizer and preparation method and application thereof |
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Application publication date: 20150401 Assignee: SINOCHEM YANTAI CROP NUTRITION Co.,Ltd. Assignor: Sinochem agriculture (Xinjiang) Biotechnology Co.,Ltd. Contract record no.: X2020980008889 Denomination of invention: A synergistic anti caking agent for water soluble fertilizer with large amount of elements Granted publication date: 20171027 License type: Common License Record date: 20201207 |