CN103804834B - 一种有机硅组合物及其制备方法 - Google Patents
一种有机硅组合物及其制备方法 Download PDFInfo
- Publication number
- CN103804834B CN103804834B CN201210453468.7A CN201210453468A CN103804834B CN 103804834 B CN103804834 B CN 103804834B CN 201210453468 A CN201210453468 A CN 201210453468A CN 103804834 B CN103804834 B CN 103804834B
- Authority
- CN
- China
- Prior art keywords
- silicon composition
- silicon
- alpha
- silicone resin
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 64
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 47
- 239000010703 silicon Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 49
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- 229920002050 silicone resin Polymers 0.000 claims abstract description 25
- 239000004711 α-olefin Substances 0.000 claims abstract description 18
- 229960001866 silicon dioxide Drugs 0.000 claims abstract description 15
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 15
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000010792 warming Methods 0.000 claims description 14
- -1 α-laurylene Chemical compound 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 9
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical group CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 claims description 5
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 claims description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical group CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 2
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 15
- 239000006260 foam Substances 0.000 abstract description 14
- 238000011284 combination treatment Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 239000013530 defoamer Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 239000007787 solid Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 7
- 230000003254 anti-foaming effect Effects 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000012808 vapor phase Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000012716 precipitator Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940056729 sodium sulfate anhydrous Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Silicon Polymers (AREA)
- Detergent Compositions (AREA)
- Degasification And Air Bubble Elimination (AREA)
Abstract
Description
Claims (4)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210453468.7A CN103804834B (zh) | 2012-11-13 | 2012-11-13 | 一种有机硅组合物及其制备方法 |
PCT/CN2013/074012 WO2014075422A1 (zh) | 2012-11-13 | 2013-04-10 | 一种有机硅组合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210453468.7A CN103804834B (zh) | 2012-11-13 | 2012-11-13 | 一种有机硅组合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103804834A CN103804834A (zh) | 2014-05-21 |
CN103804834B true CN103804834B (zh) | 2015-10-28 |
Family
ID=50702251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210453468.7A Active CN103804834B (zh) | 2012-11-13 | 2012-11-13 | 一种有机硅组合物及其制备方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN103804834B (zh) |
WO (1) | WO2014075422A1 (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104069656B (zh) * | 2014-07-09 | 2016-01-20 | 江苏四新科技应用研究所股份有限公司 | 一种消泡组合物 |
CN106890485A (zh) * | 2015-12-18 | 2017-06-27 | 滁州四新科技有限责任公司 | 一种用于漂洗的消泡组合物的制备方法 |
CN106799069A (zh) * | 2016-12-28 | 2017-06-06 | 广东中联邦精细化工有限公司 | 一种洗涤用品生产专用消泡剂及其制备方法 |
CN109824838B (zh) * | 2018-12-29 | 2021-08-06 | 宁波特粒科技有限公司 | 一种基于mq树脂的有机硅表面活性剂及其制备方法 |
CN115521830B (zh) * | 2022-10-26 | 2023-04-07 | 南京瑞思化学技术有限公司 | 一种有机硅组合物的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1724106A (zh) * | 2004-07-23 | 2006-01-25 | 瓦克化学有限公司 | 消泡剂组合物 |
CN101048212A (zh) * | 2004-10-26 | 2007-10-03 | 瓦克化学股份公司 | 消泡剂组合物 |
CN102698475A (zh) * | 2012-06-29 | 2012-10-03 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
-
2012
- 2012-11-13 CN CN201210453468.7A patent/CN103804834B/zh active Active
-
2013
- 2013-04-10 WO PCT/CN2013/074012 patent/WO2014075422A1/zh active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1724106A (zh) * | 2004-07-23 | 2006-01-25 | 瓦克化学有限公司 | 消泡剂组合物 |
CN101048212A (zh) * | 2004-10-26 | 2007-10-03 | 瓦克化学股份公司 | 消泡剂组合物 |
CN102698475A (zh) * | 2012-06-29 | 2012-10-03 | 南京四新科技应用研究所有限公司 | 一种消泡组合物 |
Also Published As
Publication number | Publication date |
---|---|
CN103804834A (zh) | 2014-05-21 |
WO2014075422A1 (zh) | 2014-05-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102698475B (zh) | 一种消泡组合物 | |
CN103804834B (zh) | 一种有机硅组合物及其制备方法 | |
CN104069656B (zh) | 一种消泡组合物 | |
CN103037949B (zh) | 基于氨基聚硅氧烷的消泡剂及其制备方法 | |
US5668101A (en) | Particulate foam control agents and their use | |
JP4612162B2 (ja) | シリコーン系消泡剤 | |
CN104130879A (zh) | 一种用于液体洗涤剂的消泡剂 | |
CN104274998B (zh) | 一种有机硅组合物、制备方法及应用 | |
CN105498305B (zh) | 一种有机硅消泡组合物 | |
CN104784980B (zh) | 一种消泡组合物 | |
CN102250358B (zh) | 一种嵌段型氨基聚醚改性硅油及制备方法 | |
CN105107237B (zh) | 一种有机硅消泡组合物及其制备方法 | |
CN111151033A (zh) | 一种新型聚醚改性有机硅消泡剂制备方法 | |
JPH0356082B2 (zh) | ||
CN101798781A (zh) | 一种造纸制浆用的有机硅消泡剂及其制备方法 | |
CN110898467B (zh) | 消泡活性物、其制备方法及消泡剂 | |
CN110283322A (zh) | 一种有机硅组合物 | |
CN103275493B (zh) | 一种有机硅组合物 | |
EP2432822A1 (en) | Modified silicone polymer as anti foam agent and detergent composition having the same | |
KR101711461B1 (ko) | 소포제 및 세제 내 그의 용도 | |
CN103669108A (zh) | 一种造纸工业用有机硅消泡剂及其制备方法 | |
US6369022B2 (en) | Foam control agents | |
CN106890485A (zh) | 一种用于漂洗的消泡组合物的制备方法 | |
CN105525509B (zh) | 一种用于棉织物绳状连续煮练的低碱精练剂 | |
CN102302869A (zh) | 一种固体颗粒抑泡剂及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent for invention or patent application | ||
CB02 | Change of applicant information |
Address after: 210027 Gulou District, Nanjing Province, east of the East Wing Road, No. 199 Zijin (Shimonoseki) science and technology venture special community D11 block Applicant after: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Address before: 210027, Nanjing, Jiangsu Province, Xiaguan Road, Shimonoseki District No. 199 Zijin venture special community building D11 Applicant before: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City |
|
COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: SIXIN SCIENCE + TECHNOLOGY APPLIED INST. CO., LTD., NANJING CITY TO: JIANGSU INSTITUTE OF FOUR NEW TECHNOLOGYAPPLICATIONS |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP02 | Change in the address of a patent holder | ||
CP02 | Change in the address of a patent holder |
Address after: 210027 A22, 199 shogundong Road, Gulou District, Nanjing, Jiangsu. Patentee after: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Address before: 210027 Nanjing, Jiangsu, Gulou District, No. 199 shogundong Road, purple gold (Xiaguan) technology entrepreneurship special community D11 Patentee before: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Organosilicon composition and preparation method thereof Effective date of registration: 20190312 Granted publication date: 20151028 Pledgee: Bank of China Limited by Share Ltd Nanjing City South Branch Pledgor: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Registration number: 2019320000127 |