CN103589006A - 一种高弹耐寒改性顺丁橡胶电缆料 - Google Patents
一种高弹耐寒改性顺丁橡胶电缆料 Download PDFInfo
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- CN103589006A CN103589006A CN201310517580.7A CN201310517580A CN103589006A CN 103589006 A CN103589006 A CN 103589006A CN 201310517580 A CN201310517580 A CN 201310517580A CN 103589006 A CN103589006 A CN 103589006A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 39
- 239000005060 rubber Substances 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 title claims abstract description 34
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 title claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004793 Polystyrene Substances 0.000 claims abstract description 9
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 9
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 9
- 229920002223 polystyrene Polymers 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005864 Sulphur Substances 0.000 claims abstract description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 4
- 239000006229 carbon black Substances 0.000 claims abstract description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000008117 stearic acid Substances 0.000 claims abstract description 4
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims abstract description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 9
- 229910052667 lazurite Inorganic materials 0.000 claims description 9
- 239000010455 vermiculite Substances 0.000 claims description 9
- 229910052902 vermiculite Inorganic materials 0.000 claims description 9
- 235000019354 vermiculite Nutrition 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 7
- 229920001897 terpolymer Polymers 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- APZPSKFMSWZPKL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)CO APZPSKFMSWZPKL-UHFFFAOYSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- -1 carbon alcohols ester Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000006735 epoxidation reaction Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229920002943 EPDM rubber Polymers 0.000 abstract 2
- 229920005549 butyl rubber Polymers 0.000 abstract 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 230000003044 adaptive effect Effects 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- RLRMXWDXPLINPJ-UHFFFAOYSA-N dioctan-2-yl benzene-1,2-dicarboxylate Chemical compound CCCCCCC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)CCCCCC RLRMXWDXPLINPJ-UHFFFAOYSA-N 0.000 abstract 1
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104109395A (zh) * | 2014-06-27 | 2014-10-22 | 安徽宁国尚鼎橡塑制品有限公司 | 一种耐寒耐水橡胶材料 |
CN104277338A (zh) * | 2014-10-27 | 2015-01-14 | 安徽锐视光电技术有限公司 | 一种色选机用防老化合成橡胶及其制备方法 |
CN105367916A (zh) * | 2015-11-24 | 2016-03-02 | 安徽南洋新材料科技股份有限公司 | 一种高强度高耐候阻燃电缆 |
CN105542250A (zh) * | 2015-12-16 | 2016-05-04 | 合肥杰明新材料科技有限公司 | 一种柔韧松香顺丁橡胶材料及其制备方法 |
CN105670151A (zh) * | 2016-03-08 | 2016-06-15 | 苏州科茂电子材料科技有限公司 | 一种纤维增强复合同轴电缆材料及其制备方法 |
CN110437513A (zh) * | 2019-09-06 | 2019-11-12 | 安徽长远机电股份有限公司 | 一种强效耐老化电缆料及其制备方法 |
WO2021232711A1 (zh) * | 2020-05-18 | 2021-11-25 | 江苏亨通线缆科技有限公司 | 一种耐寒型数据传输电缆 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005036563A2 (en) * | 2003-08-21 | 2005-04-21 | Rensselaer Polytechnic Institute | Nanocomposites with controlled electrical properties |
CN101560314A (zh) * | 2009-06-09 | 2009-10-21 | 中科英华湖州工程技术研究中心有限公司 | 一种采用辐射接枝技术制备的无卤无磷阻燃聚烯烃材料及其制备方法与应用 |
CN102820078A (zh) * | 2011-06-08 | 2012-12-12 | 戴永国 | 橡、塑绝缘陶瓷化耐火电缆 |
-
2013
- 2013-10-29 CN CN201310517580.7A patent/CN103589006B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005036563A2 (en) * | 2003-08-21 | 2005-04-21 | Rensselaer Polytechnic Institute | Nanocomposites with controlled electrical properties |
CN101560314A (zh) * | 2009-06-09 | 2009-10-21 | 中科英华湖州工程技术研究中心有限公司 | 一种采用辐射接枝技术制备的无卤无磷阻燃聚烯烃材料及其制备方法与应用 |
CN102820078A (zh) * | 2011-06-08 | 2012-12-12 | 戴永国 | 橡、塑绝缘陶瓷化耐火电缆 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104109395A (zh) * | 2014-06-27 | 2014-10-22 | 安徽宁国尚鼎橡塑制品有限公司 | 一种耐寒耐水橡胶材料 |
CN104277338A (zh) * | 2014-10-27 | 2015-01-14 | 安徽锐视光电技术有限公司 | 一种色选机用防老化合成橡胶及其制备方法 |
CN105367916A (zh) * | 2015-11-24 | 2016-03-02 | 安徽南洋新材料科技股份有限公司 | 一种高强度高耐候阻燃电缆 |
CN105542250A (zh) * | 2015-12-16 | 2016-05-04 | 合肥杰明新材料科技有限公司 | 一种柔韧松香顺丁橡胶材料及其制备方法 |
CN105670151A (zh) * | 2016-03-08 | 2016-06-15 | 苏州科茂电子材料科技有限公司 | 一种纤维增强复合同轴电缆材料及其制备方法 |
CN110437513A (zh) * | 2019-09-06 | 2019-11-12 | 安徽长远机电股份有限公司 | 一种强效耐老化电缆料及其制备方法 |
WO2021232711A1 (zh) * | 2020-05-18 | 2021-11-25 | 江苏亨通线缆科技有限公司 | 一种耐寒型数据传输电缆 |
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Effective date of registration: 20170927 Address after: Xiao Shi Zhuang Cun Dong Jing Ji Zhen 075816 Zhangjiakou City Yangyuan County of Hebei province No. 30 Patentee after: Zhang Ping Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: Lvbao Cable (Group) Co., Ltd. |
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Effective date of registration: 20181226 Address after: 210000 No. 20 Beijing West Road, Gulou District, Nanjing City, Jiangsu Province Patentee after: Xie Guangcheng Address before: 075816 Xiaoshizhuang Village, Dongjing Market Town, Yangyuan County, Zhangjiakou City, Hebei Province Patentee before: Zhang Ping |
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Effective date of registration: 20191023 Address after: 314500 Tongxiang, Zhejiang City Industrial Park, the town of Stephen Patentee after: Tongxiang Guangsheng Plastic Industry Co., Ltd. Address before: 210000 No. 20 Beijing West Road, Gulou District, Nanjing City, Jiangsu Province Patentee before: Xie Guangcheng |
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