CN103570178A - Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater - Google Patents

Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater Download PDF

Info

Publication number
CN103570178A
CN103570178A CN201310509860.3A CN201310509860A CN103570178A CN 103570178 A CN103570178 A CN 103570178A CN 201310509860 A CN201310509860 A CN 201310509860A CN 103570178 A CN103570178 A CN 103570178A
Authority
CN
China
Prior art keywords
water
housing
shell
water outlet
ammonia nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310509860.3A
Other languages
Chinese (zh)
Inventor
雷春生
王清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou University
Original Assignee
Changzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou University filed Critical Changzhou University
Priority to CN201310509860.3A priority Critical patent/CN103570178A/en
Publication of CN103570178A publication Critical patent/CN103570178A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Removal Of Specific Substances (AREA)

Abstract

The invention discloses a device for treating high-concentration ammonia-nitrogen in metallurgical wastewater. The device comprises a shell (1), a water inlet (2) and a water outlet (3), wherein the water inlet (2) and the water outlet (3) are formed in the two sides of the shell (1); aerators (4) are arranged inside the shell (1); deflection baffles (5) placed in a staggered manner are installed above the aerators (4); stainless steel screen fillers (6) are arranged between the deflection baffles (5) and the water outlet (3); an electromagnetic exciter (7) is arranged below the stainless steel screen fillers (6); sprayers (9) connected with a dosing tank (8) outside the shell (1) are installed on one side of the electromagnetic exciter (7); a metering pump (10) is arranged between the dosing tank (8) and the shell (1); a pH meter (11) connected with the interior of the shell (1) is also installed on one side of the metering pump (10). The device has a simple structure and good treatment effects, is low in cost, avoids secondary pollution, has an ammonia-nitrogen removal rate of above 99.99% and is worth wide popularization.

Description

Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement
Technical field
The present invention relates to Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement, belong to sewage treatment area.
Background technology
Metallurgical industry is one of industry the most ancient in human history, after the Industrial Revolution of 18th century, Iron And Steel Industry develops rapidly, cause serious pollution, since entering for 20th century, global economy and industrial expansion are that metallurgical production scale increases rapidly, and the ammonia-nitrogen content of Coal Gas Washing Cycling Water is also on the increase, the waste water NH that ,Mou Metallurgical Factory washing and filtering technique is discharged according to investigations 4 +content surpasses 10000mg/L, and the ammonia nitrogen in water body can cause the eutrophication in lake and river, reduces the concentration of dissolved oxygen, and the aquatic organism in water body is produced to toxicity, and ammonia nitrogen also can burn into blocking pipe and watering equipment simultaneously.
Existing ammonia nitrogen water technology is nearly: physico-chemical process, biochemical integrated process, new bio denitrogenation, membrane processing method etc.Although process the treatment process of ammonia nitrogen in high density, have multiplely, also there is no a kind ofly can to take into account that flow process is simple at present, less investment, technology maturation, control is convenient and non-secondary pollution, practical application methods that working cost is low.
Summary of the invention
In order to solve, the removal efficiency existing in prior art is low, cost is high, easily produce the problem of environmental pollution, the Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement providing is provided, have simple in structure, treatment effect good, the low level of automation advantages of higher of working cost, ammonia nitrogen removal frank reaches more than 99.99%.
To achieve these goals, the concrete technical scheme that the present invention takes is: Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement, comprise housing (1), water-in (2), water outlet (3), water-in (2) and water outlet (3) are arranged on housing (1) both sides, housing (1) inside is provided with aerator (4), the baffle (5) being staggeredly placed is equipped with in the top of aerator (4), between baffle (5) and water outlet (3), be provided with Stainless Steel Cloth filler (6), Stainless Steel Cloth filler (6) bottom is provided with electromagnetism excitation device (7), electromagnetism excitation device (7) one sides are equipped with the spray thrower (9) being connected with housing (1) outside dosing tank (8), between dosing tank (8) and housing (1), be provided with volume pump (10), volume pump (10) one sides are also equipped with and the inner pH meter (11) being connected of housing (1).
Water distributor (12) and circulating sprayer (13) are also housed between described water-in (2) and spray thrower (9).
Described electromagnetism excitation device (7) comprises electromagnetic launcher (14) and electromagnetic receiver (15), and both are at a distance of 3-6cm, between by wire (16), be connected with power supply (17).
The application method of Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement of the present invention is: waste water enters into housing (1) inside by water-in (2), in the time of aerator (4) aeration, waste water is delivered to spray thrower (9) through circulating sprayer (13) and is sprayed, recycling water distributor (12) water distribution uniformity, throw out is tackled by baffle (5), electromagnetism excitation device (7) is by exciting electromagnetism to produce electric field, thereby generation strong oxidizer, further decontaminating liquid, pH meter (11) is monitored the potential of hydrogen of the interior waste water of housing (1) at any time, controlling dosing tank (8) soaks to inner the interpolation through alkali of housing (1) by volume pump (10), Actidose after pickling and metal catalytic, the ionization vaporization under the effect of electric field again of this solution, ammonia nitrogen can be reduced to nitrogen, finally, liquid is discharged from water outlet (3) after Stainless Steel Cloth filler (6) filters.
The invention has the beneficial effects as follows: this apparatus structure is simple, treatment effect is good, and cost is low, there is no secondary pollution, and ammonia nitrogen removal frank reaches more than 99.99%, should be widely promoted.
Accompanying drawing explanation
Fig. 1 is the structural representation of apparatus of the present invention;
1, housing, 2, water-in, 3, water outlet, 4, aerator, 5, baffle, 6, Stainless Steel Cloth filler, 7, electromagnetism excitation device, 8, dosing tank, 9, spray thrower, 10, volume pump, 11, pH meter, 12, water distributor, 13, circulating sprayer, 14, electromagnetic launcher, 15, electromagnetic receiver, 16, wire, 17, power supply.
Specific embodiments
Below in conjunction with accompanying drawing, technical solution of the present invention is further illustrated.
As shown in Figure 1, Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement provided by the present invention, comprise housing (1), water-in (2), water outlet (3), water-in (2) and water outlet (3) are arranged on housing (1) both sides, housing (1) inside is provided with aerator (4), the baffle (5) being staggeredly placed is equipped with in the top of aerator (4), between baffle (5) and water outlet (3), be provided with Stainless Steel Cloth filler (6), Stainless Steel Cloth filler (6) bottom is provided with electromagnetism excitation device (7), electromagnetism excitation device (7) one sides are equipped with the spray thrower (9) being connected with housing (1) outside dosing tank (8), between dosing tank (8) and housing (1), be provided with volume pump (10), volume pump (10) one sides are also equipped with and the inner pH meter (11) being connected of housing (1), water distributor (12) and circulating sprayer (13) are also housed between water-in (2) and spray thrower (9), electromagnetism excitation device (7) comprises electromagnetic launcher (14) and electromagnetic receiver (15), and both are at a distance of 3-6cm, between by wire (16), be connected with power supply (17).
When Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement provided by the invention is used, waste water enters into housing (1) inside by water-in (2), in the time of aerator (4) aeration, waste water is delivered to spray thrower (9) through circulating sprayer (13) and is sprayed, recycling water distributor (12) water distribution uniformity, throw out is tackled by baffle (5), electromagnetism excitation device (7) is by exciting electromagnetism to produce electric field, thereby generation strong oxidizer, further decontaminating liquid, pH meter (11) is monitored the potential of hydrogen of the interior waste water of housing (1) at any time, controlling dosing tank (8) soaks to inner the interpolation through alkali of housing (1) by volume pump (10), Actidose after pickling and metal catalytic, the ionization vaporization under the effect of electric field again of this solution, ammonia nitrogen can be reduced to nitrogen, finally, liquid is discharged from water outlet (3) after Stainless Steel Cloth filler (6) filters, after testing, ammonia nitrogen concentration drops to 0.038mg/L by 378mg/L, clearance reaches more than 99.99%.

Claims (3)

1. Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement, it is characterized in that: comprise housing (1), water-in (2), water outlet (3), water-in (2) and water outlet (3) are arranged on housing (1) both sides, housing (1) inside is provided with aerator (4), the baffle (5) being staggeredly placed is equipped with in the top of aerator (4), between baffle (5) and water outlet (3), be provided with Stainless Steel Cloth filler (6), Stainless Steel Cloth filler (6) bottom is provided with electromagnetism excitation device (7), electromagnetism excitation device (7) one sides are equipped with the spray thrower (9) being connected with housing (1) outside dosing tank (8), between dosing tank (8) and housing (1), be provided with volume pump (10), volume pump (10) one sides are also equipped with and the inner pH meter (11) being connected of housing (1).
2. Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement according to claim 1, is characterized in that: water distributor (12) and circulating sprayer (13) are also housed between described water-in (2) and spray thrower (9).
3. Metallurgical Waste Water middle and high concentration ammonia nitrogen handling arrangement according to claim 1, it is characterized in that: described electromagnetism excitation device (7) comprises electromagnetic launcher (14) and electromagnetic receiver (15), both are at a distance of 3-6cm, between by wire (16), be connected with power supply (17).
CN201310509860.3A 2013-10-25 2013-10-25 Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater Pending CN103570178A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310509860.3A CN103570178A (en) 2013-10-25 2013-10-25 Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310509860.3A CN103570178A (en) 2013-10-25 2013-10-25 Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater

Publications (1)

Publication Number Publication Date
CN103570178A true CN103570178A (en) 2014-02-12

Family

ID=50042987

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310509860.3A Pending CN103570178A (en) 2013-10-25 2013-10-25 Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater

Country Status (1)

Country Link
CN (1) CN103570178A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104229970A (en) * 2014-08-26 2014-12-24 常州大学 Device for treating high-concentration ammonia nitrogen in refinery wastewater by using surface activity catalyst
CN106966489A (en) * 2017-05-15 2017-07-21 王佳姝钰 A kind of denitrogenation dephosphorizing sewage-treatment plant

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11319804A (en) * 1998-05-11 1999-11-24 Kurita Engineering Co Ltd Treatment of waste water containing ammonia
GB2383034A (en) * 2001-11-03 2003-06-18 Accentus Plc Removal of ammonia from liquids
CN101234803A (en) * 2008-03-07 2008-08-06 北京蓝景创新科技有限公司 Device for degrading high concentration ammonia nitrogen waste water by electronic excitation
CN101244850A (en) * 2008-01-31 2008-08-20 黄立维 Method and device for removing volatility injurant from wastewater
CN101318752A (en) * 2008-07-10 2008-12-10 浙江大学 Treatment method and apparatus for recycling ammonia nitrogen wastewater
CN101857309A (en) * 2010-06-12 2010-10-13 浙江工商大学 Electrochemical biological combined denitrification reactor
CN201857289U (en) * 2010-10-22 2011-06-08 殷衡 Stripping tower capable of ionizing ammonia-nitrogen at high frequency
CN202164164U (en) * 2011-05-13 2012-03-14 安徽省阜南县新天化工有限公司 Sewage treatment device for removing high-concentration ammonia nitrogen
CN102774934A (en) * 2012-07-18 2012-11-14 常州大学 Method for treating high-concentration ammonia nitrogen in metallurgical wastewater

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11319804A (en) * 1998-05-11 1999-11-24 Kurita Engineering Co Ltd Treatment of waste water containing ammonia
GB2383034A (en) * 2001-11-03 2003-06-18 Accentus Plc Removal of ammonia from liquids
CN101244850A (en) * 2008-01-31 2008-08-20 黄立维 Method and device for removing volatility injurant from wastewater
CN101234803A (en) * 2008-03-07 2008-08-06 北京蓝景创新科技有限公司 Device for degrading high concentration ammonia nitrogen waste water by electronic excitation
CN101318752A (en) * 2008-07-10 2008-12-10 浙江大学 Treatment method and apparatus for recycling ammonia nitrogen wastewater
CN101857309A (en) * 2010-06-12 2010-10-13 浙江工商大学 Electrochemical biological combined denitrification reactor
CN201857289U (en) * 2010-10-22 2011-06-08 殷衡 Stripping tower capable of ionizing ammonia-nitrogen at high frequency
CN202164164U (en) * 2011-05-13 2012-03-14 安徽省阜南县新天化工有限公司 Sewage treatment device for removing high-concentration ammonia nitrogen
CN102774934A (en) * 2012-07-18 2012-11-14 常州大学 Method for treating high-concentration ammonia nitrogen in metallurgical wastewater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104229970A (en) * 2014-08-26 2014-12-24 常州大学 Device for treating high-concentration ammonia nitrogen in refinery wastewater by using surface activity catalyst
CN106966489A (en) * 2017-05-15 2017-07-21 王佳姝钰 A kind of denitrogenation dephosphorizing sewage-treatment plant

Similar Documents

Publication Publication Date Title
Ilhan et al. Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy consumption
CN108383211A (en) A kind of waste water dephosphorization apparatus and method for based on iron-carbon micro-electrolysis
CN101144143A (en) Processing technique of plating auxiliary agent for hot galvanizing
CN103951107A (en) Device and method for treating coking wastewater
CN103979627A (en) Multistage efficient gas stripping system of ammonia nitrogen wastewater
CN103570178A (en) Device for treating high-concentration ammonia-nitrogen in metallurgical wastewater
CN202671286U (en) Sewage pH value adjusting system
CN102795690B (en) Wastewater treatment method by ultrasonic reinforcement micron-scale iron-copper bimetallic particle
CN203461870U (en) Ozone oxidation device for processing secondary biological treatment effluent of urban sewage plant
CN204022601U (en) The micro-electrolysis advanced oxidation of MEO reactor
CN103570159A (en) Device for treating high-concentration ammonia nitrogen in coal chemical wastewater in vortex mixing dispersion way by using surfactant
CN112358095A (en) Treatment method of EDTA complex nickel wastewater
CN210012683U (en) Electroplating wastewater treatment device
KR101951691B1 (en) A wastewater treatment apparatus
CN201495145U (en) Reaction device for high-concentration ammonia nitrogen wastewater treatment
CN105366796A (en) Ozone catalytic device
CN203513336U (en) Pharmaceutical wastewater treatment equipment
CN103570085A (en) Device for treating high-concentration ammonia nitrogen in coking wastewater by using surfactant
CN214327460U (en) Reinforced Fenton oxidation method wastewater treatment device
CN210287019U (en) Device for treating organic pollutants in landfill leachate by utilizing electrostatic spraying
CN208561793U (en) A kind of waste water dephosphorization equipment based on iron-carbon micro-electrolysis
CN203904041U (en) Micro-electrolysis reaction tank
CN209128251U (en) The processing unit of coal chemical industry gasification burner waste water
CN207451702U (en) A kind of micro-nano aeration device
CN111498951A (en) Electrochemical MAP precipitation device and process method for treating ammonia nitrogen sewage

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140212