CN103111101A - 一种双封端基聚醚改性硅油型消泡剂及其制备方法 - Google Patents
一种双封端基聚醚改性硅油型消泡剂及其制备方法 Download PDFInfo
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- CN103111101A CN103111101A CN2013100545992A CN201310054599A CN103111101A CN 103111101 A CN103111101 A CN 103111101A CN 2013100545992 A CN2013100545992 A CN 2013100545992A CN 201310054599 A CN201310054599 A CN 201310054599A CN 103111101 A CN103111101 A CN 103111101A
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- polyether modified
- end capped
- modified silicon
- silicon oil
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- 229920000570 polyether Polymers 0.000 title claims abstract description 110
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 102
- 239000002518 antifoaming agent Substances 0.000 title claims abstract description 17
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 63
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 46
- 150000001875 compounds Chemical class 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 30
- 239000003054 catalyst Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000003381 stabilizer Substances 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000003999 initiator Substances 0.000 claims abstract description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 10
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 9
- 238000009835 boiling Methods 0.000 claims abstract description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003921 oil Substances 0.000 claims description 87
- 239000013530 defoamer Substances 0.000 claims description 33
- 238000002360 preparation method Methods 0.000 claims description 23
- 230000008676 import Effects 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 14
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 10
- -1 polysiloxan Polymers 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 238000006073 displacement reaction Methods 0.000 claims description 7
- 125000004185 ester group Chemical group 0.000 claims description 7
- 238000007046 ethoxylation reaction Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000003828 vacuum filtration Methods 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
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- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 6
- 238000001914 filtration Methods 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000000178 monomer Substances 0.000 description 8
- 239000001294 propane Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000007373 indentation Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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- Silicon Polymers (AREA)
- Polyethers (AREA)
- Degasification And Air Bubble Elimination (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
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CN201310054599.2A CN103111101B (zh) | 2013-02-20 | 2013-02-20 | 一种双封端基聚醚改性硅油型消泡剂及其制备方法 |
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CN201310054599.2A CN103111101B (zh) | 2013-02-20 | 2013-02-20 | 一种双封端基聚醚改性硅油型消泡剂及其制备方法 |
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CN103111101A true CN103111101A (zh) | 2013-05-22 |
CN103111101B CN103111101B (zh) | 2015-01-07 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104906832A (zh) * | 2015-05-22 | 2015-09-16 | 陕西省石油化工研究设计院 | 一种聚醚酯/矿物油复合型消泡剂及其制备方法 |
CN106943773A (zh) * | 2017-04-20 | 2017-07-14 | 天津亿利科能源科技发展股份有限公司 | 一种海上平台中质原油消泡剂的制备方法 |
CN110465119A (zh) * | 2019-08-28 | 2019-11-19 | 启东曦瑞新材料科技有限公司 | 一种矿物油消泡剂的制备方法 |
WO2020033340A1 (en) * | 2018-08-08 | 2020-02-13 | Kop-Coat, Inc. | Granulated agricultural adjuvant and method of making and using same |
CN113069796A (zh) * | 2020-01-03 | 2021-07-06 | 万华化学集团股份有限公司 | 一种可用于水性涂料的有机硅消泡剂及其制备方法 |
CN115400464A (zh) * | 2022-09-29 | 2022-11-29 | 深哲新材料(广州)有限公司 | 一种水性涂料用消泡助剂及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5431853A (en) * | 1992-04-27 | 1995-07-11 | Nikko Chemical Institute Inc. | Modified silicone oil-in-water emulsion defoaming agent and defoaming method using it |
EP0887383B1 (en) * | 1997-06-27 | 2004-03-24 | Shin-Etsu Chemical Co., Ltd. | Silicone-based composition |
CN1613537A (zh) * | 2004-09-22 | 2005-05-11 | 曹治平 | 一种高温消泡剂及其制备方法 |
CN1919936A (zh) * | 2006-08-31 | 2007-02-28 | 南京四新科技应用研究所有限公司 | 一种用于水性体系有机硅消泡剂及其制备方法 |
CN101053706A (zh) * | 2007-04-30 | 2007-10-17 | 南京四新科技应用研究所有限公司 | 一种通用消泡剂的制备及其应用 |
CN102527096A (zh) * | 2011-05-12 | 2012-07-04 | 湖北新四海化工股份有限公司 | 一种有机硅消泡剂及其制备方法 |
-
2013
- 2013-02-20 CN CN201310054599.2A patent/CN103111101B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5431853A (en) * | 1992-04-27 | 1995-07-11 | Nikko Chemical Institute Inc. | Modified silicone oil-in-water emulsion defoaming agent and defoaming method using it |
EP0887383B1 (en) * | 1997-06-27 | 2004-03-24 | Shin-Etsu Chemical Co., Ltd. | Silicone-based composition |
CN1613537A (zh) * | 2004-09-22 | 2005-05-11 | 曹治平 | 一种高温消泡剂及其制备方法 |
CN1919936A (zh) * | 2006-08-31 | 2007-02-28 | 南京四新科技应用研究所有限公司 | 一种用于水性体系有机硅消泡剂及其制备方法 |
CN101053706A (zh) * | 2007-04-30 | 2007-10-17 | 南京四新科技应用研究所有限公司 | 一种通用消泡剂的制备及其应用 |
CN102527096A (zh) * | 2011-05-12 | 2012-07-04 | 湖北新四海化工股份有限公司 | 一种有机硅消泡剂及其制备方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104906832A (zh) * | 2015-05-22 | 2015-09-16 | 陕西省石油化工研究设计院 | 一种聚醚酯/矿物油复合型消泡剂及其制备方法 |
CN106943773A (zh) * | 2017-04-20 | 2017-07-14 | 天津亿利科能源科技发展股份有限公司 | 一种海上平台中质原油消泡剂的制备方法 |
WO2020033340A1 (en) * | 2018-08-08 | 2020-02-13 | Kop-Coat, Inc. | Granulated agricultural adjuvant and method of making and using same |
US11957126B2 (en) | 2018-08-08 | 2024-04-16 | Kop-Coat, Inc. | Granulated agricultural adjuvant and method of making and using same |
CN110465119A (zh) * | 2019-08-28 | 2019-11-19 | 启东曦瑞新材料科技有限公司 | 一种矿物油消泡剂的制备方法 |
CN113069796A (zh) * | 2020-01-03 | 2021-07-06 | 万华化学集团股份有限公司 | 一种可用于水性涂料的有机硅消泡剂及其制备方法 |
CN115400464A (zh) * | 2022-09-29 | 2022-11-29 | 深哲新材料(广州)有限公司 | 一种水性涂料用消泡助剂及其制备方法 |
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Denomination of invention: Double-end-blocked polyether modified silicone-oil defoaming agent and method for preparing same Effective date of registration: 20150410 Granted publication date: 20150107 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: Xi'an Suny Fine Chemicals Co., Ltd. Registration number: 2015990000279 |
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