CN102826580B - 氯化钙的制备方法 - Google Patents
氯化钙的制备方法 Download PDFInfo
- Publication number
- CN102826580B CN102826580B CN2012103330131A CN201210333013A CN102826580B CN 102826580 B CN102826580 B CN 102826580B CN 2012103330131 A CN2012103330131 A CN 2012103330131A CN 201210333013 A CN201210333013 A CN 201210333013A CN 102826580 B CN102826580 B CN 102826580B
- Authority
- CN
- China
- Prior art keywords
- calcium chloride
- chloride solution
- solution
- lime powder
- ammonium chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 title claims abstract description 98
- 239000001110 calcium chloride Substances 0.000 title claims abstract description 36
- 229910001628 calcium chloride Inorganic materials 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 128
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000000243 solution Substances 0.000 claims abstract description 82
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 64
- 238000000034 method Methods 0.000 claims abstract description 64
- 230000008569 process Effects 0.000 claims abstract description 54
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 52
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 52
- 239000004571 lime Substances 0.000 claims abstract description 52
- 239000000843 powder Substances 0.000 claims abstract description 52
- 239000007787 solid Substances 0.000 claims abstract description 52
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 50
- 238000002156 mixing Methods 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- 239000012452 mother liquor Substances 0.000 claims abstract description 20
- 239000012047 saturated solution Substances 0.000 claims abstract description 20
- 239000006227 byproduct Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 43
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 239000011575 calcium Substances 0.000 claims description 11
- 239000007790 solid phase Substances 0.000 claims description 11
- 238000005649 metathesis reaction Methods 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000013589 supplement Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 230000000740 bleeding effect Effects 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 5
- 239000000047 product Substances 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 230000036632 reaction speed Effects 0.000 abstract 1
- 239000012265 solid product Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 230000009615 deamination Effects 0.000 description 4
- 238000006481 deamination reaction Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- -1 by changing feed way Substances 0.000 description 1
- AMAICRYCMCVAHT-UHFFFAOYSA-K calcium;sodium;trichloride Chemical compound [Na+].[Cl-].[Cl-].[Cl-].[Ca+2] AMAICRYCMCVAHT-UHFFFAOYSA-K 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Fertilizers (AREA)
Abstract
Description
温度℃ | 0 | 10 | 20 | 30 | 40 | 50 | 60 | 70 | 80 | 90 | 100 |
重量% | 22.7 | 25.0 | 27.1 | 29.3 | 31.4 | 33.5 | 35.6 | 37.6 | 39.6 | 41.6 | 43.6 |
Claims (2)
Priority Applications (1)
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CN2012103330131A CN102826580B (zh) | 2012-09-11 | 2012-09-11 | 氯化钙的制备方法 |
Applications Claiming Priority (1)
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CN2012103330131A CN102826580B (zh) | 2012-09-11 | 2012-09-11 | 氯化钙的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102826580A CN102826580A (zh) | 2012-12-19 |
CN102826580B true CN102826580B (zh) | 2013-11-13 |
Family
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Family Applications (1)
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CN2012103330131A Active CN102826580B (zh) | 2012-09-11 | 2012-09-11 | 氯化钙的制备方法 |
Country Status (1)
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CN (1) | CN102826580B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104192861A (zh) * | 2014-08-22 | 2014-12-10 | 江苏德邦化学工业集团有限公司 | 联碱法氯化铵分解回收氨副产氯化钙溶液的方法 |
CN106495197B (zh) * | 2016-09-30 | 2017-10-27 | 江苏海企技术工程股份有限公司 | 一种降低无水氯化钙溶解液浊度的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3329479A (en) * | 1964-04-21 | 1967-07-04 | Hustinx Edmond | Process for recovering calcium chloride from the ammonium chloride waste liquor of the ammonia soda process |
CN101941719A (zh) * | 2010-05-25 | 2011-01-12 | 河北科技大学 | 一种氯化铵分解生产氨联产碱式氯化钙的方法 |
CN102145912A (zh) * | 2011-03-01 | 2011-08-10 | 大连大化工程设计有限公司 | 利用氨碱滤过母液制备氯化钙溶液的工艺方法 |
-
2012
- 2012-09-11 CN CN2012103330131A patent/CN102826580B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3329479A (en) * | 1964-04-21 | 1967-07-04 | Hustinx Edmond | Process for recovering calcium chloride from the ammonium chloride waste liquor of the ammonia soda process |
CN101941719A (zh) * | 2010-05-25 | 2011-01-12 | 河北科技大学 | 一种氯化铵分解生产氨联产碱式氯化钙的方法 |
CN102145912A (zh) * | 2011-03-01 | 2011-08-10 | 大连大化工程设计有限公司 | 利用氨碱滤过母液制备氯化钙溶液的工艺方法 |
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CN102826580A (zh) | 2012-12-19 |
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CB03 | Change of inventor or designer information |
Inventor after: Li Dongchan Inventor after: Yuan Junsheng Inventor after: Wang Jun Inventor after: Liu Yanlan Inventor before: Yuan Junsheng Inventor before: Li Dongchan Inventor before: Wang Jun Inventor before: Liu Yanlan |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: YUAN JUNSHENG LI DONGCHAN WANG JUN LIU YANLAN TO: LI DONGCHAN YUAN JUNSHENG WANG JUN LIU YANLAN |
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TR01 | Transfer of patent right |
Effective date of registration: 20190114 Address after: 256600 Gaotian, Mashanzi Town, Beihai New Area, Binzhou City, Shandong Province Patentee after: Jinsheng Ocean Technology Co.,Ltd. Address before: 300401 Hebei University of Technology, 5304 Xiping Road, Beichen District, Tianjin Patentee before: Hebei University of Technology |
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Address after: 256600 Gaotian, Mashanzi Town, Beihai New Area, Binzhou City, Shandong Province Patentee after: Jinsheng Marine Technology Co.,Ltd. Address before: 256600 Ma Shan Zi Zhen Gao Tian, Beihai New District, Binzhou City, Shandong Province Patentee before: Jinsheng Ocean Technology Co.,Ltd. |
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Address after: 256600 Huitai Blue Industrial Park, Beihai Economic Development Zone, Binzhou, Shandong Patentee after: Jinsheng Marine Technology Co.,Ltd. Address before: 256600 Gaotian, Mashanzi Town, Beihai New Area, Binzhou City, Shandong Province Patentee before: Jinsheng Marine Technology Co.,Ltd. |
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