CN102212414B - 碱催化毛叶山桐子油和废油制取生物柴油及方法 - Google Patents
碱催化毛叶山桐子油和废油制取生物柴油及方法 Download PDFInfo
- Publication number
- CN102212414B CN102212414B CN2011101040549A CN201110104054A CN102212414B CN 102212414 B CN102212414 B CN 102212414B CN 2011101040549 A CN2011101040549 A CN 2011101040549A CN 201110104054 A CN201110104054 A CN 201110104054A CN 102212414 B CN102212414 B CN 102212414B
- Authority
- CN
- China
- Prior art keywords
- oil
- idesia polycarpa
- mixing
- alkali
- waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003513 alkali Substances 0.000 title abstract description 7
- 238000006555 catalytic reaction Methods 0.000 title abstract description 7
- 241000538126 Idesia polycarpa var. vestita Species 0.000 title abstract 5
- 239000003225 biodiesel Substances 0.000 title abstract 5
- 238000002156 mixing Methods 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000009874 alkali refining Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 239000002551 biofuel Substances 0.000 claims description 35
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 33
- 241001299699 Idesia Species 0.000 claims description 32
- 239000002585 base Substances 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000002283 diesel fuel Substances 0.000 claims description 12
- 230000036571 hydration Effects 0.000 claims description 12
- 238000006703 hydration reaction Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
- 229910003023 Mg-Al Inorganic materials 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 114
- 235000019198 oils Nutrition 0.000 abstract description 114
- 239000002994 raw material Substances 0.000 abstract description 7
- 241001465754 Metazoa Species 0.000 abstract description 6
- 238000011084 recovery Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 2
- 239000010775 animal oil Substances 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 230000000887 hydrating effect Effects 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- 238000011161 development Methods 0.000 description 15
- 230000018109 developmental process Effects 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000000126 substance Substances 0.000 description 7
- 235000014593 oils and fats Nutrition 0.000 description 5
- 238000004821 distillation Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000005815 base catalysis Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 244000036905 Benincasa cerifera Species 0.000 description 2
- 235000011274 Benincasa cerifera Nutrition 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000010503 gourd oil Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 244000247747 Coptis groenlandica Species 0.000 description 1
- 235000002991 Coptis groenlandica Nutrition 0.000 description 1
- 240000006766 Cornus mas Species 0.000 description 1
- 244000147058 Derris elliptica Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241001415765 Polycarpa Species 0.000 description 1
- 229920000263 Rubber seed oil Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 240000001866 Vernicia fordii Species 0.000 description 1
- 244000089698 Zanthoxylum simulans Species 0.000 description 1
- 235000009932 Zanthoxylum simulans Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 208000012839 conversion disease Diseases 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 241000894007 species Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000004808 supercritical fluid chromatography Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2011101040549A CN102212414B (zh) | 2011-04-26 | 2011-04-26 | 碱催化毛叶山桐子油和废油制取生物柴油及方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011101040549A CN102212414B (zh) | 2011-04-26 | 2011-04-26 | 碱催化毛叶山桐子油和废油制取生物柴油及方法 |
Publications (2)
Publication Number | Publication Date |
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CN102212414A CN102212414A (zh) | 2011-10-12 |
CN102212414B true CN102212414B (zh) | 2013-04-10 |
Family
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CN2011101040549A Expired - Fee Related CN102212414B (zh) | 2011-04-26 | 2011-04-26 | 碱催化毛叶山桐子油和废油制取生物柴油及方法 |
Country Status (1)
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CN (1) | CN102212414B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106244337A (zh) * | 2016-08-03 | 2016-12-21 | 佛山市盈合电力燃料有限公司 | 一种供汽车使用的生物柴油 |
CN108795578A (zh) * | 2018-07-06 | 2018-11-13 | 扬州工业职业技术学院 | 一种利用固体碱催化酯交换制备生物柴油的方法 |
CN109880696A (zh) * | 2019-03-04 | 2019-06-14 | 扬州中天利新材料股份有限公司 | 一种采用废弃油脂制备生物柴油的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101358141A (zh) * | 2008-09-28 | 2009-02-04 | 四川省国政生物质能源科技发展股份有限公司 | 用固体碱催化毛叶山桐子油制备生物柴油的方法 |
CN101608131A (zh) * | 2008-06-20 | 2009-12-23 | 华东理工大学 | 一种无副产甘油的生物柴油制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1687314A (zh) * | 2005-04-27 | 2005-10-26 | 莫春礼 | 用高酸值废弃动植物油生产生物柴油的工艺 |
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2011
- 2011-04-26 CN CN2011101040549A patent/CN102212414B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101608131A (zh) * | 2008-06-20 | 2009-12-23 | 华东理工大学 | 一种无副产甘油的生物柴油制备方法 |
CN101358141A (zh) * | 2008-09-28 | 2009-02-04 | 四川省国政生物质能源科技发展股份有限公司 | 用固体碱催化毛叶山桐子油制备生物柴油的方法 |
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Publication number | Publication date |
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CN102212414A (zh) | 2011-10-12 |
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Owner name: SICHUAN ZHIYU BIOLOGICAL ENERGY TECHNOLOGY CO., LT Free format text: FORMER OWNER: LIU CHANGGEN Effective date: 20120918 |
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Free format text: CORRECT: ADDRESS; FROM: 610041 CHENGDU, SICHUAN PROVINCE TO: 621000 MIANYANG, SICHUAN PROVINCE |
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Effective date of registration: 20120918 Address after: 621000, No. 6, building 1, 2, north section of torch West Street, Mianyang hi tech Zone, Sichuan, 2 Applicant after: SICHUAN ZHIYU BIO-ENERGY SOURCE TECHNOLOGY Co.,Ltd. Address before: 610041 No. 13 East Yulin street, Chengdu, Sichuan, Wuhou District Applicant before: Liu Changgen |
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Owner name: GUANGDONG DINGRONG ECOLOGICAL AGRICULTURE DEVELOPM Free format text: FORMER OWNER: SICHUAN ZHIYU BIOLOGICAL ENERGY TECHNOLOGY CO., LTD. Effective date: 20150724 |
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Effective date of registration: 20150724 Address after: Guangning County, Guangdong province 526334 Zhaoqing city Jiangtun town (formerly radio station and alliance building) Patentee after: Guangdong Ding Rong Ecological Agriculture Development Co.,Ltd. Address before: 621000, No. 6, building 1, 2, north section of torch West Street, Mianyang hi tech Zone, Sichuan, 2 Patentee before: SICHUAN ZHIYU BIO-ENERGY SOURCE TECHNOLOGY Co.,Ltd. |
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C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: Guangning County, Guangdong province 526334 Zhaoqing city Jiangtun town (formerly radio station and alliance building) Patentee after: GUANGDONG DINGFENG ECOLOGICAL AGRICULTURE DEVELOPMENT Co.,Ltd. Address before: Guangning County, Guangdong province 526334 Zhaoqing city Jiangtun town (formerly radio station and alliance building) Patentee before: Guangdong Ding Rong Ecological Agriculture Development Co.,Ltd. |
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Granted publication date: 20130410 |