CN101824550A - 高纯镍萃取提纯工艺 - Google Patents
高纯镍萃取提纯工艺 Download PDFInfo
- Publication number
- CN101824550A CN101824550A CN200910096246A CN200910096246A CN101824550A CN 101824550 A CN101824550 A CN 101824550A CN 200910096246 A CN200910096246 A CN 200910096246A CN 200910096246 A CN200910096246 A CN 200910096246A CN 101824550 A CN101824550 A CN 101824550A
- Authority
- CN
- China
- Prior art keywords
- extraction
- nickel
- organic phase
- saponification
- carrying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 32
- 238000000605 extraction Methods 0.000 claims abstract description 73
- 238000007127 saponification reaction Methods 0.000 claims abstract description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 33
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011777 magnesium Substances 0.000 claims abstract description 22
- 239000012074 organic phase Substances 0.000 claims abstract description 21
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 230000011218 segmentation Effects 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 150000002739 metals Chemical class 0.000 claims abstract description 7
- 239000007800 oxidant agent Substances 0.000 claims abstract description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 6
- 230000001590 oxidative effect Effects 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 12
- 239000001117 sulphuric acid Substances 0.000 claims description 10
- 235000011149 sulphuric acid Nutrition 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000012071 phase Substances 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 5
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000013049 sediment Substances 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- ZGBSOTLWHZQNLH-UHFFFAOYSA-N [Mg].S(O)(O)(=O)=O Chemical compound [Mg].S(O)(O)(=O)=O ZGBSOTLWHZQNLH-UHFFFAOYSA-N 0.000 claims description 3
- 150000002815 nickel Chemical class 0.000 claims description 3
- 238000005352 clarification Methods 0.000 claims description 2
- 239000012452 mother liquor Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 abstract description 18
- 238000000034 method Methods 0.000 abstract description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 5
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 5
- 239000002893 slag Substances 0.000 abstract description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- 239000010413 mother solution Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000002910 solid waste Substances 0.000 abstract 1
- 239000010949 copper Substances 0.000 description 19
- 239000007788 liquid Substances 0.000 description 18
- 239000011572 manganese Substances 0.000 description 12
- 239000011701 zinc Substances 0.000 description 12
- 229910052802 copper Inorganic materials 0.000 description 8
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 7
- 229910017052 cobalt Inorganic materials 0.000 description 7
- 239000010941 cobalt Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 206010067171 Regurgitation Diseases 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 4
- 238000004070 electrodeposition Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012716 precipitator Substances 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- OGJLPLDTKZHLLH-UHFFFAOYSA-N [Ca].[Co] Chemical compound [Ca].[Co] OGJLPLDTKZHLLH-UHFFFAOYSA-N 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- RYTYSMSQNNBZDP-UHFFFAOYSA-N cobalt copper Chemical compound [Co].[Cu] RYTYSMSQNNBZDP-UHFFFAOYSA-N 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
组成 | Ni | Co | Fe | Cu | Mn | Zn | Ca | Mg | 备注 |
含量g/L | 30~60 | 0.1~1.0 | 0.01 | ~0.5 | 0.1~2.0 | ~0.1 | ~0.5 | 1~10 |
段数 | 萃取 | 反萃Co | 反萃Cu、Mn、Ca等 | 反Fe | 皂化 | 沉清 |
级数 | 6 | 3 | 3 | 3 | 1 | 4 |
组成 | Ni | Co | Fe | Cu | Mn | Zn | Ca | Mg | 备注 |
料液 | 55.0 | 0.15 | 0.01 | 0.5 | 1.5 | 0.05 | 0.4 | 1.5 | |
萃余液 | 54.5 | 0.001 | 0.0005 | 0.0003 | 0.0003 | 0.0001 | 0.001 | 1.49 |
段数 | 萃取 | 反萃1 | 反萃2 | 反Fe | 皂化 | 沉清 |
级数 | 5~9 | 6~12 | 3~8 | 2~4 | 1~3 | 4~8 |
组成 | Ni | Co | Fe | Cu | Mn | Ca | Mg | 备注 |
料液 | 54.5 | 0.001 | 0.0005 | 0.0003 | 0.0003 | 0.001 | 1.49 | |
Ni液1 | 90.5 | 0.001 | 0.0004 | 0.0003 | 0.0003 | 0.001 | 0.07 | 作电积阴极液 |
Ni液2 | 100.5 | 0.001 | 0.0004 | 0.0003 | 0.0003 | 0.001 | 0.002 | NiO原料液 |
组成 | Ni | Co | Fe | Cu | Mn | Zn | Ca | Mg | 备注 |
料液 | 45 | 1.05 | 0.05 | 0.5 | 2.0 | 0.1 | 0.5 | 2.5 | |
P204萃余液 | 44.8 | 0.001 | 0.0005 | 0.0003 | 0.0003 | 0.0003 | 0.001 | 2.48 |
组成 | Ni | Co | Fe | Cu | Mn | Zn | Ca | Mg | 备注 |
P507反萃液1 | 85.0 | 0.0007 | 0.0005 | 0.0003 | 0.0003 | 0.0002 | 0.001 | 0.15 | 电积液 |
P507反萃液2 | 92.5 | 0.0007 | 0.0005 | 0.0003 | 0.0003 | 0.0002 | 0.001 | 0.002 | NiO原料液 |
组成 | Ni | Co | Fe | Cu | Mn | Zn | Ca | Mg | 备注 |
料液 | 60.0 | 0.5 | 0.05 | 0.5 | 1.6 | 0.1 | 0.45 | 2.3 | |
P204萃余液 | 59.5 | 0.001 | 0.0005 | 0.0003 | 0.0003 | 0.0003 | 0.001 | 2.2 | |
P507反萃液1 | 90.0 | 0.001 | 0.0004 | 0.0003 | 0.0003 | 0.0002 | 0.001 | 0.01 | 电积液 |
P507反萃液2 | 95.0 | 0.0005 | 0.0004 | 0.0003 | 0.0003 | 0.0002 | 0.001 | 0.001 | NiO原料液 |
Claims (4)
Priority Applications (1)
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CN2009100962462A CN101824550B (zh) | 2009-03-02 | 2009-03-02 | 高纯镍萃取提纯工艺 |
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CN2009100962462A CN101824550B (zh) | 2009-03-02 | 2009-03-02 | 高纯镍萃取提纯工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101824550A true CN101824550A (zh) | 2010-09-08 |
CN101824550B CN101824550B (zh) | 2012-05-23 |
Family
ID=42688713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2009100962462A Expired - Fee Related CN101824550B (zh) | 2009-03-02 | 2009-03-02 | 高纯镍萃取提纯工艺 |
Country Status (1)
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CN (1) | CN101824550B (zh) |
Cited By (19)
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CN102091789A (zh) * | 2010-12-21 | 2011-06-15 | 丹阳市求精合金钢有限公司 | 一种亚微米级链球状超细镍粉的制备方法 |
CN102251253A (zh) * | 2011-06-24 | 2011-11-23 | 厦门大学 | 一种电解液中镍、铁、铜的萃取分离方法 |
CN102627333A (zh) * | 2012-04-24 | 2012-08-08 | 中南大学 | 一种精制硫酸镍的方法 |
CN102676814A (zh) * | 2012-06-06 | 2012-09-19 | 金柯有色金属有限公司 | 一种硫酸镍溶液中杂质铁的去除方法 |
CN103555954A (zh) * | 2013-11-04 | 2014-02-05 | 湖南格瑞普新能源有限公司 | 从废旧镍氢电池中回收稀土元素的方法 |
CN103946401A (zh) * | 2011-11-22 | 2014-07-23 | 住友金属矿山株式会社 | 高纯度硫酸镍的制造方法 |
CN105567981A (zh) * | 2016-02-26 | 2016-05-11 | 金川集团股份有限公司 | 一种从废旧镍氢电池中提取镍制备电解镍的方法 |
CN105669437A (zh) * | 2014-11-21 | 2016-06-15 | 中国石油化工股份有限公司 | 一种异辛酸镍的制备方法 |
CN105714119A (zh) * | 2016-04-08 | 2016-06-29 | 金川集团股份有限公司 | 一种用离子交换溶液从含镍的钙镁渣中回收镍的方法 |
CN106319210A (zh) * | 2015-06-16 | 2017-01-11 | 天津市茂联科技有限公司 | 一种提高p204萃取箱杂质分离效率的方法及萃取设备 |
CN108751267A (zh) * | 2018-06-30 | 2018-11-06 | 贵州中伟资源循环产业发展有限公司 | 一种精制硫酸镍的方法 |
CN111244437A (zh) * | 2020-01-19 | 2020-06-05 | 杨雄强 | 一种三元前驱体原材料的制备方法 |
CN112320860A (zh) * | 2020-11-30 | 2021-02-05 | 北京博萃循环科技有限公司 | 一种提纯硫酸镍的方法 |
CN112746168A (zh) * | 2019-10-30 | 2021-05-04 | 平顶山德源精细化学品有限公司 | 一种用组合萃取剂处理红土镍矿浸液的工艺方法 |
CN114134331A (zh) * | 2021-11-25 | 2022-03-04 | 苏州博萃循环科技有限公司 | 一种用石油pox渣制备硫酸氧钒和硫酸镍的方法 |
CN114873660A (zh) * | 2022-04-21 | 2022-08-09 | 紫金铜业有限公司 | 一种粗硫酸镍溶液中脱出铜铁锌的方法 |
CN115057481A (zh) * | 2022-06-09 | 2022-09-16 | 云南金浔资源股份有限公司 | 一种高性能锂离子动力电池使用硫酸钴生产方法 |
CN115161476A (zh) * | 2022-07-20 | 2022-10-11 | 万宝矿产有限公司 | 一种降低次生硫化铜矿生物堆浸***中酸铁浓度的方法 |
CN116987905A (zh) * | 2023-08-10 | 2023-11-03 | 广东海文环保技术有限公司 | 一种电镀含镍污泥中重金属回收方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PH31603A (en) * | 1994-03-22 | 1998-11-03 | Goro Nickels S A | Process for the extraction and separation of nickel and/or cobalt. |
-
2009
- 2009-03-02 CN CN2009100962462A patent/CN101824550B/zh not_active Expired - Fee Related
Cited By (26)
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CN102091789A (zh) * | 2010-12-21 | 2011-06-15 | 丹阳市求精合金钢有限公司 | 一种亚微米级链球状超细镍粉的制备方法 |
CN102251253B (zh) * | 2011-06-24 | 2013-12-04 | 厦门大学 | 一种电解液中镍、铁、铜的萃取分离方法 |
CN102251253A (zh) * | 2011-06-24 | 2011-11-23 | 厦门大学 | 一种电解液中镍、铁、铜的萃取分离方法 |
CN107032417A (zh) * | 2011-11-22 | 2017-08-11 | 住友金属矿山株式会社 | 高纯度硫酸镍的制造方法 |
CN103946401A (zh) * | 2011-11-22 | 2014-07-23 | 住友金属矿山株式会社 | 高纯度硫酸镍的制造方法 |
CN102627333B (zh) * | 2012-04-24 | 2014-07-23 | 中南大学 | 一种精制硫酸镍的方法 |
CN102627333A (zh) * | 2012-04-24 | 2012-08-08 | 中南大学 | 一种精制硫酸镍的方法 |
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CN103555954A (zh) * | 2013-11-04 | 2014-02-05 | 湖南格瑞普新能源有限公司 | 从废旧镍氢电池中回收稀土元素的方法 |
CN105669437B (zh) * | 2014-11-21 | 2017-10-31 | 中国石油化工股份有限公司 | 一种异辛酸镍的制备方法 |
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CN108751267A (zh) * | 2018-06-30 | 2018-11-06 | 贵州中伟资源循环产业发展有限公司 | 一种精制硫酸镍的方法 |
CN112746168A (zh) * | 2019-10-30 | 2021-05-04 | 平顶山德源精细化学品有限公司 | 一种用组合萃取剂处理红土镍矿浸液的工艺方法 |
CN111244437A (zh) * | 2020-01-19 | 2020-06-05 | 杨雄强 | 一种三元前驱体原材料的制备方法 |
CN112320860A (zh) * | 2020-11-30 | 2021-02-05 | 北京博萃循环科技有限公司 | 一种提纯硫酸镍的方法 |
CN112320860B (zh) * | 2020-11-30 | 2023-02-17 | 北京博萃循环科技有限公司 | 一种提纯硫酸镍的方法 |
CN114134331A (zh) * | 2021-11-25 | 2022-03-04 | 苏州博萃循环科技有限公司 | 一种用石油pox渣制备硫酸氧钒和硫酸镍的方法 |
CN114873660A (zh) * | 2022-04-21 | 2022-08-09 | 紫金铜业有限公司 | 一种粗硫酸镍溶液中脱出铜铁锌的方法 |
CN115057481A (zh) * | 2022-06-09 | 2022-09-16 | 云南金浔资源股份有限公司 | 一种高性能锂离子动力电池使用硫酸钴生产方法 |
CN115161476A (zh) * | 2022-07-20 | 2022-10-11 | 万宝矿产有限公司 | 一种降低次生硫化铜矿生物堆浸***中酸铁浓度的方法 |
CN115161476B (zh) * | 2022-07-20 | 2023-06-02 | 万宝矿产有限公司 | 一种降低次生硫化铜矿生物堆浸***中酸铁浓度的方法 |
CN116987905A (zh) * | 2023-08-10 | 2023-11-03 | 广东海文环保技术有限公司 | 一种电镀含镍污泥中重金属回收方法 |
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