CN101740192B - Thermoplastic magnetorheological elastomer composite material and preparation method thereof - Google Patents

Thermoplastic magnetorheological elastomer composite material and preparation method thereof Download PDF

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Publication number
CN101740192B
CN101740192B CN2009103121986A CN200910312198A CN101740192B CN 101740192 B CN101740192 B CN 101740192B CN 2009103121986 A CN2009103121986 A CN 2009103121986A CN 200910312198 A CN200910312198 A CN 200910312198A CN 101740192 B CN101740192 B CN 101740192B
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Prior art keywords
thermoplastic
composite material
elastomer composite
magnetorheological elastomer
preparation
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CN2009103121986A
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CN101740192A (en
Inventor
乔秀颖
杨涛
孙康
卢秀首
陈晓东
李盟
杨康
谢宏恩
殷奇
王东
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Shanghai Jiaotong University
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Shanghai Jiaotong University
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Abstract

The invention relates to a thermoplastic magnetorheological elastomer composite material and a preparation method thereof, belonging to the technical field of materials. The composite material comprises the following components in percentage by weight: 40-85% of carbonyl iron, 0.4-2.0% of coupling agent, 8-30% of thermoplastic elastomer and 6-40% of plasticizing agent. The preparation method of the composite material comprises the following steps of: step 1, taking all the components in the percentage by weight; step 2, stirring the carbonyl iron and the coupling agent in a high-speed mixer to obtain a mixture; step 3, stirring the mixture, the thermoplastic elastomer and the plasticizing agent in a low-speed mixer to obtain a premix; step 4, taking the premix, mixing and milling the premix by a double screw extruder at 180-240 DEG C, extruding and granulating; and then, molding the granules at 180-240 DEG C under the action of a magnetic field, cooling, forming and demolding to obtain the thermoplastic magnetorheological elastomer composite material. The method of the invention has simple processes, and the thermoplastic magnetorheological elastomer composite material prepared by the method of the invention has excellent mechanical properties, stability and magnetic response efficiency, can be formed by multiple processes and can realize industrialization and commercialization easily.

Description

Thermoplastic magnetorheological elastomer composite material and preparation method thereof
Technical field
The present invention relates to the composite material in a kind of material technology field and preparation method thereof, specifically is a kind of thermoplastic magnetorheological elastomer composite material and preparation method thereof.
Background technology
Magnetorheological materials is that a kind of rheological property can be by the novel intelligent material of magnetic field control.Magnetic rheology elastic body is a new branch of magnetorheological materials; It is that soft magnetic particles with micro-meter scale is mixed in liquid state or the visco-plastic body high molecular polymer; Form to solidify after the special ordered structure and form; Such material is in magnetic field, and all performances of its mechanics, electricity will change with adding magnetic field intensity, and these unique advantages make it in safety engineering fields such as the suspension of tuning bump leveller, adjustable rigidity and adjustable impedance surfaces great application prospect arranged.Magnetic rheology elastic body has magnetorheological materials and elastomeric advantage concurrently, as responds soon, good reversibility, and controlled ability is strong etc., has overcome shortcomings such as magnetic flow liquid sedimentation, poor stability again, thereby becomes a focus of magnetorheological materials research in recent years.Can be made into devices such as various vibration damping holders, suspension, impact bump leveller, vibration isolator with magnetic rheology elastic body, can simplify mechanical structure greatly, the control performance of the system that enhances your vigilance is accomplished the function that some traditional mechanical structures are difficult to realize.
Literature search through to prior art finds that Chinese utility model patent ZL 200820002729.2 discloses a kind of magnetic rheology elastic body vibration isolator; China utility model patent ZL 200620154712.X discloses a kind of rotor oscillation control and has used the magnetic rheology elastic body damper; The magnetic rheology elastic body that said vibration isolator and damper adopt is to be the magnetic rheology elastic body of matrix with silicon rubber or natural rubber; But; These rubber-based magnetorheological elastomer composite materials; Have that mechanical strength is undesirable, processing is inconvenient (auxiliary agent is many, need to vulcanize, can't kinds of processes moulding), heat-resisting weather-proof many shortcomings such as wear no resistance; Magnetic rheology effect (amplitude of variation of modulus of elasticity) is still waiting further raising simultaneously, makes magnetic rheology elastic body receive very big restriction in the application in safety engineering fields such as damping isolation device.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, provide a kind of thermoplastic magnetorheological elastomer multiple
Condensation material and preparation method thereof.Method technology of the present invention is simple, and the thermoplastic magnetorheological elastomer composite material mechanical performance of preparation, stability and magnetic response usefulness are good, but the kinds of processes moulding is prone to realize industrialization and commercialization.
The present invention realizes through following technical scheme:
The present invention relates to a kind of thermoplastic magnetorheological elastomer composite material, its component and percentage by weight are: carbonyl iron 40~85%, coupling agent 0.4~2.0%, thermoplastic elastomer (TPE) 8~30%, plasticizer 6~40%.
Said coupling agent is silane coupler, titanate coupling agent or stearic acid.
Said thermoplastic elastomer (TPE) is styrene type thermoplastic elastomer (TPE), SIS/SEBS (SEBS), styrene-ethylene-propylene-styrene copolymer (SEPS) or styrene-ethylene-ethylene-propylene-styrol copolymer (SEEPS).
Said plasticizer is white oil or naphthenic rubber oil.
The invention still further relates to a kind of preparation method of aforesaid thermoplastic magnetorheological elastomer composite material, comprise the steps:
Step 1 is got each component by weight percentage;
Step 2 stirs carbonyl iron and coupling agent in high-speed mixer, get mixture;
Step 3 stirs mixture and thermoplastic elastomer (TPE), plasticizer in low speed mixer, get premix;
Step 4 is got premix, uses double screw extruder mixing under 180~240 ℃, extrudes granulation;
With particle mold pressing under 180~240 ℃ of the action of a magnetic fields, the cooling forming demoulding promptly gets thermoplastic magnetorheological elastomer composite material afterwards.
In step 2 and the step 3, the time of said stirring is 10~20min.
In the step 4, the time of said mold pressing is 20~40min.
Compared with prior art; The present invention has following beneficial effect: method technology of the present invention is simple; Thermoplastic magnetorheological elastomer composite material mechanical performance, stability and the magnetic response usefulness of preparation are good, but the kinds of processes moulding is prone to realize industrialization and commercialization.
Embodiment
Present embodiment provided detailed execution mode and process, but protection scope of the present invention is not limited to following embodiment being to implement under the prerequisite with technical scheme of the present invention.The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition, or the condition of advising according to manufacturer.
Embodiment 1
The component of the thermoplastic magnetorheological elastomer composite material that present embodiment relates to and parts by weight are:
85 parts of carbonyl irons, 1 part of silane coupler, 8 parts of SIS/SEBSs (SEBS), 6 parts of white oils.
The method for preparing thermoplastic magnetorheological elastomer composite material comprises the steps:
Step 1 is got each component by weight percentage;
Step 2 stirs 20min with carbonyl iron and silane coupler in high-speed mixer, get mixture;
Step 3 stirs 10min with mixture and SEBS, white oil in low speed mixer, get premix;
Step 4 is got premix, uses double screw extruder mixing under 240 ℃, extrudes granulation; With particle mold pressing 40min under 240 ℃ of the action of a magnetic fields, the cooling forming demoulding promptly gets thermoplastic magnetorheological elastomer composite material afterwards.
Embodiment 2
The component of the thermoplastic magnetorheological elastomer composite material that present embodiment relates to and parts by weight are:
40 parts of carbonyl irons, 0.4 part of titanate coupling agent, 19.6 parts of styrene-ethylenes-propylene-styrene copolymer (SEPS), 40 parts of naphthenic rubber oil.
The method for preparing thermoplastic magnetorheological elastomer composite material comprises the steps:
Step 1 is got each component by weight percentage;
Step 2 stirs 10min with carbonyl iron and titanate coupling agent in high-speed mixer, get mixture;
Step 3 stirs 20min with mixture and SEPS, naphthenic rubber oil in low speed mixer, get premix;
Step 4 is got premix, uses double screw extruder mixing under 180 ℃, extrudes granulation; With particle mold pressing 20min under 1 80 ℃ of the action of a magnetic fields, the cooling forming demoulding promptly gets thermoplastic magnetorheological elastomer composite material afterwards.
Embodiment 3
The component of the thermoplastic magnetorheological elastomer composite material that present embodiment relates to and parts by weight are:
50 parts of carbonyl irons, 2 parts of stearic acid coupling agents, 30 parts of styrene-ethylene-ethylene-propylenes-styrol copolymer (SEEPS), 18 parts of naphthenic rubber oil.
The method for preparing thermoplastic magnetorheological elastomer composite material comprises the steps:
Step 1 is got each component by weight percentage;
Step 2 stirs 15min with carbonyl iron and stearic acid coupling agent in high-speed mixer, get mixture;
Step 3, with mixture and SEEPS, naphthenic rubber oil stirs 15min in low speed mixer, gets premix;
Step 4 is got premix, uses double screw extruder mixing under 210 ℃, extrudes granulation; With particle mold pressing 30min under 210 ℃ of the action of a magnetic fields, the cooling forming demoulding promptly gets thermoplastic magnetorheological elastomer composite material afterwards.
The magnetic response usefulness result of the thermoplastic magnetorheological elastomer composite material of embodiment 1~3 preparation is following: modulus of elasticity is estimated the magnetic response usefulness of thermoplastic magnetorheological elastomer with the variation of externally-applied magnetic field intensity under use MDMA (the dynamic mechanical analysis appearance of externally-applied magnetic field) test implementation example 1~3 prepared thermoplastic magnetorheological elastomer composite material normal temperature that obtains to the relative magnetic rheology effect of the ratio calculation of initial elasticity modulus through the modulus of elasticity increment.The result shows that the relative magnetic rheology effect of the thermoplastic magnetorheological elastomer that embodiment 1~3 prepares is respectively 250%, 80%, 120%.

Claims (7)

1. a thermoplastic magnetorheological elastomer composite material is characterized in that, its component and percentage by weight are: carbonyl iron 40~85%, coupling agent 0.4~2.0%, thermoplastic elastomer (TPE) 8~30%, plasticizer 6~40%.
2. thermoplastic magnetorheological elastomer composite material according to claim 1 is characterized in that, said coupling agent is silane coupler, titanate coupling agent or stearic acid.
3. thermoplastic magnetorheological elastomer composite material according to claim 1; It is characterized in that said thermoplastic elastomer (TPE) is styrene type thermoplastic elastomer (TPE), SIS/SEBS, styrene ethylene-propylene-styrene copolymer or styrene-ethylene-ethylene-propylene-styrol copolymer.
4. thermoplastic magnetorheological elastomer composite material according to claim 1 is characterized in that, said plasticizer is white oil or naphthenic rubber oil.
5. the preparation method of a thermoplastic magnetorheological elastomer composite material according to claim 1 is characterized in that, comprises the steps:
Step 1 is got each component by weight percentage;
Step 2 stirs carbonyl iron and coupling agent in high-speed mixer, get mixture;
Step 3 stirs mixture and thermoplastic elastomer (TPE), plasticizer in low speed mixer, get premix;
Step 4 is got premix, uses double screw extruder mixing under 180~240 ℃, extrudes granulation; With particle mold pressing under 180~240 ℃ of the action of a magnetic fields, the cooling forming demoulding promptly gets thermoplastic magnetorheological elastomer composite material afterwards.
6. the preparation method of thermoplastic magnetorheological elastomer composite material according to claim 5 is characterized in that, in step 2 and the step 3, the time of said stirring is 10~20min.
7. the preparation method of thermoplastic magnetorheological elastomer composite material according to claim 5 is characterized in that, in the step 4, the time of said mold pressing is 20~40min.
CN2009103121986A 2009-12-24 2009-12-24 Thermoplastic magnetorheological elastomer composite material and preparation method thereof Expired - Fee Related CN101740192B (en)

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Publication number Priority date Publication date Assignee Title
CN102737803B (en) * 2012-06-29 2016-04-13 中国科学技术大学 Phase change type magnetorheological material and preparation method thereof
CN105598459B (en) * 2016-01-25 2017-10-27 广东工业大学 A kind of method that magnetic flow liquid is prepared based on ferrous alloy micro wire
CN107418210A (en) * 2017-06-07 2017-12-01 常州市瑞泰物资有限公司 A kind of preparation method of high rheomagnetic magnetorheological elastomer based on silicone rubber
CN108987087A (en) * 2018-07-13 2018-12-11 吴江市聚盈电子材料科技有限公司 A kind of preparation method for adulterating bismuth element magnetic material
CN110319143A (en) * 2019-07-12 2019-10-11 吉林建筑大学 A kind of dismountable bumping post
CN110283373A (en) * 2019-07-19 2019-09-27 航天特种材料及工艺技术研究所 A kind of thermoplastic magnetic composite and preparation method
CN111334357A (en) * 2020-04-14 2020-06-26 无锡中石油润滑脂有限责任公司 Mineral oil lithium-based lubricating grease and preparation process thereof

Citations (1)

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CN1129044A (en) * 1993-06-24 1996-08-14 ***米龙大学 Metal, alloy, or metal carbide nanoparticles and process for forming same

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN1129044A (en) * 1993-06-24 1996-08-14 ***米龙大学 Metal, alloy, or metal carbide nanoparticles and process for forming same

Non-Patent Citations (1)

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赵军等.纳米镍/炭复合材料的制备与磁性表征.《功能材料与器件学报》.2006,第12卷(第2期), *

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