CA1237261A - Method of making a moulded body of foam plastics material - Google Patents
Method of making a moulded body of foam plastics materialInfo
- Publication number
- CA1237261A CA1237261A CA000490053A CA490053A CA1237261A CA 1237261 A CA1237261 A CA 1237261A CA 000490053 A CA000490053 A CA 000490053A CA 490053 A CA490053 A CA 490053A CA 1237261 A CA1237261 A CA 1237261A
- Authority
- CA
- Canada
- Prior art keywords
- film
- mould
- mold
- portions
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
ABSTRACT
Method of making a moulded body of foam plastics material The present invention relates to a method for the manufacture of moulded bodies such as cornices from foam plastics material, the visible side of these bodies being heavily textured or profiled, smooth, non-porous and free from separation elements, with a unit weight of less than 200 kg/m3. In the method, a thin, elastic, heat-deformable film (3) is inserted between two heated mould portions (1, 2 ) in such a way that the film edges are clamped between the superimposed mould edges of the two mould portions (1, 2), a reactive, heat emitting, foaming plastics mixture is introduced through the upper mould portion (1) in such a way that it may be distributed on the film, and the hollow chamber formed between the film and the lower mould portion is evacuated during foaming, such that the film intimately conforms to the shape of the lower mould portion.
Method of making a moulded body of foam plastics material The present invention relates to a method for the manufacture of moulded bodies such as cornices from foam plastics material, the visible side of these bodies being heavily textured or profiled, smooth, non-porous and free from separation elements, with a unit weight of less than 200 kg/m3. In the method, a thin, elastic, heat-deformable film (3) is inserted between two heated mould portions (1, 2 ) in such a way that the film edges are clamped between the superimposed mould edges of the two mould portions (1, 2), a reactive, heat emitting, foaming plastics mixture is introduced through the upper mould portion (1) in such a way that it may be distributed on the film, and the hollow chamber formed between the film and the lower mould portion is evacuated during foaming, such that the film intimately conforms to the shape of the lower mould portion.
Description
123~7Z~;l Method of making a moulded body of ~oam plastics material _______________________________ The present invention relates to a method of making a moulded body of foam plastics material, particularly but not exclusively where the visible side thereof is heavily textured or profiled, smooth and non-porous with a unit weight of less than 200 kg/m3.
Moulded bodies of this type typically comprise cornices or like decorative profiled sections of a length of 2m, which produce a stucco effect after they have been fixed at the join between a wall and a ceiling.
Such moulded bodies have in the past been produced by introducing a plastics mixture to be foamed into a two-part mould provided with a separation medium therein.
The mould parts are conventionally made from silicone rubber or ~rom polyurethane elastomers. It has been observed that the moulds swell because they ~bsorb fluid components from the foaming reaction mixture, and have to be regenerated after lO mould openings.
Also the dimensions of the moulded articles deviate to a considerable ex~ent from the admissible measurement tolerances as a result of the swelling effect.` Consequentally, wastage of up to 15% is produced. Moreover, the maximum number of components ~Z37;~6~
which may be produced using these moulds is only approximately 250 to 300 per mould which has a de-trimental effect on the pr:ice of the moulded body.
In addition, the moulds made from silicone rubber or polyurethane elastomers are ~ifficult to tem~er, which consequently makes reproduceable production difficult.
Further moulds of this type cannot be de-aerated easily as a result of their softness, which leads to bubbles on the surface. It should also be noted that additional problems are caused by the use of separation means which are generally very difficult to remove from the mould body.
It might be thought possible to counter the latter two drawbacks by foaming onto film which has previously been deep drawn. This is only possible, however, with relatively thick film, and the mould bodies obtained are heavily distorted since they are only laminated on one side. Thus, a method of this ( type is not suitable for the production of moulded bodies having a unit weight of less than 200 kg/m3.
Also a method of this type is expensive in terms of apparatus cost and power consumption.
In order to counter these drawbacks we have considered the possibility of using a very thin, elastic, heat-deformable film, which would remain elastic in the end product so as not to lead to any distortion of the mould body. The elastic, heat-deformable film ~ ~37261 would be clamped between two mould por-tions and the plastics mixture to ~e foamed introduced through the upper mould portion such that the film is pressed by the mixture -to be foamed against the lower mould portion.
This method is only successful, as tests carried out by the applicants have shown, with foam plastics mi~tures producing moulded bodies with a unit weight of more than , 500 kg/m3, as it is only mixtures to be foamed of this type which produce the foam pressure required to press the film accurately into fine textured contours of the mould.
With a view to overcoming the aforesaid difficulties and drawbacks the present invention provides a method of making a moulded body of foam plastics material, comprising providing a thin heat de~ormable film between two portions of a mould.
providing foaming plastics material in a space between a first of the mould portions and the film.
producing a partial vacuum between the film and the second of the mould portions, and causing the film to become heated such that the film is urged by the partial vacuum and by pressure of the foaming material into intimate contact with the second mould portion.
37~36~
The invention therefore provides a method which enables the production of longi-tudinal or round, non-distorted, moulded bodies having a unit weight of less than 200 kg/m3, whose visible sides have an accurately produced surface which is heavily textured or profiled, smooth, bubble-free and has no separation elements.
In addition, the method is designed to enabl~ the production, using a mould which has an upper and a lower mould portion, of up to one million moulded articles, with a wastage of less than 2%.
In a preferred form, the invention provides a combination of features which comprise the use of a thin, elastic, heat-deformable film, which retains or recovers its elasticity after moulding, in the use of a foaming plastics mixture which emits heat for the additional heating of the film as well as the use of a tempered mould device and the evacuation of the hollow chamber formed between the film and the lower mould portion, for the purposes of supporting the deformatlon of thin, elastic, heat-deformable film by the foaming pressure.
The invention therefore relates to a method for the manufacture of mould bodies from foam plastics, the visible side of these bodies being heavily textured profiled, smooth, non-porous and free from separation elements and having a unit weight of less than 200 kg/m~
which is characterised in that ~23726~
a) a thin, elas-tic~ heat-deformable film is inserted between two heated mould portions i~ such a way that the film edges are clamped between the super-imposed mould edges of the two mould portiorls, b) a reactive, heat emitting, foaming plastic mixture is introduced through the upper mould portion in such a way that it may be distributed on the film, ! and c) the hollow chamber formed between the film and the lower mould portion is evacuated during foaming, so that the film which is heated both by the heated mould portions and by the heat of reaction given off by the reaction mixture is pressed by the foam pressure together with the vacuum provided so that its contours accurately fit the heavily textured or profiled mould surface of the lower mould portion.
For the purposes of the $nvention any thin elastic or ductile, heat-deformable plastics film, ~ which has an elastic or ductile nature after moulding, is suitable. Film having a thickness of 180 to ~a~m is preferred, and in particular film of this type made from soft polyvinyl chloride.
Whilst carrying out the method, the mould device, or the two mould portions, is kept at a temperature of 55 to 65C. For this purpose, the mould portions are provided with passages through which a corresponding heated medium flows.
Mixtures known to persons skilled in the art are suitable for use as foaming plas-tics mixtures for the purposes of the invention. Two component mixtures which produce a polyurethane hard foam are particularly preferred as foaming plastics mixtures. Similarly, use may also be made of epoxy resin foams or phenol resin foams. With respect to the production of hard polyurethane foams, reference should be made to the "Kunststoffhandbuch" (Plastics handbook), Vol.Vll, Polyurethane, by Vieweg/Hoechtlen (Karl Hanser-Verlag, Munich 1966) and to the references given therein.
In order that the invention may be more fully understood an embodiment thereof will now be described by way of illustrative example with reference to the accompanying drawings wherein:
Figure 1 is a cross-sectional view of a moulded body in the form of a cornice, made by a method according to the invention;
Figure 2 is a schematic perspective view of a pattern of recesses and projections which runs along the length of the cornice, and Figure 3 is a schematic cross-sectional view of a two part mould for mou~ding the cornice shown in Fig.l ~2~ 61 . , .
In the Figures, the reference numerals have the following significance:
l. Upper mould portion
Moulded bodies of this type typically comprise cornices or like decorative profiled sections of a length of 2m, which produce a stucco effect after they have been fixed at the join between a wall and a ceiling.
Such moulded bodies have in the past been produced by introducing a plastics mixture to be foamed into a two-part mould provided with a separation medium therein.
The mould parts are conventionally made from silicone rubber or ~rom polyurethane elastomers. It has been observed that the moulds swell because they ~bsorb fluid components from the foaming reaction mixture, and have to be regenerated after lO mould openings.
Also the dimensions of the moulded articles deviate to a considerable ex~ent from the admissible measurement tolerances as a result of the swelling effect.` Consequentally, wastage of up to 15% is produced. Moreover, the maximum number of components ~Z37;~6~
which may be produced using these moulds is only approximately 250 to 300 per mould which has a de-trimental effect on the pr:ice of the moulded body.
In addition, the moulds made from silicone rubber or polyurethane elastomers are ~ifficult to tem~er, which consequently makes reproduceable production difficult.
Further moulds of this type cannot be de-aerated easily as a result of their softness, which leads to bubbles on the surface. It should also be noted that additional problems are caused by the use of separation means which are generally very difficult to remove from the mould body.
It might be thought possible to counter the latter two drawbacks by foaming onto film which has previously been deep drawn. This is only possible, however, with relatively thick film, and the mould bodies obtained are heavily distorted since they are only laminated on one side. Thus, a method of this ( type is not suitable for the production of moulded bodies having a unit weight of less than 200 kg/m3.
Also a method of this type is expensive in terms of apparatus cost and power consumption.
In order to counter these drawbacks we have considered the possibility of using a very thin, elastic, heat-deformable film, which would remain elastic in the end product so as not to lead to any distortion of the mould body. The elastic, heat-deformable film ~ ~37261 would be clamped between two mould por-tions and the plastics mixture to ~e foamed introduced through the upper mould portion such that the film is pressed by the mixture -to be foamed against the lower mould portion.
This method is only successful, as tests carried out by the applicants have shown, with foam plastics mi~tures producing moulded bodies with a unit weight of more than , 500 kg/m3, as it is only mixtures to be foamed of this type which produce the foam pressure required to press the film accurately into fine textured contours of the mould.
With a view to overcoming the aforesaid difficulties and drawbacks the present invention provides a method of making a moulded body of foam plastics material, comprising providing a thin heat de~ormable film between two portions of a mould.
providing foaming plastics material in a space between a first of the mould portions and the film.
producing a partial vacuum between the film and the second of the mould portions, and causing the film to become heated such that the film is urged by the partial vacuum and by pressure of the foaming material into intimate contact with the second mould portion.
37~36~
The invention therefore provides a method which enables the production of longi-tudinal or round, non-distorted, moulded bodies having a unit weight of less than 200 kg/m3, whose visible sides have an accurately produced surface which is heavily textured or profiled, smooth, bubble-free and has no separation elements.
In addition, the method is designed to enabl~ the production, using a mould which has an upper and a lower mould portion, of up to one million moulded articles, with a wastage of less than 2%.
In a preferred form, the invention provides a combination of features which comprise the use of a thin, elastic, heat-deformable film, which retains or recovers its elasticity after moulding, in the use of a foaming plastics mixture which emits heat for the additional heating of the film as well as the use of a tempered mould device and the evacuation of the hollow chamber formed between the film and the lower mould portion, for the purposes of supporting the deformatlon of thin, elastic, heat-deformable film by the foaming pressure.
The invention therefore relates to a method for the manufacture of mould bodies from foam plastics, the visible side of these bodies being heavily textured profiled, smooth, non-porous and free from separation elements and having a unit weight of less than 200 kg/m~
which is characterised in that ~23726~
a) a thin, elas-tic~ heat-deformable film is inserted between two heated mould portions i~ such a way that the film edges are clamped between the super-imposed mould edges of the two mould portiorls, b) a reactive, heat emitting, foaming plastic mixture is introduced through the upper mould portion in such a way that it may be distributed on the film, ! and c) the hollow chamber formed between the film and the lower mould portion is evacuated during foaming, so that the film which is heated both by the heated mould portions and by the heat of reaction given off by the reaction mixture is pressed by the foam pressure together with the vacuum provided so that its contours accurately fit the heavily textured or profiled mould surface of the lower mould portion.
For the purposes of the $nvention any thin elastic or ductile, heat-deformable plastics film, ~ which has an elastic or ductile nature after moulding, is suitable. Film having a thickness of 180 to ~a~m is preferred, and in particular film of this type made from soft polyvinyl chloride.
Whilst carrying out the method, the mould device, or the two mould portions, is kept at a temperature of 55 to 65C. For this purpose, the mould portions are provided with passages through which a corresponding heated medium flows.
Mixtures known to persons skilled in the art are suitable for use as foaming plas-tics mixtures for the purposes of the invention. Two component mixtures which produce a polyurethane hard foam are particularly preferred as foaming plastics mixtures. Similarly, use may also be made of epoxy resin foams or phenol resin foams. With respect to the production of hard polyurethane foams, reference should be made to the "Kunststoffhandbuch" (Plastics handbook), Vol.Vll, Polyurethane, by Vieweg/Hoechtlen (Karl Hanser-Verlag, Munich 1966) and to the references given therein.
In order that the invention may be more fully understood an embodiment thereof will now be described by way of illustrative example with reference to the accompanying drawings wherein:
Figure 1 is a cross-sectional view of a moulded body in the form of a cornice, made by a method according to the invention;
Figure 2 is a schematic perspective view of a pattern of recesses and projections which runs along the length of the cornice, and Figure 3 is a schematic cross-sectional view of a two part mould for mou~ding the cornice shown in Fig.l ~2~ 61 . , .
In the Figures, the reference numerals have the following significance:
l. Upper mould portion
2. Lower mould portion
3. Film
4. Foam
5. Heating ducts
6. Vacuum chamber
7. Vacuum nozzles
8. Recesses
9. Projections Figure l shows a cross section through an orn-amental profiled section moulded body in the form e.g.
of a cornice, made from plastics foam 4, typically a hard polyurethane foam as aforesaid, and a heat de-formable plastics film 3, typically of P.V.C. as afore-said. Recesses 8 and projections 9 are disposed '~ along the length of the body as shown schematically in Fig.2. The recess 8 and the projection 9 show~ in Fig.l do not lie in the same cross-sectional plane, but behind one another. The recesses 8 and the pro-jections 9 may be formed as shown in outline in Fig.2 and may be ornaments, Figure 2 is a diagrammatic perspective view of the recesses 8 and the projections 9, wherein it can be seen that these recesses and projections may have the form of ornaments.
~23~:6~
Figure 3 is a cross-section through the mould device, which comprises an upper mould portion l and a lower mould portion 2 which are each provided with the heating ducts 5. The mould portion 2 is provided with a surface pattern which de~ines the recesses 8 and projections 9,together with the rest of the ornamental pattern for the cornice. The lower mould portion 2 also in use defines a vacuum chamber 6 and has vacuum nozzles 7, which are connected to a vacuum source(not shown).
To make the moulded body, the two mould portions 1,2 which are preferably of cast aluminium or a different metal or alloy are initially seperated from one another They are brought to the required temperature, typically 55 65C by passing a heated fluid through the ducts 5.
A thin, highly elastic plastics deformable film (i.e.
the film 3)is inserted between the mould portions 1,2 such as to overlie the lower mould portion. The mould portions 1 and 2 are then brought together such that the film 3 is sandwiched between edge regions o the portions. Then,plastics foam mixture is injected into the mould into a space between the upper mould portion 1 and the film 3, such as to be distributed over the film. ~fter the predetermined starting time the mixture begins to foam and is thereby distributed throughout the mould. The heat of reaction of the ~237;~
g foaming material and also the heat from the mould portions l, 2 causes softening of the film 3. After distribution, i.e. when the mould is full of foam, an overpressure is crea-ted. This overpressure presses the film 3 onto the mould surface of the lower mould member 2. Components produced soley in this way do not have sharply defined edges, in particular in the case of deep recesses, In order to prevent or solve this, a vacuum is provided between the lower mould portion 2 and the film 3 whilst the foam pressure is rising in the mould. This partial vacuum helps to bring the film into contact with the mould in all areas and corners. The vacuum therefore aids the foam pressure during simultaneous uniform foaming in causing intimate contact of the film 3 with the lower mould portion surface. As the film lies flat, in the first instance, in the mould and assumes the mould contour:;
'~ as a result of the foam pressure, the formation of air bubbles on the surface is completely avoided. In addition, the film also acts as a separation layer (between the foam and the lower mould portion). Further, the film 3 can provide a final surface ornamentation, for example in the form of different colours, or as a printed wood grain imitation, for different types of decor.
~23726~
~- 10 -A two component system as aforesaid for the production of polyurethane hard foam is used as the foaming mixture and the resulting moulded body has a unit weigh-t of less than 200 kg/m3.
Long decorative profiled sections such as cornices, and also rosettes and dadoes may be produced in the manner described above.
of a cornice, made from plastics foam 4, typically a hard polyurethane foam as aforesaid, and a heat de-formable plastics film 3, typically of P.V.C. as afore-said. Recesses 8 and projections 9 are disposed '~ along the length of the body as shown schematically in Fig.2. The recess 8 and the projection 9 show~ in Fig.l do not lie in the same cross-sectional plane, but behind one another. The recesses 8 and the pro-jections 9 may be formed as shown in outline in Fig.2 and may be ornaments, Figure 2 is a diagrammatic perspective view of the recesses 8 and the projections 9, wherein it can be seen that these recesses and projections may have the form of ornaments.
~23~:6~
Figure 3 is a cross-section through the mould device, which comprises an upper mould portion l and a lower mould portion 2 which are each provided with the heating ducts 5. The mould portion 2 is provided with a surface pattern which de~ines the recesses 8 and projections 9,together with the rest of the ornamental pattern for the cornice. The lower mould portion 2 also in use defines a vacuum chamber 6 and has vacuum nozzles 7, which are connected to a vacuum source(not shown).
To make the moulded body, the two mould portions 1,2 which are preferably of cast aluminium or a different metal or alloy are initially seperated from one another They are brought to the required temperature, typically 55 65C by passing a heated fluid through the ducts 5.
A thin, highly elastic plastics deformable film (i.e.
the film 3)is inserted between the mould portions 1,2 such as to overlie the lower mould portion. The mould portions 1 and 2 are then brought together such that the film 3 is sandwiched between edge regions o the portions. Then,plastics foam mixture is injected into the mould into a space between the upper mould portion 1 and the film 3, such as to be distributed over the film. ~fter the predetermined starting time the mixture begins to foam and is thereby distributed throughout the mould. The heat of reaction of the ~237;~
g foaming material and also the heat from the mould portions l, 2 causes softening of the film 3. After distribution, i.e. when the mould is full of foam, an overpressure is crea-ted. This overpressure presses the film 3 onto the mould surface of the lower mould member 2. Components produced soley in this way do not have sharply defined edges, in particular in the case of deep recesses, In order to prevent or solve this, a vacuum is provided between the lower mould portion 2 and the film 3 whilst the foam pressure is rising in the mould. This partial vacuum helps to bring the film into contact with the mould in all areas and corners. The vacuum therefore aids the foam pressure during simultaneous uniform foaming in causing intimate contact of the film 3 with the lower mould portion surface. As the film lies flat, in the first instance, in the mould and assumes the mould contour:;
'~ as a result of the foam pressure, the formation of air bubbles on the surface is completely avoided. In addition, the film also acts as a separation layer (between the foam and the lower mould portion). Further, the film 3 can provide a final surface ornamentation, for example in the form of different colours, or as a printed wood grain imitation, for different types of decor.
~23726~
~- 10 -A two component system as aforesaid for the production of polyurethane hard foam is used as the foaming mixture and the resulting moulded body has a unit weigh-t of less than 200 kg/m3.
Long decorative profiled sections such as cornices, and also rosettes and dadoes may be produced in the manner described above.
Claims (8)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A method for making molded article of foam plastic material with a complicated sharp textured surface profile structure, which is smooth, non-porous and free from mold release agent, comprising the following steps:
(a) a thin, elastic, heat-deformable film is inserted between two heated mold portions so that the film edges are clamped between the superimposed mold edges of the two mold portions and the film lies flat between both mold portions.
(b) a reactive, heat emitting, foaming plastic mixture is introduced through the upper mold portion and distributed on the film, and (c) the hollow chamber formed between the film and the lower mold portion is evacuated during foaming, so that the film which is heated both by the heated mold portions by heat radiation and by the heat of reaction given off by the reaction mixture is pressed by the foam pressure together with the vacuum provided so that its contours accurately fit the complicated textured or profiled mold surface of the lower mold portion.
(a) a thin, elastic, heat-deformable film is inserted between two heated mold portions so that the film edges are clamped between the superimposed mold edges of the two mold portions and the film lies flat between both mold portions.
(b) a reactive, heat emitting, foaming plastic mixture is introduced through the upper mold portion and distributed on the film, and (c) the hollow chamber formed between the film and the lower mold portion is evacuated during foaming, so that the film which is heated both by the heated mold portions by heat radiation and by the heat of reaction given off by the reaction mixture is pressed by the foam pressure together with the vacuum provided so that its contours accurately fit the complicated textured or profiled mold surface of the lower mold portion.
2. A method according to claim 1 wherein the moulded body has, by contact with the second mold member a heavily textured or profiled, smooth nonporous surface.
3. A method according to claim 1 wherein the moulded body is of a density of less than 200 kg/m-3.
4. A method according to claim 1 wherein the film is of a thickness of 180-250 um.
5. A method according to claim 1 wherein the film is of soft polyvinyl chloride.
6. A method according to claim 1 wherein the two mould portions are heated to 55° to 65°C.
7. A method according to claim 1 wherein said foaming plastics material comprises a two component mixture producing a hard polyurethene foam.
8. A moulded body produced by the method of claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA000490053A CA1237261A (en) | 1985-09-05 | 1985-09-05 | Method of making a moulded body of foam plastics material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA000490053A CA1237261A (en) | 1985-09-05 | 1985-09-05 | Method of making a moulded body of foam plastics material |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1237261A true CA1237261A (en) | 1988-05-31 |
Family
ID=4131316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000490053A Expired CA1237261A (en) | 1985-09-05 | 1985-09-05 | Method of making a moulded body of foam plastics material |
Country Status (1)
Country | Link |
---|---|
CA (1) | CA1237261A (en) |
-
1985
- 1985-09-05 CA CA000490053A patent/CA1237261A/en not_active Expired
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4661391A (en) | Method of making a moulded body of foam plastics material | |
US4053545A (en) | Process for manufacturing laminated structural foam articles | |
KR20010080892A (en) | Method for manufacturing a multi-layered moulded synthetic part and thus obtained part | |
YU206981A (en) | Method of making hollow articles of a polyolefine in a mould with a polyurethane foam with improved adhering of the polyolefine to the polyurethane foam | |
NZ216594A (en) | Shaped foamed article with a thermoplastic show surface | |
CA2043311A1 (en) | Method of forming an article consisting of a foam core and one or more covering layers | |
CA1237261A (en) | Method of making a moulded body of foam plastics material | |
JP2003094473A (en) | Method for manufacturing press molding having foamed part | |
EP0497335B1 (en) | Method for the production of coated panels | |
JPH0857982A (en) | Production of interior material for car | |
US3422495A (en) | Means for making curved optical and reflective surfaces | |
JPH0152168B2 (en) | ||
JP3025424B2 (en) | Method for producing molded body having double walls | |
US20070048468A1 (en) | Decorative glazing panels and methods of manufacturing the same | |
JPS5759730A (en) | Preparation of molded product having foamed layer on surface thereof | |
FR2405125A1 (en) | Moulded seats esp. for automobiles - from poured foam blanks reinforced and clad with cloth or synthetic leather | |
JPH06293031A (en) | Manufacture of foam molded form for automotive interior-finishing | |
JPH066289B2 (en) | Interior material manufacturing method | |
JPS58141937A (en) | Instrument pad for car and manufacture thereof | |
JP2002192682A (en) | Wall material with pattern and its manufacturing method | |
JPS6240190B2 (en) | ||
JP2879862B2 (en) | Method for imparting an uneven pattern to urethane foam | |
JPH04158013A (en) | Manufacture of continuous fiber reinforced plastic article | |
JPS63302009A (en) | Manufacture of urethane molded product | |
JPS5644632A (en) | Foamed blow molding for skinned full molding and its manufacture |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |