CA1139738A - Catalysts for the polymerization of olefins - Google Patents
Catalysts for the polymerization of olefinsInfo
- Publication number
- CA1139738A CA1139738A CA000350235A CA350235A CA1139738A CA 1139738 A CA1139738 A CA 1139738A CA 000350235 A CA000350235 A CA 000350235A CA 350235 A CA350235 A CA 350235A CA 1139738 A CA1139738 A CA 1139738A
- Authority
- CA
- Canada
- Prior art keywords
- compound
- catalyst component
- solid catalyst
- ether
- component according
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
ABSTRACT OF THE DISCLOSURE
Solid catalyst components produced by reacting an organomagnesium compound with an alkoxy compound of the formula, R1aA1(OR2)bXc wherein R1 and R2 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom and a, b and c are numbers satisfying the equations at the same time, 0 ?a < 3, 0 < b ? 3, 0 ? c < 3, and a + b + c = 3 and/or of the formula, R3dP(OR4)eXr wherein R3 and R4 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and d, e and r are numbers satisfying the equations at the same time, 0 ? d < 3, 0 < e ? 3, 0 ? f < 3, and d + e + f = 3 to produce a solid product, and allowing the solid product to support a titanium compound and/or a vanadium compound, and a method for producing polyolefins which comprises polymerizing olefin in the presence of a catalyst system comprising said solid catalyst component and an organoaluminum compound.
Solid catalyst components produced by reacting an organomagnesium compound with an alkoxy compound of the formula, R1aA1(OR2)bXc wherein R1 and R2 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom and a, b and c are numbers satisfying the equations at the same time, 0 ?a < 3, 0 < b ? 3, 0 ? c < 3, and a + b + c = 3 and/or of the formula, R3dP(OR4)eXr wherein R3 and R4 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and d, e and r are numbers satisfying the equations at the same time, 0 ? d < 3, 0 < e ? 3, 0 ? f < 3, and d + e + f = 3 to produce a solid product, and allowing the solid product to support a titanium compound and/or a vanadium compound, and a method for producing polyolefins which comprises polymerizing olefin in the presence of a catalyst system comprising said solid catalyst component and an organoaluminum compound.
Description
~397~
1 The present invention relates to a homopolymeri-zation or copolymerization of olefin with a catalyst o~ high activity. More particularly, it relates to a method for producing olefin homopolymers or copolymers (hereina~ter re~erred to simply as ole~in polymers) o~
narro~ particle size distribution which are in a good slurry state, using a catalyst of markedly high activity.
As to catalysts for olefin polymerization, it is well known that catalyst systems comprising combi.n~
ing a compound of a transition metal in Groups IVb to VIb of the Periodic Table of the Elements with an organic compound of a metal in Groups I to III of the Periodic Table, the so-called "Ziegler" catalyst, are effective for olefin polymerization. Further, many studies were made on supported catalysts comprising a carrier and the compound of a transition metal supported thereon, and as a result, it was found that inorganic compounds such as oxides, hydroxides, chlorides or carbonates of a metal or silicon, and mixtures or complexes thereof are useful as a carrier. Of these compounds, magnesium compounds are particularly useful ; as a carrier, and for example, magnesium halide is used as a carrier for catalysts of high activity (Japanese Patent Publication Nos. 12105/1964 and 41676/1972).
. ., .
~....................................... .
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1 The activity of these catalysts is relatively high but not always satisfactory, and the catalysts generally have a broad particle size distribution and do not always produce olefin polymers having a narrow particle size distribution. Further, there are many studies on improvements of the catalysts, but the results are not said to be satisfactory.
In producing ole~ln polymers, it is desirable to minimize the content o~ resldual catalysts in the produced polymers. The residual catalysts cause many problems such as reduction in the stability and process-ability of the polymers and consequently require equipments for after-treatments such as removal o~ the residual catalysts. This disadvantage can be improved by increasing catalytic activity expressed in the weight of olefirl polymer produced per unit weight of catalyst ~:
as well as o~ transition metal in the catalyst. And in this case, the above equipments for the removal of residual catalysts become unnecessary (the so-called "non-deashing process" can be applied), which results in that a manufacturing cost for the production of olefin polymers can be reduced. While when the slurry polymerization process is applied to the production of olefin polymers, the bulk density, average particle size and particle size distribution of the produced polymers are important factors having a large influence on productivity. Improvements in these factors decrease the amount of polymer attached to polymerization vessels ~J
~1~3~;~
1 and raise the ef~iciency of use of reactors and the efficiency of ~ransfer, drying and granulation, thereby making it possible to raise the productivity and to reduce the manufacturing cost. Further, the produced powdery olefin polymers can be used as they are without pelletizing. Generally, however, olefin polymers produced wi~h the supported catalyst have disadvantages such as low ~ulk density, small average particle size and broad particle size distribution. Conse~uently, supported catalyst of high activity, high bulk density and narrow particle size distribution which can produce olefin polymers applicable to the non-deashing process, are of markedly high value from the industrial point of view, and the development o~ such catalysts is very important.
The inventors previously found that a catalyst component comprising a solid product produced by reacting a Grignard compound with an aluminum halide and/or a silicone halide and a titanium compound and/or a vanadium compound supported thereon ~ecomes an olefin polymerization catalyst having an outstandingly high activity when combined with an organoaluminum compound (British Patent Mo. 1,554,460).
As a result of further study on the foregoing olefin polymerization catalyst having outstandingly high activity and industrial advantages, it was found that a method for preparing a solid carrier useful to produce a supported catalyst which is very high in :, ~3g~3~
l activity not only per transition metal but also per solid catalyst component, and besides able to provide olefin polymers in good slurry state having a narrow particle siæe distribution which are applicable to the non-deashing process and free from adhesion to reactors.
The inventors thus attained to the present invention.
An obJect of the present invention is ~o provide a solid catalyst component having both high activity and narrow particle size distribution.
Another object of the present invention is to provide a method for polymeri~ing olefin using a catalyst system comprising said solid catalyst component and an organoaluminum compound.
Other ob~ects and advantages of the present invention will become apparent from the following description.
According to the present invention, there are provided a solid catalyst component prepared by a method which comprises reacting an organomagnesium compound with an alkoxy compound of the formula, Rl aA ( OR2 ) bXC
wherein Rl and R2 are each a hydrocarbon group having l to 20 carbon atoms, X is a halogen atom, and a, b and c are numbers satisfying the equations at the same time, , .
' .
1~5L39~73~
1 0 ~a < 3, 0 <b ~ 3, 0 ~ c < 3, and a + b + c = 3 and/or of the formula, R3dP(oR4)exf wherein R3 and R4 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen at~m, and d, e and ~ are numbers satis~ying the equations at the same time, 0 ~d ~ 3, 0 ~e ~ 3, 0 ~ f < 3, and d + e + f = 3 to produce a solid product, and allowing the solid product to support a titanium compound and/or a vana~lium compound, and a method for producing olefin polymers which comprises polymerizing olefin in the presence of a catalyst system comprising said solid catalyst component and an organoaluminum compound.
As the organomagnesium compound used for the synthesis of the solid carrier in the present invention, any type of those obtained by the reaction between a halogen-containing organic compound and metallic magnesium may be used. Particularly, Grignard compounds of the formula, R5MgX (wherein R5 is a hydrocarbon group having 1 to 20 carbon atoms and X is a halogen atom), and dialkylmagnesium compounds of the formula, R62Mg (~herein R6 has the same meaning as R5 above), are preferably used. The groups, R5 and R6, specifically include for example alkyl, aryl, aralkyl and alkenyl ; - 5 -.
-:
:
:;' , . .
1 groups having 1 to 20 carbon atoms (e.g. methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, n-amyl, isoamyl, n-hexyl, n-octyl, 2-ethylhexyl, phenyl, benzyl), and the group, X, means chlorine, bromine and iodine atoms.
Specific examples of Grignard compound include for example ethylmagnesium chloride, ethyl-magnesium bromide, ethylmagnesium iodide, n-propyl-magnesium chloride, n-propylmagnesium bromide, n-butyl-magnesium chloride, n-butylmagnesium bromide, n-amyl-magnesium chloride, phenylmagnesium chloride and phenylmagnesium bromide. The dialkylmagnesium compounds specifically include for example diethylmagnesium, di-n-propylmagnesium, di-n-butylmagnesium, di-n-am~l~
magnesium and diphenylmagnesium. As a solvent ~or the synthesis of these organomagnesium compounds, ether compounds such as diethyl ether, di-n-propyl ether, diisopropyl ether, di-n-butyl ether, diisobutyl ether, di-n-amyl ether, diisoamyl ether, di-n-hexyl ether, di-n-octyl ether, diphenyl ether, dibenzyl ether, phenetole, anisole and tetrahydrofuran are used. In place of the ether compounds, hydrocarbons (e.g. hexane, heptane, octane, cyclohexane, methylcyclohexane, benzene, toluene, xylene), or mixtures of the ether compound and hydrocarbon may be used. It is desirable that the organomagnesium compounds are used as an ether solution or as complexes with an ether ~or the synthesis of the solid carrier. It is particularly preferred to use ~ -~3~73~ , 1 Grignard compounds of the formula, R5MgCl, as an ether solution or as complexes with an ether.
Aluminum alkoxides among the alkoxy compounds are represen~ed by the formula, RlaAl(OR2)bXc, and they give good results as the number of alkoxy groups in-creases. Aluminum trialkoxides o~ the formula, Al(OR2)3, are most desirable. In the above formula, Rl and R2 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a helogen atom, and a, b and c are numbers satisfying the equations at the same time, 0 ~a < 3, 0 <b ~ 3, 0 5 c <3, a + b + c = 3. Specific examples of aluminum alkoxide include for example 3 3' (C2H5)3' Al(~n~C3H7)3, Al(O-iso-C3H7)3 A1(0-n-C4Hg)3, Al(0-sec-C4Hg)3, Al(0-tert-CLIH9)3, Al(O-iso-CL~H9)3~ Al(C6Hs)3~ C2H5A1(OC2H5)2~
C2H5Al(-iso-C3H7)2' (C2H5)2Al(O-iso-C3H7)' iso-3 7 4 9)2' (iso-C3H7)2Al(OC2H5), Al(OC2H5)2Cl, Al(0-iso-C3~7)C12, C2H5Al(OC6H5)Cl and iso-C4H~Al(OCH3)Cl.
These compounds are prepared by the well-known methods, and for example, they are obtained particularly easily by the reaction between an orGanoaluminum compound and an alcohol.
Phosphorus alkoxides among the alkoxy compounds are represented by the formula, R3dP(oR )eX
wherein R3 and R4 are each a hydrocarbon group having 1 to 2~ carbon atoms, X is a halogen atom, and d, e and f are numbers satisfying the following equations at the same time, O < d ~ 3, 0< e ~ 3, 0~ f< 3 and ~, , .
~ 3~
l d + e + f = 3. They give good results as the number of alkoxy groups increases.
The phosphorus alkoxides specifically include for example P(OCH3)3, P(OC2H5)3, P(0-iso-C3H7)3, P(O-n-C4Hg)3, P(OCX2CH=C~12)3, P(OC6H5)3, P(OCH2CH2Cl)3, p(ocH3)2cl~ P(0C2H5)2Cl, P(o-n-c4Hg)cl2~ P( 6 5 2 3 3)2' 2H5P(OC2H5)2, n-C4HgP(0C6H5)2' (C H ) -PtOC~3), (n-CL~Hg)2P(OC6H5), C~3P(OC2H5) C2H5P(OC6H5)Cl. Of these compounds, trialkyl phosphites of the formula, P(oR4)3, are most desirable.
The titanium compound and/or vanadium compound supported on carrier include for example titanium compounds of the formula, Ti(oR7)mX4 m (in which R7 is a hydrocarbon group having l to 20 carbon atom~, X is a halogen atom, and m is a number satis~ying the equation, 0 ~ m 5 4), vanadium tetrachloride and vanadium oxytrichloride. As specific examples o~ the titanium compounds, there may be given for example titanium tetrachloride, titanium tetrabromide, titanium tetra-iodide, titanium tetraethoxide, titanium tetra-n-propoxide, titanium tetra-isopropoxide, titanium tetra-n-butoxide, tetrakis(2-ethylhexyl) titanate, tetrastearyl titanate, ethoxytitanium trichloride, diethoxytitanium dichloride, triethoxytitanium chloride, isopropoxytitanium trichloride, diisopropoxytitanium dichloride, tri-isopropoxytitanium chloride, n-butoxy-titanium trichloride, di-n-butoxytitanium dichloride, tri-n-butoxytitanium chloride, ethoxytitanium tribromide, ,~
.
~L~3~73~
l diethoxytitanium dibromide, triethoxytitanium bromide, n-propoxytitanium tribromide, di-n-butoxytitanium dibromide and tri-n-butoxytitanium bromide. Of these compounds, titanium tetrachloride is particularly preferred. These compounds may be used alone or in combination.
The preparation of the solid catalyst component o~ the present invention is always carried out in the atmosphere of inert gas such as nitrogen or argon.
Reaction between the organomagnesium compound and the alkoxy compound is desirably carried out at -30C to 150C, preferably -10C to 100C in a solvent. In carrying out this reaction, the alkoxy compound is added, as it is or in solution or dilution in a suitable solvent, to a solution of the organomagnesium compound, or the way o~ addi~ion is reversed. The reaction time is not particularly limited, so far as it is enough long to complete the reaction, but generally it is lO
minutes or more, preferably 30 minutes to 5 hours. The molar ratio of organomagnesium compound to alkoxy compound is l:lO to lO:l, preferably 1:3 to 3:1. The solvent used for this reaction includes for example aliphatic hydrocarbons (e.g. pentane, hexane, heptane, octane), aromatic hydrocarbons (e.g. benzene, toluene, xylene), alicyclic hydrocarbons (e.g. cyclohexane, cyclopentane) and ether compounds of the ~ormula, R8-0-R9 (in which R8 and R9 are each a hydrocarbon group having l to 20 carbon atoms, or they may be linked _ 9 _ .~ .
- ~3L3~B
together to form a ring). Speci~ic examples of the ether compound include or example diethyl ether, di~n-propyl ether, diisopropyl ether, di n-butyl ether r di-sec-butyl ether, di-n-amyl ether, diisoamyl ether, di-n~hexyl ether, di-n-octyl ether, diphenyl ether, diben~yl ether, anisole, phene-tole, methyl benzyl ether, and tetrahydrofuran. These sol-vents may be used alone or in combination.
From the reaction products thus obtained, a solid pro-duct is isolated and used as a solid carrier. Specifically, the solid product isolated ~y filtra~ion is used as it is, or after washed ~ith an inert hydrocarbon solvent such as hexane, heptane, octane, benzene, toluene, xylene, cyclo-hexane and the like, or after further dried. A particularly preferred solid carrier is complexes having a coordinated ether compound which are produced by carrying out this reac-tion in the ether compound as solvent or in the presence of the ether compound. The amount of coordinated ether can be adjusted by the reaction conditions, ether compounds and washing and drying conditions, and generally it is adjusted to 0.1 to 100~ by weight, preferably 0.5 to 50~ by weight based on the weight o solid composition excluding the co-ordinated ether.
The solid carrier thus obtained has a particularly good particle size distribution, showing properties outstandingly superior as carrier. Generally, the solid carrier is amor-phous or markedly weakly crystalline, and the X-ray diffrac-tion pattern of the it,~
`` ~1397~
1 carrier hardly shows a peak, or if it does, it shows only a very broad and weak peak at 51 to 52(2~).
The solid carrier thus synthesized is allowed to support a titanium compound and/or a vanadium compound by the well~known methods such as impregnation or kneading. For example~ the titanium compound and/or vanadium compound are brought into contact with the foregoing carrier without solvent or in a suitable inert solvent. This reaction is preferably carried out at room temperature to 150C. The reaction product 1s filtered, washed with an inert hydrocarbon solvent described above and used as it is or after drying.
As to the amount of titanium compound and/or vanadium compound supported, it is particularly desirable to adjust the content of titanium atom and/or vanadium atom so as to be within a range of generally 0.01 to 30%
by weight, preferably 0.1 to 15~ by weight based on the resulting solid catalyst component. The solid catalyst component thus obtained has a good particle form and a narrow particle size distribution like the carrier, exhibiting markedly superior properties as catalysts.
As the organoaluminum compound which forms the catalyst system for polymerization together with the foregoing solid catalyst component~ compounds represented by the formula, R103 (p+q)Al(ORll)pYq (wherein R10 and Rll are each a hydrocarbon group . having 1 to 20 carbon atoms, Y is a hydrogen or halogen i ~
. .
` ' ' ~13~38 1 atom, and p and q are numbers satisfying the equations at the same time, 0_ p < 3, 0 ~ q < 3 and 0 ~p-~q < 3), are used. As specific examples of the compound, there may be given for example trialkylaluminum (e.g. tri-ethylaluminum, tri~n-propylaluminum, tri-isobutylaluminum, tri-n-hexylaluminum), dialkylaluminum monohalides (e.g.
diethylaluminum monochloride, di-n-propylaluminum monochloride, diisobutylaluminum monochloride, di-n-hexylaluminum monochloride), alkylaluminum dihalides (e.g. ethylaluminum dichloride~ n-propylaluminum dichloride, isobutylaluminum dichloride, n-hexylaluminum dichloride), alkylaluminum sesquihalides (e.g. ethyl~
aluminum sesquichloride, n-propylaluminum sesquichlor:Lde, isobutylalum:lnum sesquichloride, n-hexylalum:lnum sesquichloride~, alkylaluminum hydrides (e.g. diethyl-a~uminum hydride, diisobutylaluminum hydride), and alkylaluminum alkoxides (e.g~ diethylaluminum methoxide, diethylaluminum ethoxide, diisobutylaluminum ethoxide, diethylaluminum propoxide, diisobutylaluminum butoxide, diethylaluminum phenoxide, ethylaluminum diethoxide, isobutylaluminum dibutoxide~.
These organoaluminum compounds may be used alone or in combination.
The molar ratio of titanium and/or vanadium ~25 atoms in the solid catalyst component to organoaluminum compound can be selected ~rom a range as wide as 10:1 to 1:500, but a range from 2:1 to 1:200 is particularly pre~erred.
1 The molecular weight distribution of olefin polymers can easily be controlled by varying the type of organoaluminum compound.
Olefin used in the present invention includes for example those having 2 to 15 carbon atoms such as ethylene, propylene, butene-l, butadiene, 4-methyl-pentene-l, pentene-l, hexene-l, vinylcyclohexene, styrene and divinylbenzene.
~urther, the stereoregularity of the polymers of ~-olefin (e g. propylene, butene-l) can be improved by adding an electron-donor as a third component of the catalyst system on polymerization. The electron-donor includes for e~ample oxygen-containing organic compounds (e.g. alcohols, ethers, ketones, esters), nitrogen-containing organic compounds (e.g. amines, amides) and phosphorus-containing organic compounds (e.g. phosphines, phosphates). Specifically, there may be given for example ethyl alcohol, n-butyl alcohol, isoamyl alcohol, diethyl ether, di-n-butyl ether, diisoamyl ether, diphenyl ether, tetrahydrofuran, dioxane, acetone, acetophenone, benzophenone, acetyl-acetone, ethyl acetate, ethyl benzoate, ethyl p-anisate, pyridine, triethylamine, triphenyl phosphine, triphenyl phosphite, triphenyl phosphine oxide and hexamethyl
1 The present invention relates to a homopolymeri-zation or copolymerization of olefin with a catalyst o~ high activity. More particularly, it relates to a method for producing olefin homopolymers or copolymers (hereina~ter re~erred to simply as ole~in polymers) o~
narro~ particle size distribution which are in a good slurry state, using a catalyst of markedly high activity.
As to catalysts for olefin polymerization, it is well known that catalyst systems comprising combi.n~
ing a compound of a transition metal in Groups IVb to VIb of the Periodic Table of the Elements with an organic compound of a metal in Groups I to III of the Periodic Table, the so-called "Ziegler" catalyst, are effective for olefin polymerization. Further, many studies were made on supported catalysts comprising a carrier and the compound of a transition metal supported thereon, and as a result, it was found that inorganic compounds such as oxides, hydroxides, chlorides or carbonates of a metal or silicon, and mixtures or complexes thereof are useful as a carrier. Of these compounds, magnesium compounds are particularly useful ; as a carrier, and for example, magnesium halide is used as a carrier for catalysts of high activity (Japanese Patent Publication Nos. 12105/1964 and 41676/1972).
. ., .
~....................................... .
~. , ' .
ii3g73~ ~
1 The activity of these catalysts is relatively high but not always satisfactory, and the catalysts generally have a broad particle size distribution and do not always produce olefin polymers having a narrow particle size distribution. Further, there are many studies on improvements of the catalysts, but the results are not said to be satisfactory.
In producing ole~ln polymers, it is desirable to minimize the content o~ resldual catalysts in the produced polymers. The residual catalysts cause many problems such as reduction in the stability and process-ability of the polymers and consequently require equipments for after-treatments such as removal o~ the residual catalysts. This disadvantage can be improved by increasing catalytic activity expressed in the weight of olefirl polymer produced per unit weight of catalyst ~:
as well as o~ transition metal in the catalyst. And in this case, the above equipments for the removal of residual catalysts become unnecessary (the so-called "non-deashing process" can be applied), which results in that a manufacturing cost for the production of olefin polymers can be reduced. While when the slurry polymerization process is applied to the production of olefin polymers, the bulk density, average particle size and particle size distribution of the produced polymers are important factors having a large influence on productivity. Improvements in these factors decrease the amount of polymer attached to polymerization vessels ~J
~1~3~;~
1 and raise the ef~iciency of use of reactors and the efficiency of ~ransfer, drying and granulation, thereby making it possible to raise the productivity and to reduce the manufacturing cost. Further, the produced powdery olefin polymers can be used as they are without pelletizing. Generally, however, olefin polymers produced wi~h the supported catalyst have disadvantages such as low ~ulk density, small average particle size and broad particle size distribution. Conse~uently, supported catalyst of high activity, high bulk density and narrow particle size distribution which can produce olefin polymers applicable to the non-deashing process, are of markedly high value from the industrial point of view, and the development o~ such catalysts is very important.
The inventors previously found that a catalyst component comprising a solid product produced by reacting a Grignard compound with an aluminum halide and/or a silicone halide and a titanium compound and/or a vanadium compound supported thereon ~ecomes an olefin polymerization catalyst having an outstandingly high activity when combined with an organoaluminum compound (British Patent Mo. 1,554,460).
As a result of further study on the foregoing olefin polymerization catalyst having outstandingly high activity and industrial advantages, it was found that a method for preparing a solid carrier useful to produce a supported catalyst which is very high in :, ~3g~3~
l activity not only per transition metal but also per solid catalyst component, and besides able to provide olefin polymers in good slurry state having a narrow particle siæe distribution which are applicable to the non-deashing process and free from adhesion to reactors.
The inventors thus attained to the present invention.
An obJect of the present invention is ~o provide a solid catalyst component having both high activity and narrow particle size distribution.
Another object of the present invention is to provide a method for polymeri~ing olefin using a catalyst system comprising said solid catalyst component and an organoaluminum compound.
Other ob~ects and advantages of the present invention will become apparent from the following description.
According to the present invention, there are provided a solid catalyst component prepared by a method which comprises reacting an organomagnesium compound with an alkoxy compound of the formula, Rl aA ( OR2 ) bXC
wherein Rl and R2 are each a hydrocarbon group having l to 20 carbon atoms, X is a halogen atom, and a, b and c are numbers satisfying the equations at the same time, , .
' .
1~5L39~73~
1 0 ~a < 3, 0 <b ~ 3, 0 ~ c < 3, and a + b + c = 3 and/or of the formula, R3dP(oR4)exf wherein R3 and R4 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen at~m, and d, e and ~ are numbers satis~ying the equations at the same time, 0 ~d ~ 3, 0 ~e ~ 3, 0 ~ f < 3, and d + e + f = 3 to produce a solid product, and allowing the solid product to support a titanium compound and/or a vana~lium compound, and a method for producing olefin polymers which comprises polymerizing olefin in the presence of a catalyst system comprising said solid catalyst component and an organoaluminum compound.
As the organomagnesium compound used for the synthesis of the solid carrier in the present invention, any type of those obtained by the reaction between a halogen-containing organic compound and metallic magnesium may be used. Particularly, Grignard compounds of the formula, R5MgX (wherein R5 is a hydrocarbon group having 1 to 20 carbon atoms and X is a halogen atom), and dialkylmagnesium compounds of the formula, R62Mg (~herein R6 has the same meaning as R5 above), are preferably used. The groups, R5 and R6, specifically include for example alkyl, aryl, aralkyl and alkenyl ; - 5 -.
-:
:
:;' , . .
1 groups having 1 to 20 carbon atoms (e.g. methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, n-amyl, isoamyl, n-hexyl, n-octyl, 2-ethylhexyl, phenyl, benzyl), and the group, X, means chlorine, bromine and iodine atoms.
Specific examples of Grignard compound include for example ethylmagnesium chloride, ethyl-magnesium bromide, ethylmagnesium iodide, n-propyl-magnesium chloride, n-propylmagnesium bromide, n-butyl-magnesium chloride, n-butylmagnesium bromide, n-amyl-magnesium chloride, phenylmagnesium chloride and phenylmagnesium bromide. The dialkylmagnesium compounds specifically include for example diethylmagnesium, di-n-propylmagnesium, di-n-butylmagnesium, di-n-am~l~
magnesium and diphenylmagnesium. As a solvent ~or the synthesis of these organomagnesium compounds, ether compounds such as diethyl ether, di-n-propyl ether, diisopropyl ether, di-n-butyl ether, diisobutyl ether, di-n-amyl ether, diisoamyl ether, di-n-hexyl ether, di-n-octyl ether, diphenyl ether, dibenzyl ether, phenetole, anisole and tetrahydrofuran are used. In place of the ether compounds, hydrocarbons (e.g. hexane, heptane, octane, cyclohexane, methylcyclohexane, benzene, toluene, xylene), or mixtures of the ether compound and hydrocarbon may be used. It is desirable that the organomagnesium compounds are used as an ether solution or as complexes with an ether ~or the synthesis of the solid carrier. It is particularly preferred to use ~ -~3~73~ , 1 Grignard compounds of the formula, R5MgCl, as an ether solution or as complexes with an ether.
Aluminum alkoxides among the alkoxy compounds are represen~ed by the formula, RlaAl(OR2)bXc, and they give good results as the number of alkoxy groups in-creases. Aluminum trialkoxides o~ the formula, Al(OR2)3, are most desirable. In the above formula, Rl and R2 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a helogen atom, and a, b and c are numbers satisfying the equations at the same time, 0 ~a < 3, 0 <b ~ 3, 0 5 c <3, a + b + c = 3. Specific examples of aluminum alkoxide include for example 3 3' (C2H5)3' Al(~n~C3H7)3, Al(O-iso-C3H7)3 A1(0-n-C4Hg)3, Al(0-sec-C4Hg)3, Al(0-tert-CLIH9)3, Al(O-iso-CL~H9)3~ Al(C6Hs)3~ C2H5A1(OC2H5)2~
C2H5Al(-iso-C3H7)2' (C2H5)2Al(O-iso-C3H7)' iso-3 7 4 9)2' (iso-C3H7)2Al(OC2H5), Al(OC2H5)2Cl, Al(0-iso-C3~7)C12, C2H5Al(OC6H5)Cl and iso-C4H~Al(OCH3)Cl.
These compounds are prepared by the well-known methods, and for example, they are obtained particularly easily by the reaction between an orGanoaluminum compound and an alcohol.
Phosphorus alkoxides among the alkoxy compounds are represented by the formula, R3dP(oR )eX
wherein R3 and R4 are each a hydrocarbon group having 1 to 2~ carbon atoms, X is a halogen atom, and d, e and f are numbers satisfying the following equations at the same time, O < d ~ 3, 0< e ~ 3, 0~ f< 3 and ~, , .
~ 3~
l d + e + f = 3. They give good results as the number of alkoxy groups increases.
The phosphorus alkoxides specifically include for example P(OCH3)3, P(OC2H5)3, P(0-iso-C3H7)3, P(O-n-C4Hg)3, P(OCX2CH=C~12)3, P(OC6H5)3, P(OCH2CH2Cl)3, p(ocH3)2cl~ P(0C2H5)2Cl, P(o-n-c4Hg)cl2~ P( 6 5 2 3 3)2' 2H5P(OC2H5)2, n-C4HgP(0C6H5)2' (C H ) -PtOC~3), (n-CL~Hg)2P(OC6H5), C~3P(OC2H5) C2H5P(OC6H5)Cl. Of these compounds, trialkyl phosphites of the formula, P(oR4)3, are most desirable.
The titanium compound and/or vanadium compound supported on carrier include for example titanium compounds of the formula, Ti(oR7)mX4 m (in which R7 is a hydrocarbon group having l to 20 carbon atom~, X is a halogen atom, and m is a number satis~ying the equation, 0 ~ m 5 4), vanadium tetrachloride and vanadium oxytrichloride. As specific examples o~ the titanium compounds, there may be given for example titanium tetrachloride, titanium tetrabromide, titanium tetra-iodide, titanium tetraethoxide, titanium tetra-n-propoxide, titanium tetra-isopropoxide, titanium tetra-n-butoxide, tetrakis(2-ethylhexyl) titanate, tetrastearyl titanate, ethoxytitanium trichloride, diethoxytitanium dichloride, triethoxytitanium chloride, isopropoxytitanium trichloride, diisopropoxytitanium dichloride, tri-isopropoxytitanium chloride, n-butoxy-titanium trichloride, di-n-butoxytitanium dichloride, tri-n-butoxytitanium chloride, ethoxytitanium tribromide, ,~
.
~L~3~73~
l diethoxytitanium dibromide, triethoxytitanium bromide, n-propoxytitanium tribromide, di-n-butoxytitanium dibromide and tri-n-butoxytitanium bromide. Of these compounds, titanium tetrachloride is particularly preferred. These compounds may be used alone or in combination.
The preparation of the solid catalyst component o~ the present invention is always carried out in the atmosphere of inert gas such as nitrogen or argon.
Reaction between the organomagnesium compound and the alkoxy compound is desirably carried out at -30C to 150C, preferably -10C to 100C in a solvent. In carrying out this reaction, the alkoxy compound is added, as it is or in solution or dilution in a suitable solvent, to a solution of the organomagnesium compound, or the way o~ addi~ion is reversed. The reaction time is not particularly limited, so far as it is enough long to complete the reaction, but generally it is lO
minutes or more, preferably 30 minutes to 5 hours. The molar ratio of organomagnesium compound to alkoxy compound is l:lO to lO:l, preferably 1:3 to 3:1. The solvent used for this reaction includes for example aliphatic hydrocarbons (e.g. pentane, hexane, heptane, octane), aromatic hydrocarbons (e.g. benzene, toluene, xylene), alicyclic hydrocarbons (e.g. cyclohexane, cyclopentane) and ether compounds of the ~ormula, R8-0-R9 (in which R8 and R9 are each a hydrocarbon group having l to 20 carbon atoms, or they may be linked _ 9 _ .~ .
- ~3L3~B
together to form a ring). Speci~ic examples of the ether compound include or example diethyl ether, di~n-propyl ether, diisopropyl ether, di n-butyl ether r di-sec-butyl ether, di-n-amyl ether, diisoamyl ether, di-n~hexyl ether, di-n-octyl ether, diphenyl ether, diben~yl ether, anisole, phene-tole, methyl benzyl ether, and tetrahydrofuran. These sol-vents may be used alone or in combination.
From the reaction products thus obtained, a solid pro-duct is isolated and used as a solid carrier. Specifically, the solid product isolated ~y filtra~ion is used as it is, or after washed ~ith an inert hydrocarbon solvent such as hexane, heptane, octane, benzene, toluene, xylene, cyclo-hexane and the like, or after further dried. A particularly preferred solid carrier is complexes having a coordinated ether compound which are produced by carrying out this reac-tion in the ether compound as solvent or in the presence of the ether compound. The amount of coordinated ether can be adjusted by the reaction conditions, ether compounds and washing and drying conditions, and generally it is adjusted to 0.1 to 100~ by weight, preferably 0.5 to 50~ by weight based on the weight o solid composition excluding the co-ordinated ether.
The solid carrier thus obtained has a particularly good particle size distribution, showing properties outstandingly superior as carrier. Generally, the solid carrier is amor-phous or markedly weakly crystalline, and the X-ray diffrac-tion pattern of the it,~
`` ~1397~
1 carrier hardly shows a peak, or if it does, it shows only a very broad and weak peak at 51 to 52(2~).
The solid carrier thus synthesized is allowed to support a titanium compound and/or a vanadium compound by the well~known methods such as impregnation or kneading. For example~ the titanium compound and/or vanadium compound are brought into contact with the foregoing carrier without solvent or in a suitable inert solvent. This reaction is preferably carried out at room temperature to 150C. The reaction product 1s filtered, washed with an inert hydrocarbon solvent described above and used as it is or after drying.
As to the amount of titanium compound and/or vanadium compound supported, it is particularly desirable to adjust the content of titanium atom and/or vanadium atom so as to be within a range of generally 0.01 to 30%
by weight, preferably 0.1 to 15~ by weight based on the resulting solid catalyst component. The solid catalyst component thus obtained has a good particle form and a narrow particle size distribution like the carrier, exhibiting markedly superior properties as catalysts.
As the organoaluminum compound which forms the catalyst system for polymerization together with the foregoing solid catalyst component~ compounds represented by the formula, R103 (p+q)Al(ORll)pYq (wherein R10 and Rll are each a hydrocarbon group . having 1 to 20 carbon atoms, Y is a hydrogen or halogen i ~
. .
` ' ' ~13~38 1 atom, and p and q are numbers satisfying the equations at the same time, 0_ p < 3, 0 ~ q < 3 and 0 ~p-~q < 3), are used. As specific examples of the compound, there may be given for example trialkylaluminum (e.g. tri-ethylaluminum, tri~n-propylaluminum, tri-isobutylaluminum, tri-n-hexylaluminum), dialkylaluminum monohalides (e.g.
diethylaluminum monochloride, di-n-propylaluminum monochloride, diisobutylaluminum monochloride, di-n-hexylaluminum monochloride), alkylaluminum dihalides (e.g. ethylaluminum dichloride~ n-propylaluminum dichloride, isobutylaluminum dichloride, n-hexylaluminum dichloride), alkylaluminum sesquihalides (e.g. ethyl~
aluminum sesquichloride, n-propylaluminum sesquichlor:Lde, isobutylalum:lnum sesquichloride, n-hexylalum:lnum sesquichloride~, alkylaluminum hydrides (e.g. diethyl-a~uminum hydride, diisobutylaluminum hydride), and alkylaluminum alkoxides (e.g~ diethylaluminum methoxide, diethylaluminum ethoxide, diisobutylaluminum ethoxide, diethylaluminum propoxide, diisobutylaluminum butoxide, diethylaluminum phenoxide, ethylaluminum diethoxide, isobutylaluminum dibutoxide~.
These organoaluminum compounds may be used alone or in combination.
The molar ratio of titanium and/or vanadium ~25 atoms in the solid catalyst component to organoaluminum compound can be selected ~rom a range as wide as 10:1 to 1:500, but a range from 2:1 to 1:200 is particularly pre~erred.
1 The molecular weight distribution of olefin polymers can easily be controlled by varying the type of organoaluminum compound.
Olefin used in the present invention includes for example those having 2 to 15 carbon atoms such as ethylene, propylene, butene-l, butadiene, 4-methyl-pentene-l, pentene-l, hexene-l, vinylcyclohexene, styrene and divinylbenzene.
~urther, the stereoregularity of the polymers of ~-olefin (e g. propylene, butene-l) can be improved by adding an electron-donor as a third component of the catalyst system on polymerization. The electron-donor includes for e~ample oxygen-containing organic compounds (e.g. alcohols, ethers, ketones, esters), nitrogen-containing organic compounds (e.g. amines, amides) and phosphorus-containing organic compounds (e.g. phosphines, phosphates). Specifically, there may be given for example ethyl alcohol, n-butyl alcohol, isoamyl alcohol, diethyl ether, di-n-butyl ether, diisoamyl ether, diphenyl ether, tetrahydrofuran, dioxane, acetone, acetophenone, benzophenone, acetyl-acetone, ethyl acetate, ethyl benzoate, ethyl p-anisate, pyridine, triethylamine, triphenyl phosphine, triphenyl phosphite, triphenyl phosphine oxide and hexamethyl
2~ phosphoric triamide (H~PA).
The present invention is useful in the produc~
tion of homopolymers and copolymers of the foregoing olefins, but its effect is particularly remarkable "
.. . . . .
. - .
;
" :
73~
1 in the production of ethylene homopolymers and copolymers of ethylene and other olefins (e.g. chiefly propylene, butene-1, 4-methylpentene-1, pentene-l, hexene-1, butadiene).
The polymerization procedure of the present invention is generally carried out by the conventional processes such as slurry polymerization process, gas-phase polymerization process and solution polymerizaticn process. It is desirable to carry out the polymerization as follows: The solid catalyst component and organo-alumi~t~-~m compound are mixed in an inert hydrocarbon solvent, and the olefin is continuously supplied to the mixture at a reaction temperature between room ternpe-rature and 200C and at a react:lon pressure between atmospheric pressure and about 100 atm. The reaction temperature and reactlon pressure are not limited to the foregoing ranges, and they may be further raised.
Also, for example hydrogen may be added as a molecular weight regulating agent. The polymerization may be carried out in either of a continuous form or batchwise form.
The inert hydrocarbon solvent used for poly-merization includes for example aliphatic hydrocarbons (e.g. propane, butane, pentane, hexane, heptane, octane), alicyclic hydrocarbons Ce.g. cyclohexane, cycloheptane) and aromatic hydrocarbons (e.g. benzene, toluene, xylene).
These solvents may be used alone or in combination.
Also, the spent BB fraction may be used as a polymerization ~i ~3~
1 solvent.
The present invention will be illustrated in more detail with reference to the following examples, and it is to be understood that the present invention is not limited to these examples within the spirit and scope of the invention.
The properties of the produced polymers were measured by the following methods:
Melt index (MI): Measured at 190C using a weight o~ 2.16 kg according to ASTM D 1238 and expressed in g/10 min.
DenSitD : Measured according to JIS K 6760.
Bulk density : Measured according to JIS K 6721.
Example 1 (1) Synthesis of organomagnesium compound (Grignard compound) To a l-liter ~our-necked flask equlpped with a stirrer, a re~lux condenser and a dropping ~unnel was added magnesium chip (32.0 g) for Grignard reaction, and air and moisture in the ~lask were completely removed by replacement with nitrogen. n-Butyl chloride (120 g) and diethyl ether (500 ml) were placed in the dropping ~unnel, and the mixture (a~out 30 ml~ was dropped to magnesium to allow reaction to start (when the reaction did not begin, it was started by heating the flask a little~ After the beginning of the reaction, dropping was continued so as to allow the reaction to proceed ~:, - : . . ~ ;
1 smoothly. After dropping was finished, the reaction was continued under reflux for further a~out 1 hour.
Thereafter, the reaction solution was cooled to room temperature, and unreacted magnesium was filtered o~f using a glass filter.
The content o~ Grignard compound in diethyl ether was determined by hydrolyzing the compound ~ith 1~ sulfuric acid, ~ollowed by back titration with lN
sodium hydroxide (indicator~ phenolphthalein). It was found that the content was 2 00 mole/liter.
(2) Synthesis of solid catalyst component Air and moisture in a 100-ml four-necked flask equipped with a stirrer, a dropping funnel arld a thermometer were thoroughly removed by replacement with nitrogen.
Aluminum triisopropoxide ~Al(0-iso-C3H7)3, 10.2 g] was dissolved in diethyl ether (30 ml) in the flask, and to this solution was gradually added dropwise the diethyl ether solution (25 ml) containing 50.0 mmole of n-butylmagnesium chloride synthesized in (1) from the dropping funnel with ice-cooling. White precipitate was formed. Reaction was carried out for 1 hour with ice-cooling and then at the boiling point of diethyl ether for further 1 hour. After reaction, ethyl ether was removed by filtration, and the precipitate was washed with purified n-heptane (50 ml) and filtered.
This washing/~iltration cycle was repeated five times, and then the precipitate was dried at room temperature . .
' ~ .
.
~3~
1 under reduced pressure to obtain 5.2 g of a white solid.
It was found by analysis that the contents of Mg, Al, Cl and (C2H5)20 in the white solid were 20.5%, 1.3%, 28.8% and 8.7% by weight, respectively. This white solid (3.0 g) was dipped in titanium tetrachloride (30 ml) in a 100-ml four-necked flask, and reaction was carried out at 130C for 1 hour. After the reaction was finished, the solid product was repea~edly washed with n-heptane until titanium tetrachloride in the washings was no longer detected. A solid catalyst component was thus obtained. The component was dried and analyzed, and it was found that the amount of titanium supported was 53 mg per 1 g of solid catalyst component.
The synthetic method for the above solid catalyst component is also applicable to the synthesis of other solld catalyst components~
The present invention is useful in the produc~
tion of homopolymers and copolymers of the foregoing olefins, but its effect is particularly remarkable "
.. . . . .
. - .
;
" :
73~
1 in the production of ethylene homopolymers and copolymers of ethylene and other olefins (e.g. chiefly propylene, butene-1, 4-methylpentene-1, pentene-l, hexene-1, butadiene).
The polymerization procedure of the present invention is generally carried out by the conventional processes such as slurry polymerization process, gas-phase polymerization process and solution polymerizaticn process. It is desirable to carry out the polymerization as follows: The solid catalyst component and organo-alumi~t~-~m compound are mixed in an inert hydrocarbon solvent, and the olefin is continuously supplied to the mixture at a reaction temperature between room ternpe-rature and 200C and at a react:lon pressure between atmospheric pressure and about 100 atm. The reaction temperature and reactlon pressure are not limited to the foregoing ranges, and they may be further raised.
Also, for example hydrogen may be added as a molecular weight regulating agent. The polymerization may be carried out in either of a continuous form or batchwise form.
The inert hydrocarbon solvent used for poly-merization includes for example aliphatic hydrocarbons (e.g. propane, butane, pentane, hexane, heptane, octane), alicyclic hydrocarbons Ce.g. cyclohexane, cycloheptane) and aromatic hydrocarbons (e.g. benzene, toluene, xylene).
These solvents may be used alone or in combination.
Also, the spent BB fraction may be used as a polymerization ~i ~3~
1 solvent.
The present invention will be illustrated in more detail with reference to the following examples, and it is to be understood that the present invention is not limited to these examples within the spirit and scope of the invention.
The properties of the produced polymers were measured by the following methods:
Melt index (MI): Measured at 190C using a weight o~ 2.16 kg according to ASTM D 1238 and expressed in g/10 min.
DenSitD : Measured according to JIS K 6760.
Bulk density : Measured according to JIS K 6721.
Example 1 (1) Synthesis of organomagnesium compound (Grignard compound) To a l-liter ~our-necked flask equlpped with a stirrer, a re~lux condenser and a dropping ~unnel was added magnesium chip (32.0 g) for Grignard reaction, and air and moisture in the ~lask were completely removed by replacement with nitrogen. n-Butyl chloride (120 g) and diethyl ether (500 ml) were placed in the dropping ~unnel, and the mixture (a~out 30 ml~ was dropped to magnesium to allow reaction to start (when the reaction did not begin, it was started by heating the flask a little~ After the beginning of the reaction, dropping was continued so as to allow the reaction to proceed ~:, - : . . ~ ;
1 smoothly. After dropping was finished, the reaction was continued under reflux for further a~out 1 hour.
Thereafter, the reaction solution was cooled to room temperature, and unreacted magnesium was filtered o~f using a glass filter.
The content o~ Grignard compound in diethyl ether was determined by hydrolyzing the compound ~ith 1~ sulfuric acid, ~ollowed by back titration with lN
sodium hydroxide (indicator~ phenolphthalein). It was found that the content was 2 00 mole/liter.
(2) Synthesis of solid catalyst component Air and moisture in a 100-ml four-necked flask equipped with a stirrer, a dropping funnel arld a thermometer were thoroughly removed by replacement with nitrogen.
Aluminum triisopropoxide ~Al(0-iso-C3H7)3, 10.2 g] was dissolved in diethyl ether (30 ml) in the flask, and to this solution was gradually added dropwise the diethyl ether solution (25 ml) containing 50.0 mmole of n-butylmagnesium chloride synthesized in (1) from the dropping funnel with ice-cooling. White precipitate was formed. Reaction was carried out for 1 hour with ice-cooling and then at the boiling point of diethyl ether for further 1 hour. After reaction, ethyl ether was removed by filtration, and the precipitate was washed with purified n-heptane (50 ml) and filtered.
This washing/~iltration cycle was repeated five times, and then the precipitate was dried at room temperature . .
' ~ .
.
~3~
1 under reduced pressure to obtain 5.2 g of a white solid.
It was found by analysis that the contents of Mg, Al, Cl and (C2H5)20 in the white solid were 20.5%, 1.3%, 28.8% and 8.7% by weight, respectively. This white solid (3.0 g) was dipped in titanium tetrachloride (30 ml) in a 100-ml four-necked flask, and reaction was carried out at 130C for 1 hour. After the reaction was finished, the solid product was repea~edly washed with n-heptane until titanium tetrachloride in the washings was no longer detected. A solid catalyst component was thus obtained. The component was dried and analyzed, and it was found that the amount of titanium supported was 53 mg per 1 g of solid catalyst component.
The synthetic method for the above solid catalyst component is also applicable to the synthesis of other solld catalyst components~
(3) Polymerization Air in a l-liter stainless steel autoclave equipped with a magnetic stirrer was thoroughly replaced with nitrogen, and the autoclave was heated to gooc.
n-Heptane (500 ml) completely free from moisture and oxygen, triethylaluminum (2.5 mmole) and the foregoing solid catalyst component (4.2 mg) were added to the autoclave with stirring. Thereafter, hydrogen gas was charged to a pressure of 2 kg/cm2 (gauge) and then ethylene was charged to a pressure of 12 kg/cm2 (gauge) to start polymerization. Polymerization was continued at 90C for 1 hour while keeping the total pressure ;
:.
.. ; .
~.~39~ 8 1 of 12 kg/cm by supplying ethylene. After polymerization was finished, the resulting polymer was filtered, washed with n-heptane and dried at 60C under reduced pressure to obtain 72 g of polyethylene. The poly-ethylene had a melt index of 0.26 g/10 min. and a bulkdensity of 0.31 g/cc. In this case, the catalytic acti~ity was 17~ g (polyethylene)/g(solid catalyst componen~-hr, and in another expression, 323,000 g(polyethylene)~g Ti-hr.
Example 2 (1) Synthesis of organomagnesium compound (Grignard compound) To a l-liter four-necked flask equipped with a stlrrer, a reflux condenser and a dropping funnel was added magnesium chip (35.0 g) for Grignard reaction, and air and moisture in the flask were completely removed by replacement with nitrogen. n-Butyl chloride (125 g) and di-n-butyl ether (500 ml) were placed in the dropping funnel~ and the mixture (about 30 ml) was dropped to magnesium to allow reaction to start. After the beginning of the reaction, dropping was continued so as to allow the reaction to proceed smoothly. After dropping was finished, the reaction was continued at 60C to 70C for further about 1 hour. Thereafter, the reaction solution was cooled to room temperature, and unreacted magnesium was filtered off using a glass filter.
;
. . .
.
~139!7~
1 The content of Grignard compound in di-n-butyl ether was determined by hydrolyzing the compound with lN sulfuric acid, followed by back titration with lN
sodium hydroxide (indicator, phenolphthalein). It was found that the content was 2.10 mole/liter.
(2) Synthesis of solid catalyst component Air and moisture in a 100-ml four-necked flask e~uipped with a stirrer, a dropping funnel and a thermometer were thoroughly removed by replacement with nitrogen.
The di-n-butyl ether solution (23.8 ml~
containing 50 mmole of n~butylmagnesium chloride (n-~uMgCl) synthesi~ed in (1) was placed in the flask and stirred. Thereafter, triethyl phosphite (4.2 g~ was gradually added dropwise to the solution from the dropping funnel with ice-cooling. White precipitate was formed. Reaction was carried out for 1 hour with ice-cooling and then at 60C for further 1 hour. After reaction, di-n-butyl ether was removed by filtration, and the precipitate was washed with purified n-heptane (50 ml) and filtered. This washing and filtration cycle was repeated five times~ and then the precipitate was dried at room temperature under reduced pressure to obtain 8.4 g of a white solid. It was found by analysis that the contents of Mg, P, Cl and (n-C4Hg)20 were 20.0%, 0.3%, 25.8% and 16.8% by weight, respectively.
This white solid (3.5 g) was dipped in titanium tetra-chloride (30 ml) in a 100-ml four-necked flask, and , :. . ' ' ~ ' ~ ' ,~
~3g7~8 1 reaction was carried out at 130C for 1 hour. After the reaction was ~inished, the so].id product was repeatedly washed with n-h2ptane until titanium tetra-chloride in the washings was no longer detected. A
solid catalyst component (3.3 g) was thus obtained.
The component was dried and analyzed, and it was found that the amount of titanium supported was 47 mg per 1 g of solid catalyst component.
The synthetic method for the above solid catalyst component is also applicable to the synthesis of other solid catalyst components.
(3) Polymerization Polymerization was carried out in the same manner as in (3) of Example 1 except that 5~1 mg of the solid catalyst component obtained above was used.
As a result, 105 g of polyethylene was obtained. This polyethylene had a melt index of 0.64 g/10 min. and a bulk density of 0.32 g/cc. The catalytic activity was 20,600 g(polyethylene)/g(solid catalyst component)-hr, and in another expression, 438,000 g(polyethylene)/
g Ti-hr.
Example 3 Ethylene was polymerized in the same manner as in Example 1 except that 2.5 mmole of triisobutyl-aluminum was used in place of triethylaluminum, and that3.2 mg o~ the solid catalyst component was used. Thus, 60.0 g of polyethylene was obtained. This polyethylene :, - 20 _ ' : ~, - - ' ' ' ~
1~3g'73~
1 had a melt index of 0.20 g/10 min. and a bulk density of` 0.30 g/cc. The catalytic activity was 18,800 g(polyethylene)~g(solid catalyst component) hr, and in another expression, 354,000 g(polyethylene)/
g Ti-hr.
Example 4 Ethylene was polymerized in the same manner as in Example 2 except that 2.5 ~nole of diisobutyl-aluminum hydride was used in place of triethylaluminum, and that 3.5 mg of the solid catalyst component was used. Thus, 81.0 g of polyethylene was obtalned Thi.s polyethylene had a melt index o~ 0.35 g/10 min~ and a bulk density o~ 0.31 g/cc. The catalytic activity was 23,100 g(polyethylene)/g(solid catalyst component~-hr, and in another expression, 491,000 g(polyethylene)/
g Ti-hr.
Example 5 Ethylene was polymerized in the same manner as in Example 2 except that 2.5 mmole of diethylaluminum chloride was used in place of triethylaluminum, 15.5 mg of the solid catalyst component was used, and that the hydrogen pressure was 10 kg/cm2 and the total pressure was 20 kg/cm . Thus, 74.0 g of polyethylene was obtained.
This polyethylene had a melt index of 0.23 g/10 min.
and a bulk density of 0.34 g/cc. The catalytic acti~ity was 4,770 g(polyethylene)/g(solid catalyst component)-hr, ' ' - :'' , and in another expression, lOl,OQO g (polyethylene)/g Ti~hr.
Exa~ple 6 The synthesis of solid catalyst component was carried out in the same manner as in (2l of Example 2 except that ethylaluminum diisobutoxide IC2H5Al~O-iso-C4Hg)2, 50 mmol~
produced by reaction between triethylaluminum and isobutyl alcohol was used in place of triethyl phosphate, 30 ml of n-heptane was used as solvent. ~hus, 4.2 g of a white solid was obta~ned, This white solid contained 15.8% of di-n-butyl ether ~n-C4Hg)20]. This white solid (3.0 g) was allowed to react with t;~anium tetrachloride in the same manner as in ~2) of Example 1 to obtain a solid catalyst component. It was found that the amount of titanium supported was 5:L mg per 1 g of solid catalyst component.
Eth~lene was polymerized in the same manner as in Example 1 except that 4.0 mg o the solid catalyst component thus obtained was used, and that 2.5 mmole of triisobutylaluminum was used in place of triethylaluminum. ~hus, 93.5 g of polyethylene was obtained.
This polyethylene had a melt index of 0.67 g/10 min. and a bulk density of 0.32 g/cc. The catalytic activity was 23,400 g (polyethylene~/g(solid catalyst component)-hr, and in another expression, 459,000 g(polyethylene~/g Ti-hr.
~ 22 ~Q
' ' ~' 1 Examples 7 to 13 The preparation o~ solid catalyst component ancl polymerization of ethylene were carried out in the same manner as in Example 1 but using various compounds.
Preparation conditions for the solid catalyst co~lponent and the results of ethylene polymerization are shown in Tzble 1.
.
., ~
~ ' .
: .
~39q~
o ~^ C~ , 3~--~_ ~ , ~_ ~ 3--~,_ r~l (Y~ CO CO U~ ~ ~ ~1 ~D ~1 3 O ~ ~, ~ ~) ~ . . . L~ ~ C) ~ ~ . J~
~ ~ o ~æ .,~ ~ = ~ = Lr, = fO 0 ~ ~ O ~D
~0 ~J~ E~ '- `_ `_ `_ C~ E~ - ~ ~_ c~
~ l E~
_ _ O O ~
1~ æ ~ 1~ ~_ c~l 3 ~ l~
S~ ~ 1~ CO ~:) ~) O CO
~ S ~ 3 ~ ~_1 01 (~1~1 C~ O . .
~ ~ ~ I
a~
O ~ ~ ~: ~ ~d 5~ ~ (L) ~) O ~ Q 9 = ::~ Q u~ ~ ~ S~
~ ~d ~ rl ~ O ~ r~ ~ I ~ I
o ~ o ~ a) E~ l ~I Q~ rl ~ rl ~ p:; ~ ._ a ~ ~ a~
o _ . _ C~ C~ ~
r-l ~1 r1 0 J~ O ~ ¦~ 1 1 1 1 1 a) r-l ~ ¢ ~ ~ ~i 0 ~i 0 r-l r1 r-l r1 ~ rlr1 r1 rl rl ~ ~ ~d~
~ c~ _ _ _ r1 ~C) (~ 1~ 3 O .CI ~rl ~ ~ (~ .~_ ~ V
_~ ~_ ~_ ,_ , ~ ~ I
~I ~1 ~ ~ ~ U-\ ~ V O
q_~ ~ ~, P~ ~q ~ ::C l 1 01 O V l l l ~ ~O ~rl O
~_ rl _ rl 51 ~ V l u~
O ¢ O O O O O O ~rl '`
~r r~ r1 r1 r l r1 ¢ r1 .
1~; ~1 ¢ ¢ ~~rl rl 1~ ~ O O O O ~0~ S
n-Heptane (500 ml) completely free from moisture and oxygen, triethylaluminum (2.5 mmole) and the foregoing solid catalyst component (4.2 mg) were added to the autoclave with stirring. Thereafter, hydrogen gas was charged to a pressure of 2 kg/cm2 (gauge) and then ethylene was charged to a pressure of 12 kg/cm2 (gauge) to start polymerization. Polymerization was continued at 90C for 1 hour while keeping the total pressure ;
:.
.. ; .
~.~39~ 8 1 of 12 kg/cm by supplying ethylene. After polymerization was finished, the resulting polymer was filtered, washed with n-heptane and dried at 60C under reduced pressure to obtain 72 g of polyethylene. The poly-ethylene had a melt index of 0.26 g/10 min. and a bulkdensity of 0.31 g/cc. In this case, the catalytic acti~ity was 17~ g (polyethylene)/g(solid catalyst componen~-hr, and in another expression, 323,000 g(polyethylene)~g Ti-hr.
Example 2 (1) Synthesis of organomagnesium compound (Grignard compound) To a l-liter four-necked flask equipped with a stlrrer, a reflux condenser and a dropping funnel was added magnesium chip (35.0 g) for Grignard reaction, and air and moisture in the flask were completely removed by replacement with nitrogen. n-Butyl chloride (125 g) and di-n-butyl ether (500 ml) were placed in the dropping funnel~ and the mixture (about 30 ml) was dropped to magnesium to allow reaction to start. After the beginning of the reaction, dropping was continued so as to allow the reaction to proceed smoothly. After dropping was finished, the reaction was continued at 60C to 70C for further about 1 hour. Thereafter, the reaction solution was cooled to room temperature, and unreacted magnesium was filtered off using a glass filter.
;
. . .
.
~139!7~
1 The content of Grignard compound in di-n-butyl ether was determined by hydrolyzing the compound with lN sulfuric acid, followed by back titration with lN
sodium hydroxide (indicator, phenolphthalein). It was found that the content was 2.10 mole/liter.
(2) Synthesis of solid catalyst component Air and moisture in a 100-ml four-necked flask e~uipped with a stirrer, a dropping funnel and a thermometer were thoroughly removed by replacement with nitrogen.
The di-n-butyl ether solution (23.8 ml~
containing 50 mmole of n~butylmagnesium chloride (n-~uMgCl) synthesi~ed in (1) was placed in the flask and stirred. Thereafter, triethyl phosphite (4.2 g~ was gradually added dropwise to the solution from the dropping funnel with ice-cooling. White precipitate was formed. Reaction was carried out for 1 hour with ice-cooling and then at 60C for further 1 hour. After reaction, di-n-butyl ether was removed by filtration, and the precipitate was washed with purified n-heptane (50 ml) and filtered. This washing and filtration cycle was repeated five times~ and then the precipitate was dried at room temperature under reduced pressure to obtain 8.4 g of a white solid. It was found by analysis that the contents of Mg, P, Cl and (n-C4Hg)20 were 20.0%, 0.3%, 25.8% and 16.8% by weight, respectively.
This white solid (3.5 g) was dipped in titanium tetra-chloride (30 ml) in a 100-ml four-necked flask, and , :. . ' ' ~ ' ~ ' ,~
~3g7~8 1 reaction was carried out at 130C for 1 hour. After the reaction was ~inished, the so].id product was repeatedly washed with n-h2ptane until titanium tetra-chloride in the washings was no longer detected. A
solid catalyst component (3.3 g) was thus obtained.
The component was dried and analyzed, and it was found that the amount of titanium supported was 47 mg per 1 g of solid catalyst component.
The synthetic method for the above solid catalyst component is also applicable to the synthesis of other solid catalyst components.
(3) Polymerization Polymerization was carried out in the same manner as in (3) of Example 1 except that 5~1 mg of the solid catalyst component obtained above was used.
As a result, 105 g of polyethylene was obtained. This polyethylene had a melt index of 0.64 g/10 min. and a bulk density of 0.32 g/cc. The catalytic activity was 20,600 g(polyethylene)/g(solid catalyst component)-hr, and in another expression, 438,000 g(polyethylene)/
g Ti-hr.
Example 3 Ethylene was polymerized in the same manner as in Example 1 except that 2.5 mmole of triisobutyl-aluminum was used in place of triethylaluminum, and that3.2 mg o~ the solid catalyst component was used. Thus, 60.0 g of polyethylene was obtained. This polyethylene :, - 20 _ ' : ~, - - ' ' ' ~
1~3g'73~
1 had a melt index of 0.20 g/10 min. and a bulk density of` 0.30 g/cc. The catalytic activity was 18,800 g(polyethylene)~g(solid catalyst component) hr, and in another expression, 354,000 g(polyethylene)/
g Ti-hr.
Example 4 Ethylene was polymerized in the same manner as in Example 2 except that 2.5 ~nole of diisobutyl-aluminum hydride was used in place of triethylaluminum, and that 3.5 mg of the solid catalyst component was used. Thus, 81.0 g of polyethylene was obtalned Thi.s polyethylene had a melt index o~ 0.35 g/10 min~ and a bulk density o~ 0.31 g/cc. The catalytic activity was 23,100 g(polyethylene)/g(solid catalyst component~-hr, and in another expression, 491,000 g(polyethylene)/
g Ti-hr.
Example 5 Ethylene was polymerized in the same manner as in Example 2 except that 2.5 mmole of diethylaluminum chloride was used in place of triethylaluminum, 15.5 mg of the solid catalyst component was used, and that the hydrogen pressure was 10 kg/cm2 and the total pressure was 20 kg/cm . Thus, 74.0 g of polyethylene was obtained.
This polyethylene had a melt index of 0.23 g/10 min.
and a bulk density of 0.34 g/cc. The catalytic acti~ity was 4,770 g(polyethylene)/g(solid catalyst component)-hr, ' ' - :'' , and in another expression, lOl,OQO g (polyethylene)/g Ti~hr.
Exa~ple 6 The synthesis of solid catalyst component was carried out in the same manner as in (2l of Example 2 except that ethylaluminum diisobutoxide IC2H5Al~O-iso-C4Hg)2, 50 mmol~
produced by reaction between triethylaluminum and isobutyl alcohol was used in place of triethyl phosphate, 30 ml of n-heptane was used as solvent. ~hus, 4.2 g of a white solid was obta~ned, This white solid contained 15.8% of di-n-butyl ether ~n-C4Hg)20]. This white solid (3.0 g) was allowed to react with t;~anium tetrachloride in the same manner as in ~2) of Example 1 to obtain a solid catalyst component. It was found that the amount of titanium supported was 5:L mg per 1 g of solid catalyst component.
Eth~lene was polymerized in the same manner as in Example 1 except that 4.0 mg o the solid catalyst component thus obtained was used, and that 2.5 mmole of triisobutylaluminum was used in place of triethylaluminum. ~hus, 93.5 g of polyethylene was obtained.
This polyethylene had a melt index of 0.67 g/10 min. and a bulk density of 0.32 g/cc. The catalytic activity was 23,400 g (polyethylene~/g(solid catalyst component)-hr, and in another expression, 459,000 g(polyethylene~/g Ti-hr.
~ 22 ~Q
' ' ~' 1 Examples 7 to 13 The preparation o~ solid catalyst component ancl polymerization of ethylene were carried out in the same manner as in Example 1 but using various compounds.
Preparation conditions for the solid catalyst co~lponent and the results of ethylene polymerization are shown in Tzble 1.
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rO ~d O `--~ .
_ _ ~39~;~
1 Examples 14 to 20 The preparation of solid catalyst component and polymerization of ethylene were carried out in the same manner as in Example 2 but using various compounds.
The results are shown in Table 2.
- 2~ -1~3~
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~1~139~38 1 Example 21 90.0 Grams of an ethylene/propylene copolymer was obtained by the same polymerization procedure as in Example 1 except that 3.1 mg of the solid catalyst component used in Example 1 was used, 10 g of propylene was added, and that the polymerization was carried out at 70C ~or 30 minutes. This copolymer conta~ned 15.0 methyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.940 g/cm3; melt index, 0.18 g/10 min.; bulk density, 0.30 g/cc. The catalytic activity was 58,100 g(polymer)/
g(solid catalyst component)-hr, and in another expression, 1,520,000 g(polymer)/g Ti-hr.
Example 22 75.5 ~rams of an ethylene/butene-l copolymer was obtained by the same polymerization procedure as in Example 1 except that 3.0 mg of the solid catalyst component used in Example 2 was added, 10 g of butene-l was added, and that the polymerization was carried out at 70C for 30 minutes. This copolymer contained 5.0 ethyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.942 g/cm3; melt index, 0.38 g/10 min.; bulk density, 0.40 g/cc. The catalytic activity was 50,300 g(polymer~/
g(solid catalyst component).hr, and in another expres-sion, 1,070,000 g(polymer)/g Ti-hr.
3~7;~8 , 1 Example 23 94.6 Grams of an ethylene/butene-l copolymer was obtained by the same polymerization procedure as in Example 1 except that the amount o~ solid catalyst component used in Example 2 was 3.1 mg, 250 g of butene-l was used in place of 500 ml of n-heptane, the polymeriza-tion temperature was 50C, and that the hydrogen pressure, ethylene pressure and total pressure were 2.5 kg/cm2, 1~ kg/cm2 and 27 kg/cm2 (partial pressure of butene-l at 50C was 6 5 ~g/cm2), respectively.
This copolymer contained 18.5 ethyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.924 g/cm3; melt index, 0.35 g/10 min.; bulk density, 0.42 g/cc. ~he catalytic activity was 30,500 g(polymer)/g(solid catalyst component)-hr, and in another expression, 649,ooo g(polymer)/g Ti.hr.
Example 24 Air in a l-liter stainless steel autoclave eauipped with a magnetic stirrer was thoroughly replaced with nitrogen, and the solid catalyst component (10.5 mg) used in Example 1, triethylaluminum (2.5 mmole) and liquid propylene (300 g) were added thereto. Polymeriza-tion was then carried out at 60C for 1 hour. A~ter polymerization was finished, propylene was purged, and the product was taken out and dried at 60C under reduced pressure to obtain 92.0 g of polypropylene.
- ~13~
1 The boiling n-heptane-insoluble portion of this poly-propylene was 38.5% by weight. The catalytic activity was 8,760 g(polypropylene)/g(solid catalyst component)~hr, and in another expression, 165,000 g(polypropylene)/
g Ti-hr.
Examples 25 to 27 Propylene was polymerized in the same manner as in Example 24 except that the amount of solid catalyst component shown in Table 3 was changed, and that the amount o~ electron donor shown in Table 3 was added as a third component on polymerization. The results are shown in Table 3.
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rO ~d O `--~ .
_ _ ~39~;~
1 Examples 14 to 20 The preparation of solid catalyst component and polymerization of ethylene were carried out in the same manner as in Example 2 but using various compounds.
The results are shown in Table 2.
- 2~ -1~3~
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o S~ o ~) 3 ~r) ~1 ~ ~ ) 3 L~ ~ ~ O S~
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o ~ ~ ~ S ~ ~ _, _~ ~ so ~ ~ ~ l ~ ~ C~ ~ ~ I
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m ~ m ~ = m o ~ l ~ l ~ l Co, o ~ C> ~ .1 ~ .1 ~1 ., o I
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a~ .,~ ~ ~ 61 ~ ~ ~ ~ ~r L~ ~r . E o ~J o~_ .
, `` :
~1~139~38 1 Example 21 90.0 Grams of an ethylene/propylene copolymer was obtained by the same polymerization procedure as in Example 1 except that 3.1 mg of the solid catalyst component used in Example 1 was used, 10 g of propylene was added, and that the polymerization was carried out at 70C ~or 30 minutes. This copolymer conta~ned 15.0 methyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.940 g/cm3; melt index, 0.18 g/10 min.; bulk density, 0.30 g/cc. The catalytic activity was 58,100 g(polymer)/
g(solid catalyst component)-hr, and in another expression, 1,520,000 g(polymer)/g Ti-hr.
Example 22 75.5 ~rams of an ethylene/butene-l copolymer was obtained by the same polymerization procedure as in Example 1 except that 3.0 mg of the solid catalyst component used in Example 2 was added, 10 g of butene-l was added, and that the polymerization was carried out at 70C for 30 minutes. This copolymer contained 5.0 ethyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.942 g/cm3; melt index, 0.38 g/10 min.; bulk density, 0.40 g/cc. The catalytic activity was 50,300 g(polymer~/
g(solid catalyst component).hr, and in another expres-sion, 1,070,000 g(polymer)/g Ti-hr.
3~7;~8 , 1 Example 23 94.6 Grams of an ethylene/butene-l copolymer was obtained by the same polymerization procedure as in Example 1 except that the amount o~ solid catalyst component used in Example 2 was 3.1 mg, 250 g of butene-l was used in place of 500 ml of n-heptane, the polymeriza-tion temperature was 50C, and that the hydrogen pressure, ethylene pressure and total pressure were 2.5 kg/cm2, 1~ kg/cm2 and 27 kg/cm2 (partial pressure of butene-l at 50C was 6 5 ~g/cm2), respectively.
This copolymer contained 18.5 ethyl groups per 1000 carbon atoms. The physical properties of the copolymer were as follows: density, 0.924 g/cm3; melt index, 0.35 g/10 min.; bulk density, 0.42 g/cc. ~he catalytic activity was 30,500 g(polymer)/g(solid catalyst component)-hr, and in another expression, 649,ooo g(polymer)/g Ti.hr.
Example 24 Air in a l-liter stainless steel autoclave eauipped with a magnetic stirrer was thoroughly replaced with nitrogen, and the solid catalyst component (10.5 mg) used in Example 1, triethylaluminum (2.5 mmole) and liquid propylene (300 g) were added thereto. Polymeriza-tion was then carried out at 60C for 1 hour. A~ter polymerization was finished, propylene was purged, and the product was taken out and dried at 60C under reduced pressure to obtain 92.0 g of polypropylene.
- ~13~
1 The boiling n-heptane-insoluble portion of this poly-propylene was 38.5% by weight. The catalytic activity was 8,760 g(polypropylene)/g(solid catalyst component)~hr, and in another expression, 165,000 g(polypropylene)/
g Ti-hr.
Examples 25 to 27 Propylene was polymerized in the same manner as in Example 24 except that the amount of solid catalyst component shown in Table 3 was changed, and that the amount o~ electron donor shown in Table 3 was added as a third component on polymerization. The results are shown in Table 3.
:
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.
Claims (21)
OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A solid catalyst component for olefin poly-merization prepared by a method which comprises reacting an organomagnesium compound with an alkoxy compound of the formula, R1aA1(OR2)bXc wherein R1 and R2 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom and a, b and c are numbers satisfying the equations at the same time, 0 ? a < 3, 0 < b ? 3, 0 ? c < 3, a + b + c = 3 and/or of the formula, R3dP(OR4)eXf wherein R3 and R4 are each a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and d, e and f are numbers satisfying the equations at the same time, 0 ? d < 3, 0 < e ? 3, 0 ? f < 3, and d + e + f = 3 to produce a solid product which is a carrier for catalyst, and then allowing the solid product to support a titanium compound and/or a vanadium compound.
2. A solid catalyst component according to Claim 1, wherein said solid product is produced in the presence of an ether compound and isolated from the reaction mixture.
3. A solid catalyst component according to Claim 1, wherein said solid product isolated from the reaction mixture is complexes having a coordinated ether compound.
4. A solid catalyst component according to Claim 1, wherein said organomagnesium compound is represented by the formula, R5MgX or R62Mg wherein R5 and R6 are each an alkyl, aryl, aralkyl or alkenyl group having 1 to 20 carbon atoms, and X is a chlorine, bromine or iodine atom.
5. A solid catalyst component according to Claim 1, wherein the molar ratio of the organomagnesium compound to the alkoxy compound is 1:10 to 10:1.
6. A solid catalyst component according to Claim 5, wherein the molar ratio of the organomagnesium compound to the alkoxy compound is 1:3 to 3:1.
7. A solid catalyst component according to Claim 1, wherein the reaction between the organomagnesium compound and the alkoxy compound is carried out at -30°C to 150°C.
8. A solid catalyst component according to Claim 7, wherein the reaction between the organomagnesium compound and the alkoxy compound is carried out at -10° to 100°C.
9. A solid catalyst component according to Claim 1, wherein the reaction is carried out in a solvent selected from the group consisting of aliphatic hydrocarbons, aromatic hydrocarbons, alicyclic hydrocarbons and ethers.
10. A solid catalyst component according to Claim 2, 3 or 9, wherein the ether compound is one represented by the formula, wherein R8 and R9 are each a hydrocarbon group having 1 to 20 carbon atoms, or may be linked together to form a ring.
11. A solid catalyst component according to Claim 2,3 or 9, wherein the ether compound is a member selected from the group consisting of diethyl ether, di-n-propyl ether, diisopropyl ether, di-n-butyl ether, di-sec-butyl ether, di-n-amyl ether, di-isoamyl ether, di-n-hexyl ether, di-n-octyl ether, diphenyl ether, dibenzyl ether, anisole, phenetole, methyl benzyl ether and tetra-hydrofuran.
12. A solid catalyst component according to Claim 1, wherein said alkoxy compound of the formula, R1aAl(OR2)bXc are aluminum trialkoxides of the formula, Al(OR2)3, wherein R2 is as defined above.
13. A solid catalyst component according to Claim 1, wherein the alkoxy compound of the formula, R3dP(OR4)eXf are trialkyl phosphites of the formula, P(OR4)3, wherein R4 is as defined above.
14. A solid catalyst component according to Claim 1, wherein said titanium compound or vanadium compound is a titanium compound of the formula, Ti(OR7)mX4-m wherein R7 is a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and m is a number satisfying the equa-tion, 0 ? m ? 4, vanadium tetrachloride or vanadium oxytri-chloride.
15. A solid catalyst component according to claim 14, wherein the titanium compound of the formula/ Ti(OR7)mX4-m (in which R7, X and m are as defined above), is titanium tetrachloride,
16. A solid catalyst component according to claim 3, wherein the isolated solid product contains 0.1 to 100 wt%
of an ether as a coordination component.
of an ether as a coordination component.
17. A solid catalyst component according to claim 16, wherein the amount of the ether as a coordination component is 0.5 to 50 wt%.
18. A solid catalyst component according to claim 1, wherein the content of titanium atom and/or vanadium atom in the solid catalyst component is 0.01 to 30 wt%.
19. A solid catalyst component according to claim 18, wherein the content of titanium atom and/or vanadium atom is 0.1 to 15 wt%.
20. A catalyst system for olefin polymerization compris-ing (1) a solid catalyst component according to claim 1, 2 or 3 and (2) an organoaluminum compound of the formula, wherein R10 and R11 are each a hydrocarbon group having 1 to 20 carbon atoms, Y is a hydrogen or halogen atom, and p and q are numbers satisfying the equations at the same time, 0 ? p < 3, 0 ? q < 3 and 0 ? p+q < 3.
21. A method for producing a polyolefin comprising polymerizing an olefin in the presence of a catalyst system comprising (1) a solid catalyst component according to claim 1, 2 or 3, and (2) an organo-aluminum compound of the formula, wherein R10 and R11 are each a hydrocarbon group having 1 to 20 carbon atoms, Y is a hydrogen or halogen atom, and p and q are numbers satisfying the equations at the same time, 0 ? p < 3, 0 ? q < 3 and 0 ? p+q < 3.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51641/79 | 1979-04-25 | ||
| JP5164179A JPS55144006A (en) | 1979-04-25 | 1979-04-25 | Preparation of polyolefin |
| JP920080A JPS56106904A (en) | 1980-01-28 | 1980-01-28 | Production of polyolefin |
| JP9200/80 | 1980-01-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1139738A true CA1139738A (en) | 1983-01-18 |
Family
ID=26343884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000350235A Expired CA1139738A (en) | 1979-04-25 | 1980-04-21 | Catalysts for the polymerization of olefins |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US4347157A (en) |
| BR (1) | BR8002449A (en) |
| CA (1) | CA1139738A (en) |
| DE (1) | DE3015878A1 (en) |
| FR (1) | FR2455054B1 (en) |
| GB (1) | GB2048906B (en) |
| IT (1) | IT1143936B (en) |
| NL (1) | NL8002351A (en) |
| SG (1) | SG45783G (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
| WO2017143174A1 (en) | 2016-02-18 | 2017-08-24 | International Flavors & Fragrances Inc. | Polyurea capsule compositions |
| EP4209264A1 (en) | 2016-09-16 | 2023-07-12 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5827704A (en) * | 1981-08-12 | 1983-02-18 | Sumitomo Chem Co Ltd | Preparation of polyolefin |
| FR2546522B1 (en) * | 1983-05-25 | 1985-07-26 | Ato Chimie | PROCESS FOR THE PREPARATION OF A TRANSITIONAL METAL COMPONENT FOR A CATALYTIC SYSTEM FOR OLEFIN POLYMERIZATION |
| US4612299A (en) * | 1984-07-09 | 1986-09-16 | Amoco Corporation | Magnesium carboxylate supports |
| JPH0721018B2 (en) * | 1985-07-05 | 1995-03-08 | 東燃料株式会社 | Method for producing catalyst component for olefin polymerization |
| US5225005A (en) * | 1991-03-28 | 1993-07-06 | Cooper Power Systems, Inc. | Method of annealing/magnetic annealing of amorphous metal in a fluidized bed and apparatus therefor |
| DE10163457A1 (en) * | 2001-12-21 | 2003-07-03 | Merck Patent Gmbh | Heterogenization of catalytic components |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU65587A1 (en) | 1972-06-22 | 1973-12-27 | ||
| FR2212346B1 (en) * | 1972-12-28 | 1978-12-01 | Nippon Oil Co Ltd | |
| IT1038179B (en) | 1975-05-16 | 1979-11-20 | Montedison Spa | PROCEDURE FOR POLYMERIZATION OF ALPHA OLEFINS WITH AT LEAST THREEATONS OF CARBON |
| IT1039828B (en) * | 1975-07-09 | 1979-12-10 | Montedison Spa | COMPONENTS OF PEARL CATALYSTS POLYMERIZATION OF OLEFINS AND CATALYSTS OBTAINED FROM THEM |
| NL7613855A (en) * | 1975-12-18 | 1977-06-21 | Sumitomo Chemical Co | PROCESS FOR POLYMERIZING OLEFINS. |
| JPS5287489A (en) | 1976-01-19 | 1977-07-21 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
| US4507450A (en) | 1976-08-18 | 1985-03-26 | Mitsubishi Chemical Industries Limited | Process for preparing polyolefin |
| DE2742585A1 (en) * | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | NEW POLYMERIZATION CATALYSTS AND THEIR USE (I) |
| JPS591407B2 (en) * | 1977-03-04 | 1984-01-12 | 三井化学株式会社 | Method for producing titanium catalyst component |
| JPS5447783A (en) * | 1977-09-22 | 1979-04-14 | Nissan Chem Ind Ltd | Preparation of ethylene polymer |
| JPS54112982A (en) | 1978-02-02 | 1979-09-04 | Sumitomo Chem Co Ltd | Polymerization of olefins |
| JPS54146885A (en) | 1978-05-10 | 1979-11-16 | Nissan Chem Ind Ltd | Improved polymerization process for ethylene |
-
1980
- 1980-04-07 US US06/138,148 patent/US4347157A/en not_active Expired - Lifetime
- 1980-04-16 FR FR8008487A patent/FR2455054B1/en not_active Expired
- 1980-04-17 IT IT48444/80A patent/IT1143936B/en active
- 1980-04-21 CA CA000350235A patent/CA1139738A/en not_active Expired
- 1980-04-22 BR BR8002449A patent/BR8002449A/en not_active IP Right Cessation
- 1980-04-23 NL NL8002351A patent/NL8002351A/en not_active Application Discontinuation
- 1980-04-24 DE DE19803015878 patent/DE3015878A1/en not_active Withdrawn
- 1980-04-25 GB GB8013657A patent/GB2048906B/en not_active Expired
-
1982
- 1982-02-23 US US06/351,451 patent/US4394292A/en not_active Expired - Fee Related
-
1983
- 1983-08-02 SG SG457/83A patent/SG45783G/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4521541A (en) * | 1983-02-09 | 1985-06-04 | International Flavors & Fragrances Inc. | Process for forming functional fluid and solid-containing thermoplastic films, uses thereof and process for producing same |
| WO2017143174A1 (en) | 2016-02-18 | 2017-08-24 | International Flavors & Fragrances Inc. | Polyurea capsule compositions |
| EP4209264A1 (en) | 2016-09-16 | 2023-07-12 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2455054A1 (en) | 1980-11-21 |
| FR2455054B1 (en) | 1986-03-28 |
| GB2048906A (en) | 1980-12-17 |
| IT8048444A0 (en) | 1980-04-17 |
| US4347157A (en) | 1982-08-31 |
| NL8002351A (en) | 1980-10-28 |
| SG45783G (en) | 1984-07-27 |
| DE3015878A1 (en) | 1980-11-06 |
| IT1143936B (en) | 1986-10-29 |
| US4394292A (en) | 1983-07-19 |
| BR8002449A (en) | 1980-12-09 |
| GB2048906B (en) | 1983-03-30 |
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