CA1107698A - Hand operated sprayer with automatic contaner vent - Google Patents

Hand operated sprayer with automatic contaner vent

Info

Publication number
CA1107698A
CA1107698A CA000271298A CA271298A CA1107698A CA 1107698 A CA1107698 A CA 1107698A CA 000271298 A CA000271298 A CA 000271298A CA 271298 A CA271298 A CA 271298A CA 1107698 A CA1107698 A CA 1107698A
Authority
CA
Canada
Prior art keywords
container
piston
liquid
bore
venting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000271298A
Other languages
French (fr)
Inventor
Jerry H. Miller
Emile B. Steyns
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AFA Products Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/693,383 external-priority patent/US4072252A/en
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of CA1107698A publication Critical patent/CA1107698A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005Components or details
    • B05B11/0037Containers
    • B05B11/0039Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means
    • B05B11/0044Containers associated with means for compensating the pressure difference between the ambient pressure and the pressure inside the container, e.g. pressure relief means compensating underpressure by ingress of atmospheric air into the container, i.e. with venting means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1001Piston pumps
    • B05B11/1009Piston pumps actuated by a lever
    • B05B11/1011Piston pumps actuated by a lever without substantial movement of the nozzle in the direction of the pressure stroke

Landscapes

  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Reciprocating Pumps (AREA)
  • Closures For Containers (AREA)
  • Infusion, Injection, And Reservoir Apparatuses (AREA)
  • Catching Or Destruction (AREA)

Abstract

Emile B. Steyns Jerry H. Miller By Thomas W. Brennan TITLE: HAND OPERATED SPRAYER WITH AUTOMATIC CONTAINER VENT

ABSTRACT OF THE INVENTION: The problem of venting the interior of a liquid container utilizing an attached hand-operated, trigger sprayer of the piston or plunger pump type is solved by the provision of a vent passage in the housing of the pump which communicates with the container interior. The piston which is reciprocated in a bore or chamber in the housing has a seal means associated therewith and with the vent passage so that in operation in spraying the container is vented and vacuum development in the container is avoided. In a preferred embodiment said seal means is associated with an entrance or opening to the vent passage so as to provide a seal against liquid leakage from the container when the piston of the pump is in an at rest, non-pumping position and yet permits, venting of the container when the piston is in a pumping position.

Description

~76~

BACKGROUND OF THE IN~'ENTION
Field of t~e' Invention A common problem with liquid spraying devices of the hand-operated type is the need for relief of the negative pressure created in the closed container on which the device is used as liquid is pumped. The vacuum created is relieved by venting atmospheric air into the container to displace the liquid dis-pensed. Various ways to do this have been proposed in the art and, in general, usually involve separate or discrete valve means ; 10 with or without a vent passage, and more often than not, are difficult to construct and are expensive. In addition, prior art devices are often cumbersome to use and operate.
It is also very important that the device not leak when the trigger or actuator is at rest and the container and sprayer are laid on a side or even inverted such as might be the case in normal use in spraying or in shipment where a full container might be supplied with the device when sold.
Desc'ription'of the Prior'Art A number of patents have been issued on trigger-piston type hand sprayers useful for dispensing liquid from containers. For example, a particularly useful, and perhaps the basic, trigger type sprayer is disclosed in U.S. Patent 3r061,2Q2, i~sued on October 30, 1962 to Tracy B. Tyler ~herein venting is provided by means of a separate valve biased in the normally open position.
Other patents disclosing similar sprayers also using discrete valve means for venting are U.S. Patent 3,650,473, issued on March 13, 1972 to Carl E. Malone, U.S. Patent 3,685,739, on Au~ust 22, 1972 to Vance R. Vanier, and U.S. Patent 3,780,951, on December 25, 1973 to Richard T. Powers. The first mentioned Malone patent vents in a manner similar to the T~ler device while the patent to Powers shows an atmospheric vent through the body of the spray-er where it attaches to the container but has a collar which is 7~

screwed down by the operator into an annular slot to close it o~
and thus prevent leakage of liquid from the container. Second mentioned patent to Vanier utilizes a vent passage which allows atmospheric air to flow through the sprayer's lower body past a resilient, conically-shaped hollow valve into the container.
In U.S. Patent 3,8~0,157, issued on October 3, 1974 to J.
F. Hellenkamp, a trigger operated sprayer is disclosed which dif-fers from the sprayers of the afoxementioned patents in that a plunger, or piston is mounted with its axis vertically aligned and movable off a sealing collar to permit venting of a container ; and is an example of a lever or trigger operated vent device, as is U.S. Patent 3,749, 290, issued on July 31, 1973 to L.A.
Micalleff, which discloses a deformable diaphragm pump system wherein a venting surface is unseated to permit atmospheric pres-sure to be applied to the interior of the container. Other patented devices having venting means are U.S. Patent 3,701,~78, issued October 31, 1972, U.S. Patent 3,762,647, issued October 2, 1973 and U.S. Patent 3/770,2Q6, issued November 6, 1973 to T.
Tada; U.S. Patent 3,768,734, issued Octobex 3Q, 1974 to I.O.
Anderson, Jr., et al; and U.S. Patent 3,820,721, issued on June 28, 197~ to J.F. Hellenkamp.
The present invention provides a simple, efficient, relative-- ly inexpensive and easy to use venting system and includes an automatic drain back feature in a pleasantly appea~ing structure which operates during pumping and spraying and ~ithout the employ-ment of additional parts or component mechanisms.
SUMMARY OF THE INVENTION
It is, therefore, an object of the present invention to provide a vent system for a manual, trigger operated sprayer which is simple in construction, efficient in operation, and is easily and economically manufactured.
It is another object of the present invention to provide a manually operated trigger sprayer which employs no separate or ~76~!~

discrete mechanisms or other parts ~or venting the container on which it is mounted, nor additional components operatively associated therewith.
It is still another object of the present invention to pro-vide a manually operated, trigger sprayer of the foregoing type wherein liquid which may leak by a seal element may be drained back into the container rather than being permitted to leak from the sprayer.
~ ccording to the present teachings, a manually operated lQ liquid dispenser is provided which is adapted to be attached to a container holding liquid to be dispensed and comprises component retaining body means, the bulk of which is located outside of the container when attached thereto, an outwardlY
opening bore defined within the interior of the component re-taining body means, a piston which is shiftable within the bore and bounding a variable compartment with the bore, inlet and out-let means disposed within the component retaining body means for delivering liquid into and out of the compartment bounded by the piston and bore, operating means which includes a tigger normally actuated by the application of substantially horizontal force by the fingers thereto for shifting the piston within the bore be-tween a normal non-pumping position and a pumping position, vent-ing means ex~ending through the body means and opening, at one end, into the bore, and a single unit providing seal means for the venting means and the compartment, the seal means comprising ~ pair of spaced apart seals integrally molded with the piston, - the seal means in normal non-pumping position, preventing commun-ication to the ambient air from the venting means and th~ compart-ment, thereby forming a positive closure for the container, the seal means in pumping position permitting free communication be-tween the venting means and the ambient air.

~ :.f I

, 7~

Other objects and advantages of the present application will be apparent from the detailed description and drawings which follow.
BRIEF DESCRIPTION OF THE DRAWI~GS
Figure 1 is a sectional elevation of a preferred embodi-ment of the invention showing a trigger operated pump mechanism in its at rest or non-pumping condition;
Figure 2 is a sectional elevation, similar to Figure 1 of another embodiment of the invention.
DETAILED DESCRIPTION AND OPERATION OF THE INVENTION
With reference to Figure 1, a trigger type, manually oper-ated sprayer 10 comprising a housing or component retaining body lQ-a hav~ng a cylindrical, hollow pump chamber or bore 11 closed at its upper end but in communi`cation through its side wall by means of an exit or outlet passage 12 connected to a chamber 13 in a nozzle 14. Nozzle 14 has an exit orifice or "spray" nozzle opening 15. An inlet passage 16 provides communication between pump chamber or bore 11 and an inlet valve chambQr 17 in a intake body portion 17-a. Chamber 17 contains, in sealing relation on a valve seat 19 therein, a ball check 18 in an inlet passage 20.
A liquid pick-up~ or dip tube 21 is fitted in air-tight relation and extends downwardly from body portion 17-a into a container 23 terminating near the bottom thereof (not shown). A container -4a-6~3 cap 22 is attached to body 10-a on body portion 17-a and is adapted to be clamped or screwed down onto the threaded neck psr-tion of container 23 in liquid-tight relation therewith. A ring or lip seal 24 is formed on the bottom surface of body portion 17-a and mates with the top surface of container 23.
Slidably positioned for reciprocation in chamber or bore 11 is a plunger assembly 25 comprising a hollow piston 25-a and a carrier piece or holder 25-b. Ho:Lder 25-b has a recess 25-a on one end which engages an extension 27-a of an actuating trigger 27 mounted on body 10-a by means of a pivot or pin connector 29.
Piston 25-a is fitted into a second recess in holder 25-b in the opposite end thereof, and in the embodiment shown, comprises a pair of spaced apart, annular circumferentially extending seals 30 and 31, the former preferably being a lip sealing angularly, rearwardly extending and sealingly contacting the wall of bore 11, whereas seal 31 preferably has a rounded, substantially cir-cular appearance, also sealingly contacting the wall of bore 11.
A compression spring 26 axially ~iases plunger assembly 25 in a direction away from or out of bore 11, spring 26 being mounted in bore 11 between the closed end thereof at one end and the hollow interior of piston 25-a, the parts described being arranged such that when at rest, as shown in the drawings, spring 26 may be under some slight compression~ As is apparent from Figure 1, when trigger 27 is actuated and pivoted about pin 29, plunger as-sembly 25 and piston 25-a reciprocate in bore 11 compressing spring 26 to initiate and maintain pumping operation of sprayer 10.
As mentioned above, in its preferred form piston 25-a is providea with spaced apart, peripheral lip seal 30 and annular, circular seal 31 which sealingly engage in sliding relation the inner wall of bore 11. In the at rest or non~pumping position as shown in Figure 1, seals 30 and 31 are separated by a peri-pheral space or groove 32 and straddle the opening or entrance 33-a to a vent passage 33 formed in body 10-a in a bottom wall of chamber or bore 11. Passage 33 extends from space or groove 32 to one or more vertical passages 34 (one only shown in the Figures) formed in body portion 17-a and provides fluid communi-cation to the interior of container 23 from space or groove 32 permitting, as will be seen, venting of container 23.
Once again referring to Figure 1, it should be readily apparent that the present invention includes within its scope and is just as readily operated with a single seal on piston 25-a, which, preferably, would be forward lip seal 30. In this instance in the at rest position shown in Figure 1 (and Fig. 2~, piston 25 may be positioned in chamber 11 so that seal 30 is in juxtaposi-tion with opening or entrance 33-a of passage 33, by which is meant that seal 30 would normallyr when in the at rest position of piston 25 Cor 125 of Fig. 2~, be in a position proximate to entrance 33-a o~l ei~her~s;de thereof~ in or on top of said entrance 33-a. It would, of course, be preferred in a single seal arrange-ment that seal 30 (or seal 130 of Figure 2~, be juxtaposed with entrance 33-a on the trigger 27 side thereof to retain the "no leak" advantage previously referred to and described. How-ever, operationally, the objecti~ve of venting would still be achieved with a single seal 30 (or 130~ even if said seal is ar-ranged in a normally at rest position in juxtaposition on the opposite side of opening 33-a or on top of said opening. In these latter arrangements, however, some leakage may be expected in some situations such as when sprayer 10 and container 23 is inverted or laid on its side. It is, of course, possible to modify sprayer 10 somewhat to avoid this eventuality in any of several well-known ways (not shown~. For example, passage 33 may be formed as a capillary tube of fine diameter whereby liquid leakage which might occur will be insignificant, yet air passage will be unin-hibited. Another means for obviating or mitigating against such 76~8 possible leakage is the use of materi~ls ~lell-kno~rn to those skilled in the art in passage 33 which pe~m~t gas or air flow but inhibit or prevent li~u~d flow. Lastly mechanical devices such as check valves (not shownl may be employed in passage 33 or 34 to prevent liquid out flow while still permitting air flow in the opposite direction to vent conta~ner 23.
In operation of the Figure 1 or preferred embodiment of the inventionr container 23 is filled with liquid and sprayer 10 is attached by clamping or scre~ing downcap 22 onto the neck of container 23 with dip tube 21 extend~ng below the liquid surface.
A liquid~tight seal is obtained b~ seal ring 24 on the top surface of container 23 when cap 22 is screwed down or otherwise clamped on the neck thereof. Sprayer 10 is no~ ready for spraying liquid by grasping container 23 in the hand pistol gxip fashionr the fingers gripping trigger 27. Trigger 27 is squeezed forcing plunger assembly 25 and piston 25-a into bore 11 pressurizing the air therein and forcing ball 18 to close against seat 19. Air ' ; in chamber or bore 11 flo~s into exlt or discharge conduit 12 and into chamber 13 of nozzle 14 forcing a slidable valve member 35 therein to move leftwardly. Fluid flo~s around valYe member 35 through the radial passages formed between the vertical wall 35-a and ridges 35-b on the end of member 35 and is discharged in a spray through nozzle 14 orifice 15. ~hen trigger 27 is released, piston 25-a and plunger 25 moves oppositely or leftwardly under the force of compressed spring 26, and trigger 27 returns to the "at rest" position shown. This action causes an expansion or increase in volume of chamber 11 and a slight vacuum develops~
which opens ball check 18 and forces val~e member 35 in nozzle 14 to close against a seat 36 in ch~mber 13. Simultaneously liquid is drawn up into bore 11 through tube 21, chamber 17 and inlet passage 16. Seal 30 on piston 25-a prevents liquid leak-age from chamber or bore 11, however should leakage occur liquid will flow back into container 23 through passages 33 and 34 from `;~
:

annulal^ space 32, being prevented from flowing out of sprayer 10 by seal 31. Subsequent squeezing and releasing of trigger 27 repeats the above cycle except liquid is now being pumped and sprayed from container 23.
It is, however, necessary that atmospheric air be allowed to enter contalner 23 to make up for the volume of liquid drawn therefrom and equalize pressure therein. If venting is not allow-ed for, a vacuum will develop in container 23 and either liquid spray will cease or container 23 will tend to deform and/or col-lapse. The provision of vent passage 33 and passage 34 connected thereto in the wall of chamber or bore 11 and body portion 17-a respectively, permits venting communication between the interior of container 23 and the atmosphere to be established. When annular, spaced apart seals 30 and 31 are used on piston 25-a and straddle the entrance 33-a to vent 33, when trigger 27 is squeezed and piston 25-a moves into chamber 11, seal 31 will pass beyond opening or entrance 33-a to passage 33 and container 23 is vented to the atmosphere. It can be seen therefore, that the location of en~
trance 33-a to passage 33 between seals 30 and 31 in annular space 32, and closely adjacent to seal 31, permits yenting of container 23 during the pumping or spraying stroke, yet in the non-pumping or "at rest" position, a positive closure for container 23 is simultaneously also provided.
Referring now to Figure 2, an additional embodiment is dis-closed wherein a one~piece piston and plunger device 125 is shown.
Piston or plunger 125 is preferably a single molded piece including the spaced apart, annular, circumferentially extending seals or sealing surfaces 130 and 131 separated by the peripheral, or an-nular recess 132, and, as shown in Figure 2, is in the at rest position. In this position, seals 130 and 131 straddle opening or entrance 33-a vent passage 33 as in the preferred, Figure 1 embodiment. In all other respects as to construction and ~1~176~

operation,~ ~he Figure 2 embodiment is identical with the Fiyure 1 invention. In addition, while not shown herein, it is evident that seal 130 could also be formed, as by molding and the like, as a lip seal for enhanced sealing quality usually characteristic of this type seal and, due to less friction between seal and wall would provide faster return of the pump and trigger to the at rest position by compressed spring 26.
It should~also be understood that a single seal element device, similar to that previously disclosed is applicable to this embodiment and such is fully contemplated. Also piston or plunger 125 can be molded with suitable annular grooves (not shown) in which O-ring type seals or the like, can be installed in place of the shown seal elements 130 and 131 with comparable beneficial results. In addition, the sealing elements associated with the piston can also be located in bore 11 remaining stationary rela-tive to piston 25 when the latter is reciprocated. In short, any number of methods can be employed to provide the necessary sealing between piston and bore in chamber 11 and will occur to the skilled artisan. Similarly, leakage if apparent, can be dealt with in accordance with the known methods, previously de-scribed.
It is expected that the invention hereinabove described will be constructed of thermoplastic materials by any of the usual and well-known processes, for example, blow molding, injec-tion molding, casting or the like, depending on materials used and sprayer qualities desired. Examples of suitable materials useful in carrying out the invention include any of the well-known plastics such as polystyrene, polyvinylchloride, polyure-thane, the polyolefins, polyamide, polyacetate, polycarbonate, polyester and the many possible mixtures or blends thereof.
A preferred material is the polyolefin,polypropylene, which has many desirable qualities including being resilient and is thus particularly useful for sealing elements or devices and for the ~76~

pistons 25-a and 125. Other suitable materials include natural rubber, synthetic rubber, acrylonitrile-~utadiene styrene (ABS) and mixtures of these and other materials. Each material will be selected in accordance with good engineering practice to maxi-mize quality and minimize cost and expense.

: 10

Claims (7)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1 . A manually operated liquid dispenser adapted to be attached to a container holding a liquid to be dispensed comprising:
a. component retaining body means, the bulk of which is located outside of said container when attached thereto, b. an outwardly opening bore defined within the interior of the component retaining body means, c. a piston shiftable within the bore and bounding a variable compartment with said bore, d. inlet and outlet means disposed within the component retaining body means for delivering liquid into and out of the compartment bounded by the piston and bore, e. operating means, including a trigger normally actuated by the application of substantially horizontal force by the fingers thereto, for shifting the piston within the bore between a normal, non-pumping position and a pumping position, f. venting means extending through the body means and opening, at one end, into the bore, and g. a single unit providing seal means for the venting means and the compartment, the seal means comprising a pair of spaced apart seals integrally molded with the piston, the seal means in normal non-pumping position, preventing comm-unication to the ambient air from the venting means and the com-partment, thereby forming a positive closure for the container, the seal means in pumping position permitting free communication between the venting means and the ambient air.
2. The dispenser according to claim 1 in which said seals straddle said venting means.
3. A dispenser according to claim 1 in which the operating means includes resilient means to urge the piston to the normal, non-pumping position.
4. A dispenser according to Claim 1 further comprising a container for retaining the liquid to be dispensed the component retaining body means being secured upon the container so that the inlet means contacts the liquid and the venting means in pumping position extends between the ambient air and the air in the container above the liquid level.
5 . The dispenser according to Claim 1 in which at least the piston is a molded resilient article of a thermo-plastic selected from polyethylene, polypropylene, polyurethane, acrylonitrile butadiene styrene (ABS), synthetic rubber, natural rubber, polyvinylchloride, polyacetate, polyamide, polyester and mixtures thereof.
6. A manually operated liquid dispenser adapted to be attached to a container holding a liquid to be dispensed comprising:

a. component retaining body means, the bulk of which is located outside of said container when attached thereto, b. a dip tube depending from said body means, c. inlet means within said body means for admitting liquid thereinto, d. outlet means including a discharge orifice located at one end of the body means remote from the inlet means to dispense liquid therefrom, e. check valve means disposed within the component retaining body means to regulate the flow of liquid, f. an outwardly opening bore defined within the interior of the body means and communicating with the inlet and outlet means, g. a piston shiftable within said bore and defining a variable volume pumping chamber therewith, h. operating means, including a trigger normally actuated by the application of substantially horizontal force by the fingers thereto, for shifting the piston within the bore between a normal, non-pumping position and a pumping position, i. venting means extending through the body means and opening, at one end, into the bore, and j. a single unit providing seal means for the venting means and the pumping chamber, the seal means comprising a pair of spaced apart seals integrally molded with the piston, the seal means in normal non-pumping position preventing comm-unication to the ambient air from the venting means and the pumping chamber thereby providing a positive closure for the container, the seal means in pumping position permitting free communication between the venting means and the ambient air.
7. A dispenser according to claim 6 further comprising a container for retaining the liquid to be discharged the component retaining body means being secured to said container so that the dip tube extends downwardly into the liquid and said venting means in pumping position extending between and providing communication between the ambient air and the air in the container above the liquid level.
CA000271298A 1976-02-09 1977-02-08 Hand operated sprayer with automatic contaner vent Expired CA1107698A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US65654776A 1976-02-09 1976-02-09
US656,547 1976-02-09
US693,383 1976-06-07
US05/693,383 US4072252A (en) 1976-02-09 1976-06-07 Hand operated sprayer with automatic container vent

Publications (1)

Publication Number Publication Date
CA1107698A true CA1107698A (en) 1981-08-25

Family

ID=27097214

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000271298A Expired CA1107698A (en) 1976-02-09 1977-02-08 Hand operated sprayer with automatic contaner vent

Country Status (18)

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JP (1) JPS5297414A (en)
AU (1) AU503659B2 (en)
BR (1) BR7700754A (en)
CA (1) CA1107698A (en)
CH (1) CH609587A5 (en)
DE (1) DE2705071A1 (en)
DK (1) DK148379C (en)
ES (1) ES455656A1 (en)
FR (1) FR2340139A1 (en)
GB (1) GB1537004A (en)
HK (1) HK8080A (en)
IT (1) IT1079467B (en)
MX (1) MX143907A (en)
NL (1) NL7700365A (en)
NO (1) NO770099L (en)
NZ (1) NZ182980A (en)
PH (1) PH17736A (en)
SE (1) SE7700375L (en)

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US4365751A (en) * 1980-09-26 1982-12-28 Yoshino Kogyosho Co., Ltd. Trigger type liquid injector
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US5794822A (en) * 1996-04-17 1998-08-18 Contico International, Inc. Reciprocating fluid pump with improved bottle seal
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Also Published As

Publication number Publication date
JPS5297414A (en) 1977-08-16
SE7700375L (en) 1977-08-10
DK148379B (en) 1985-06-24
DK50477A (en) 1977-08-10
FR2340139A1 (en) 1977-09-02
NL7700365A (en) 1977-08-11
PH17736A (en) 1984-11-23
AU503659B2 (en) 1979-09-13
HK8080A (en) 1980-03-14
MX143907A (en) 1981-07-31
FR2340139B1 (en) 1980-01-11
AU2190177A (en) 1978-08-10
BR7700754A (en) 1977-10-11
JPS5441726B2 (en) 1979-12-10
DE2705071A1 (en) 1977-08-11
NO770099L (en) 1977-08-10
ES455656A1 (en) 1978-01-01
CH609587A5 (en) 1979-03-15
NZ182980A (en) 1979-12-11
DE2705071C2 (en) 1988-03-03
IT1079467B (en) 1985-05-13
DK148379C (en) 1985-11-18
GB1537004A (en) 1978-12-29

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